M. Sandström | Researchain

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Journal of Solution Chemistry | 1991

Structure Determination of Zinc Iodide Complexes Formed in Aqueous Solution

Hisanobu Wakita; Georg Johansson; M. Sandström; Peter L. Goggin; Hitoshi Ohtaki

Structures of the complexes formed in aqueous solutions between zinc(II) and iodide ions have been determined from large-angle X-ray scattering, Raman and far-IR measurements. The coordination in the hydrated Zn2+ hexaaqua ion and the first iodide complex, [ZnI]+, is octahedral, but is changed into tetrahedral in the higher complexes, [ZnI2(H2O)2], [ZnI3(H2O)]− and [ZnI4]2−. The Zn-I bond length is 2.635(4)Å in the [ZnI4]2− ion and slightly shorter, 2.592(6)Å, in the two lower tetrahedral complexes. In the octahedral [ZnI(H2O)5]+ complex the Zn-I bond length is 2.90(1)Å. The Zn-O bonding distances in the complexes are approximately the same as that in the hydrated Zn2+ ion, 2.10(1)Å.

Acta Chemica Scandinavica | 1978

The Crystal Structure of Hexaaquamercury(II) Perchlorate, [Hg(H2O)6](ClO4)2.

Georg Johansson; M. Sandström; H. Mosbæk; Inger Søtofte; Olav Smidsrød; Cha-On Pontchour; Pathana Phavanantha; Supanich Pramatus; B. N. Cyvin; Sven J. Cyvin

Acta Chemica Scandinavica | 1976

Hydrothermal Preparation and Magnetic Properties of alpha-CrOOH, beta-CrOOH, and gamma-CrOOH.

A. Nørlund Christensen; Erik Larsen; Juhani Murto; K. J. Watson; M. Sandström

Acta Chemica Scandinavica | 1976

Bis(2,2'-bipyridine) and Bis(1,10-phenanthroline) Complexes of Chromium(III) and Cobalt(III).

Martin Paul Hancock; Jens Josephsen; C. E. Schäffer; K. J. Watson; M. Sandström

Acta Chemica Scandinavica | 1978

The Crystal Structure of Hexaaqua-tri-mu-hydroxo-mu3-oxo-triuranyl(VI) Nitrate Tetrahydrate, [(UO2)3O(OH)3(H2O)6]NO3.4H2O.

Martha Aberg; M. Sandström; H. Mosbæk; Inger Søtofte; Olav Smidsrød; Cha-On Pontchour; Pathana Phavanantha; Supanich Pramatus; B. N. Cyvin; Sven J. Cyvin

Acta Chemica Scandinavica | 1978

An X-Ray Diffraction and Raman Study of Chloride, Bromide and Iodide Complexes of Mercury(II) in Dimethyl Sulfoxide Solution and of Mercury(II) Chloride in Methanol Solution.

M. Sandström; Erik Larsen; Torben Smith Sørensen; Elina Nasakkala; Otto Bastiansen; Liv Fernholt; Grete Gundersen; Claus J. Nielsen; B. N. Cyvin; Sven J. Cyvin

Acta Chemica Scandinavica | 1976