M. Kaneda

Positive and negative cluster ions from liquid ethanol by fast ion bombardment

Secondary ion mass spectra have been measured for the first time for a liquid ethanol target bombarded by 2.0 MeV He(+) ions. Positive and negative ion spectra exhibit evidently a series of cluster ions of the forms [(EtOH)(n)H](+) and [(EtOH)(n)-H](-), respectively, in addition to light fragment ions from intact parent molecules. It was found that these cluster ions are produced only from liquid phase ethanol. Both positive and negative secondary ion spectra show similar cluster size distributions with almost the same decay slope. We also present for the first time the cluster ion distribution emitted from the liquid at different liquid temperatures.

Measurements of stopping cross sections of liquid water for fast protons and helium ions

Stopping cross sections of liquid water for MeV energy protons and helium ions have been measured by using a liquid jet target in vacuum. Energy loss spectra after passing through the target were measured at scattering angles from 5.0 to 50 mrad. The energy loss spectra have been successfully reproduced by Monte Carlo simulation calculations (GEANT4 v9.1.p03 toolkit) by taking account of multiple scattering of projectile particles inside the target. For protons, the stopping cross sections were deduced in an energy range from 0.3 to 2.0 MeV. It was found that the present data are in fairy good agreement with recent theoretical calculations.