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Featured researches published by M.N. Pulkin.


Physics of the Solid State | 2004

Correlation between the dynamics of oxygen atoms and oxidation kinetics of solid solutions based on Bi2Sr2CaCu2O8

A.V. Knotko; A.V. Garshev; M.N. Pulkin; V. I. Putlyaev; S.I. Morozov

AbstractThe oxidation kinetics of Bi1.3Pb0.8Sr2Ca0.8Y0.2Cu2O8+δ solid solutions at different temperatures and


MRS Proceedings | 2004

Internal oxidation in solid solutions Bi2.1‑xPbxSr2-yCa1-zRy+zCu2O8+d (R = Y, Nd or La)

A.V. Garshev; A.V. Knotko; M.N. Pulkin; D.I. Kirdyankin; Andrei V. Geyer; V.I. Putlayev


Materialwissenschaft Und Werkstofftechnik | 2006

Silicon-substituted hydroxyapatite ceramics (Si-HAp): densification and grain growth through the prism of sintering theories

V.I. Putlayev; A. G. Veresov; M.N. Pulkin; A. Soin; V. Kuznetsov

p_{O_2 } = 0.21


Inorganic Materials | 2005

Internal oxidation in Bi2.1-xPbxSr2-yCa1-zRy+zCu2O8+d (R = Y, Nd, La) solid solutions

A.V. Knotko; A.V. Garshev; M.N. Pulkin; D.I. Kirdyankin; V. I. Putlyaev


Abstracts of 10th European conference on solid state chemistry | 2005

Effect of Pb-doping on microstructure and properties of Sr-hexaferrite

A.V. Garshev; A.V. Knotko; M.N. Pulkin; D.I. Kirdyankin; V.I. Chelpanov; Alexander Meledin; V.I. Putlayev

atm is investigated by thermogravimetry. The results obtained are compared with the previously studied oxidation kinetics of Bi1.3Pb0.8Sr2Ca0.8Y0.2Cu2O8+δ solid solutions. It is found that the substitution of yttrium for calcium leads to an appreciable retardation of the initial oxidation stage associated with the oxygen diffusion. The phonon spectra of the solid solutions are examined using inelastic neutron scattering on a DIN-2PI direct-geometry spectrometer. The high-frequency (>50 meV) phonon densities of states for yttrium-containing and yttrium-free solid solutions are analyzed. The possible model is proposed for a correlation between the differences observed in the high-frequency phonon densities of states attributed to the vibrations of oxygen atoms and the differences in the oxidation kinetics of the solid solutions under consideration.


Mendeleev Communications | 2004

Internal oxidation in Bi2.1-xPbxSr2-yCa1-zYy+zO8+d solid solutions

A.V. Knotko; A.V. Garshev; M.N. Pulkin; D.I. Kirdyankin; Andrei V. Geyer; V.I. Putlayev; Ru-Shi Liu

Bi 2-x Pb x Sr 2 CaCu 2 O 8+d solid solutions with substitution of Sr or Ca by Y, Nd or La were fabricated at 760 - 79°C in N 2 -flow. The as-synthesized solutions were oxidized in air under isothermal condition and tested with XRD, TGA chemical analysis, TEM, XANES. Effect of rare-earth element content on oxidation kinetics and microstructure of the product is discussed.


MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS | 2003

THE INTERNAL OXIDATION IN SOLID SOLUTIONS BASED ON BI2SR 2CACU2O8 WITH SIMULTANEOUS SUBSTITUTION BI ON PB AND CA OR SR ON RARE EARTH ELEMENTS

A.V. Knotko; F.G. Shayhutdinov; V.I. Putlayev; A.V. Garshev; M.N. Pulkin; N.M. Privalova; S.I. Morozov


Mater. of Intern. Workshop MSU - HTSC VI | 2001

The oxidation of the solid solution based on Bi-2212 phase

V.I. Putlayev; A.V. Knotko; A. G. Veresov; M.N. Pulkin; A.V. Garshev


Abstracts of conference "Solid State Chemistry 2001" | 2001

The decomposition of Bi-2212 based solid solutions through red-ox treatment

A. G. Veresov; A.V. Knotko; M.N. Pulkin; A.V. Garshev; V.I. Putlayev


Abstracts of MRS'2001 Fall Meeting, 26.11 - 29.11.2001 | 2001

The red-ox decomposition of the solid solution based on Bi-2212 phase

A.V. Knotko; A. G. Veresov; M.N. Pulkin; A.V. Garshev; V.I. Putlayev

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A.V. Knotko

Moscow State University

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A.V. Garshev

Moscow State University

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A. Soin

Moscow State University

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V. Kuznetsov

Moscow State University

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