Magdalena Aflori

Calcium carbonate microparticle templates using a PHOS-b-PMAA double hydrophilic copolymer

The crystallization characteristics of calcium carbonate microparticles grown from supersaturated aqueous solutions in the presence of a double hydrophilic block copolymer poly(p-hydroxystyrene-b-methacrylic acid), PHOS-b-PMAA, have been investigated. The studies aim to highlight both the possibilities and the limitations of CaCO3/PHOS-b-PMAA microparticle formation under different relative inorganic/polymer ratio conditions, varying the initial solution supersaturation or the polymer concentration. Scanning electron microscopy and atomic force microscopy were used to provide high-resolution images of particles and thereby information on the particle morphology, while X-ray diffraction analysis was used to determine the polymorph type and crystallite characteristics. The presence of the polymer in the composite particles was shown by thermogravimetric, particle charge density and zeta potential analysis. The polymer-induced sensitivity of the new composites to environmental pH variations has been followed by streaming potential variation.

Functional silsesquioxane-based hierarchical assemblies for antibacterial/antifungal coatings

This paper reports the first study on functional silsesquioxane-based hierarchical assemblies containing an ordered distribution of silver nanoparticles with a large number of {111} facets, obtained through sol-gel reaction, intended for antibacterial/antifungal coatings.

Bactericidal effect on Foley catheters obtained by plasma and silver nitrate treatments

New medical, materials, and surgical procedures keep improving current health-care practices. Many of these innovations involve polymeric devices that must meet certain clinical and cost requirements. Novel antimicrobial technologies and nanotechnologies are being implemented in more applications such as implant interphases, coatings, and others to avoid postoperatory infections. Here we present a novel approach to create antimicrobial surfaces on Foley catheters widely used in hospitals in order to avoid a variety of harms including infection, pain, and trauma. The combination of plasma and silver nitrate wet treatments demonstrates to be a fast, easy, and convenient method for obtaining colonization-resistant catheter surfaces.

Collagen immobilization on ultraviolet light-treated poly(ethylene terephthalate):

The present article is focused on the studies regarding the effects of ultraviolet (UV) light on poly(ethylene terephthalate) (PET) films surfaces using scanning electron microscopy (SEM), Fourier transform infrared, X-ray photoelectron spectrometry (XPS), and atomic force microscopy (AFM) measurements, subsequent to collagen immobilization. UV treatment influences the surface energy of polymers as the result of the polymer chain breaking, followed by insertion of oxygen-containing functional groups. Accordingly, after UV light treatment, collagen was adsorbed on the PET surfaces in different proportions. Significant changes in the surface topography appeared after collagen immobilization on UV-treated PET films, and they were put in evidence by SEM and tapping-mode AFM experiments. XPS measurements demonstrated the adsorption of collagen on PET UV light-altered surfaces by increasing of nitrogen content. The cytocompatibility tests using stem cells have shown good results for all treated polymers.

Polyimide surface modification by RF plasma for biocide attachment

ABSTRACT This article has been retracted.

Modification of Polyethylene Terephthalate

Nowadays, polymers find wide applications in modern industry, but finishing and bonding of almost all polymers present low hydrophilicity of their surfaces, which affects printability, wettability, biocompatibility, and adhesion. Therefore, polymer films need additional surface treatments to modify the surface properties, for better wettability and adhesion activities. There are different methods to modify the surface properties of the polymer films such as chemical or plasma treatments, ultraviolet (UV) or laser irradiation. Chemical surface modification may produce toxic compounds and physical alterations in the composition of the surface. From the polymer class, the polyesters have been frequently used to improve protein and cell adhesion.

Three-Dimensional Nanostructures with Biocidal Activity Created on a Siloxane-Containing Copolyimide Film

Surface morphological characteristics of a copolyimide film prepared from a fluorine-based dianhydride combined with an aliphatic siloxane-based diamine and an aromatic containing ether linkages one, were studied before and after oxigen plasma treatment using atomic force microscopy (AFM). The three-dimensional texture parameters calculated from the AFM data have highlighted a more pronounced surface morphology (higher average roughness and developed interfacial area ratio), improved bearing properties and no predominant orientation, as the plasma exposure time was increased from 6 to 10 minutes, using the same power (40 W). The reactive groups generated on the binding surface have facilitated the interaction with a biocidal agent, such as silver nitrate. This creates silver-containing nanoparticles, of about 120-150 nm, uniformly distributed on the copolymer surface, with a density of 10±2 particles/μm2. The functionalization with the biocidal agent of the flourinated copolyimide surface was conducted for testing its antimicrobial properties, namely the inhibition/destruction of Escherichia coli bacterium.