Mahamad Hakimi Ibrahim

Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: a review.

Chitosan based adsorbents have received a lot of attention for adsorption of dyes. Various modifications of this polysaccharide have been investigated to improve the adsorption properties as well as mechanical and physical characteristics of chitosan. This review paper discusses major research topics related to chitosan and its derivatives for application in the removal of dyes from water. Modification of chitosan changes the original properties of this material so that it can be more suitable for adsorption of different types of dye. Many chitosan derivatives have been obtained through chemical and physical modifications of raw chitosan that include cross-linking, grafting and impregnation of the chitosan backbone. Better understanding of these varieties and their affinity toward different types of dye can help future research to be properly oriented to address knowledge gaps in this area. This review provides better opportunity for researchers to better explore the potential of chitosan-derived adsorbents for removal of a great variety of dyes.

An Introduction to Anaerobic Digestion of Organic Wastes

The problem of waste disposal from a myriad of industries, is becoming increasingly acute, the world over. The burning of such wastes in open dumps or in poorly designed incinerators could be a major source of air pollution (Ndegwa and Thompson. Bioresour Technol 76:107–112, 2001). On the other hand, open dumps and poorly designed sanitary landfills can pollute surface and ground waters causing public health hazards. Meanwhile, the unavailability and rising cost of land near urban areas have made dumps and landfills increasingly expensive and impractical. The production of both livestock and grain on the other hand has increasingly relied on enormous chemical and energy inputs, leaving soils depleted of indigenous nutrients and organic matter, and resulting in wide-scale surface and groundwater contamination. As discussed earlier, recycling and utilization of organic wastes and by products through development of an economically viable, socially accepted and eco-friendly technologies are required. Over the years an array of innovative ideas for the utilization of these wastes have been put forward (Callaghan et al. Bioresour Technol 67:117–122, 1999) to increase productivity and to meet the heavy demand for food of the growing population (Jeyabal and Kuppuswamy. Eur J Agron 15:153–170, 2001). But these wastes could not be fully exploited without a viable technology for their economic recycling. It is well demonstrated that both fresh and composted amendments over these waste materials are potent to stimulate soil biological activities. Fresh wastes produces an initial burst of biochemical activity by the releasing easily degradable organic compounds whereas compost induces lower biochemical activities but more resistance to soils (Masciandaro et al. Soil Biol Biochem 32:1015–1024, 2000). Biological treatments plays a pivotal role in treating organic wastes these days. Among them, anaerobic digestion is frequently the most cost effective method because of the high energy recovery and its limited environmental impacts. Biogas production throughout Europe, could reach over 15 million m3/day of methane reported during 1998 (Tilche and Malaspina. Biogas production in Europe. Paper presented at the 10th European conference biomass for energy and industry, Wurzburg, 8–11 June, 1998). Presently, biogas production is considered to be an inevitable way of energy production.

Chitosan hydrogel beads impregnated with hexadecylamine for improved reactive blue 4 adsorption

Adsorption performance of chitosan (CS) hydrogel beads was investigated after impregnation of CS with hexadecylamine (HDA) as a cationic surfactant, for the elimination of reactive blue 4 (RB4) from wastewater. The CS/HDA beads formed with 3.8% HDA were the most effective adsorbent. The adsorption capacity was increased by 1.43 times from 317 mg/g (CS) to 454 mg/g (CS/HDA). The RB4 removal increased with decrease in the pH of dye solution from 4 to 9. The isotherm data obtained from RB4 adsorption on CS and CS/HDA are adequately described by Freundlich model (R(2)=0.946 and 0.934, χ(2)=22.414 and 64.761). The kinetic study revealed that the pseudo-second-order rate model (R(2)=0.996 and 0.997) was in better agreement with the experimental data. The negative values of ΔG° (-2.28 and -6.30 kJ/mol) and ΔH° (-172.18 and -101.62 kJ/mol) for CS beads and HDA modified CS beads, respectively; suggested a spontaneous and exothermic process for RB4 adsorption.

Elimination of reactive blue 4 from aqueous solutions using 3-aminopropyl triethoxysilane modified chitosan beads

The adsorption behavior of chitosan (CS) beads modified with 3-aminopropyl triethoxysilane (APTES) for the removal of reactive blue 4 (RB4) in batch studies has been investigated. The effects of modification conditions, such as the APTES concentration, temperature and reaction time on RB4 removal, were studied. The adsorbent prepared at a concentration of 2 wt% APTES for 8h at 50 °C was the most effective one for RB4 adsorption. The adsorption capacity of modified CS beads (433.77 mg/g) was 1.37 times higher than that of unmodified CS beads (317.23 mg/g). The isotherm data are adequately described by a Freundlich model, and the kinetic study revealed that the pseudo-second-order rate model was in better agreement with the experimental data. The negative values of the thermodynamic parameters, including ΔG° (-2.28 and -4.70 kJ/mol at 30 ± 2 °C), ΔH° (-172.18 and -43.82 kJ/mol) and ΔS° (-560.71 and -129.08 J/mol K) for CS beads and APTES modified beads, respectively, suggest that RB4 adsorption is a spontaneous and exothermic process.

Characteristic Drying Curves of Cocoa Beans

ABSTRACT The characteristic drying curves of cocoa beans are determined by using a tunnel drier where conditioned air passes a single cocoa berm suspended from an electronic balance in the test section. Weight loss, and temperatures of air, testa and nib of the cocoa bean is monitored on personal computers. The nornmalised drying rate versus the normalised moisture content is regressed by least square method to fit a new polynomial model for the penetration falling rate period and a linear model for the regular regime falling rate period. It can be concluded that there are three drying periods for cocoa beans namely the constant drying rate period, the penetration falling rate period and the regular regime falling rate period. The polynomial model estimates the penetration period quite well whereas the linear model estimates the regular regime quite well as well. There is no observable influence of relative humidity and air temperature on the characteristic drying curve of cocoa beans. However, the air ve...

A review on composting of oil palm biomass.

Abstract Nowadays, the biomass produced in oil palm industry, such as oil palm fronds, palm pressed fibers, palm kernel shells, empty fruit bunch, and liquid waste discharged from the palm oil mill effluent and others, may lead to significant environmental concerns. The quantity of produced wastes by oil palm industry is increasing with the growth of this industry day by day. Therefore, the use of these wastes as compost is considered by researchers to overcome their negative impacts and recycle them to produce a useful byproduct for agriculture. This review analyzes the recent composting studies on palm oil biomass and provides useful information about the potential uses of these biomass in composting as an alternative method for enhanced and sustainable use of biomass produced from oil palm industry. In addition, environmental impacts of composting are discussed. This knowledge could build a platform for researchers in this area to understand the recent developments in palm oil biomass composting by means of addressing the environmental pollution concerns as well.

Oil Palm Biomass as an Adsorbent for Heavy Metals

Many industries discharge untreated wastewater into the environment. Heavy metals from many industrial processes end up as hazardous pollutants of wastewaters.Heavy metal pollution has increased in recent decades and there is a growing concern for the public health risk they may pose. To remove heavy metal ions from polluted waste streams, adsorption processes are among the most common and effective treatment methods. The adsorbents that are used to remove heavy metal ions from aqueous media have both advantages and disadvantages. Cost and effectiveness are two of the most prominent criteria for choosing adsorbents. Because cost is so important, great effort has been extended to study and find effective lower cost adsorbents.One class of adsorbents that is gaining considerable attention is agricultural wastes. Among many alternatives, palm oil biomasses have shown promise as effective adsorbents for removing heavy metals from wastewater. The palm oil industry has rapidly expanded in recent years, and a large amount of palm oil biomass is available. This biomass is a low-cost agricultural waste that exhibits, either in its raw form or after being processed, the potential for eliminating heavy metal ions from wastewater. In this article, we provide background information on oil palm biomass and describe studies that indicate its potential as an alternative adsorbent for removing heavy metal ions from wastewater. From having reviewed the cogent literature on this topic we are encouraged that low-cost oil-palm-related adsorbents have already demonstrated outstanding removal capabilities for various pollutants.Because cost is so important to those who choose to clean waste streams by using adsorbents, the use of cheap sources of unconventional adsorbents is increasingly being investigated. An adsorbent is considered to be inexpensive when it is readily available, is environmentally friendly, is cost-effective and be effectively used in economical processes. The advantages that oil palm biomass has includes the following:available and exists in abundance, appears to be effective technically, and can be integrated into existing processes. Despite these advantages, oil palm biomasses have disadvantages such as low adsorption capacity, increased COD, BOD and TOC. These disadvantages can be overcome by modifying the biomass either chemically or thermally. Such modification creates a charged surface and increases the heavy metal ion binding capacity of the adsorbent.

Biological Responses of Agricultural Soils to Fly-Ash Amendment

The volume of solid waste produced in the world is increasing annually, and disposing of such wastes is a growing problem. Fly ash (FA) is a form of solid waste that is derived from the combustion of coal. Research has shown that fly ash may be disposed of by using it to amend agricultural soils. This review addresses the feasibility of amending agricultural field soils with fly ash for the purpose of improvings oil health and enhancing the production of agricultural crops. The current annual production of major coal combustion residues (CCRs) is estimated to be -600 million worldwide, of which about 500 million t (70-80%) is FA (Ahmaruzzaman 2010). More than 112 million t of FA is generated annually in India alone, and projections show that the production (including both FA and bottom ash) may exceed 170 million t per annum by 2015 (Pandey et al. 2009; Pandey and Singh 20 I 0). Managing this industrial by-product is a big challenge, because more is produced each year, and disposal poses a growing environmental problem.Studies on FA clearly shows that its application as an amendment to agricultural soils can significantly improve soil quality, and produce higher soil fertility. What FA application method is best and what level of application is appropriate for any one soil depends on the following factors: type of soil treated, crop grown, the prevailing agro climatic condition and the character of the FA used. Although utilizing FA in agricultural soils may help address solid waste disposal problems and may enhance agricultural production, its use has potential adverse effects also. In particular, using it in agriculture may enhance amounts of radionuclides and heavy metals that reach soils, and may therefore increase organism exposures in some instances.

Vermicomposting biotechnology: recycling of palm oil mill wastes into valuable products

BackgroundPalm oil mill effluent and palm press fiber are problematic wastes generated by the palm oil mill industries in Malaysia. This study has endeavored to assess the possibility of the vermicomposting of residue from the palm oil mills using epigeic earthworms Lumbricus rubellus under laboratory conditions. The study was conducted over 50 days using four combinations in three replicates of each treatment as palm oil mill effluent: palm press fiber in 50:50 ratio (T1), palm oil mill effluent/palm press fiber/cow dung in 50:25:25 ratio (T2), palm oil mill effluent/palm press fiber/cow dung/lawn clipping in 50:20:15:15 ratio (T3), and only palm press fiber (T4). Twenty healthy adult L. rubellus with average weight of 3.92 g was introduced.ResultsResults showed that T3 has a significant decrease in C/N ratio (14.81 ± 0.07) compared to the other treatments. The presence of cow dung and lawn clipping in the mixtures makes it more suitable for vermicomposting process as early compost productions were recorded in T2 and T3.ConclusionThe study showed that the major polluting problem in palm oil mills can be tackled through vermicomposting technique. Based on the results, vermicompost is found suitable for agriculture purposes as an organic fertilizer as well as soil conditioner.

DRYING CHARACTERISTICS OF OIL PALM KERNELS

ABSTRACT The drying characteristics of a single oil palm kernel suspended in a drying tunnel is studied. Luikovs unsteady state simultaneous heat and mass transpon equations are proposed as the governing equations. The model is simulated using the explicit and modified implicit Crank Nicholson finite difference algorithms. The desorption isotherms of the kernel warj determined using an environmental chamber and the data generated was found to fit the Hasleys and Hendersons equations well. The mass diffusion coefficient was determined by using a distributed system parameter identification technique where a weighted least square criterion between model and experimental average moisture content and temperature profiles is optimized using the Lagrangian algorithm within the constraints of the governing equations. The simulated parameter estimated drying characteristics were found to be in good agreement with experimental values.