Manuela Lunz

Plasmonic LED device

Plasmonic nanostructures are known to influence the emission of near-by emitters. They can enhance the absorption and modify the external quantum efficiency of the coupled system. To evaluate the possibility of using plasmonics to enhance the light emission of a phosphor-converted LED device and create an efficient directional light source, regular arrays of aluminium nanoparticles covered with a red dye layer are investigated. In arrays of aluminum nanocylinders with a diameter of ca 140 nm combined with a thin (650 nm) layer of luminescent material, very narrow resonances have been observed, which lead to large enhancement factors of up to 70 and 20 for excitation with a directional blue laser source and a lambertian LED respectively, in a small spectral range for particular angles. The measured resonances agree very well with finite-difference time-domain numerical simulations. These changes in the angular emission profile of the red dye as well as the spectral shape of its emission can help to optimize the efficacy of phosphor-converted LED modules and increase the amount of useable light in a certain angular cone. Using Fourier microscopy, large modifications of the angular emission profile as well as spectral shaping are observed for these plasmonic LED devices if compared to reference samples without plasmonic nanostructures.

Can LEDs help with art conservation? – Impact of different light spectra on paint pigment degradation

The impact of the spectral composition of light on the discoloration of paint pigments has been investigated for the case of lead chromate sulfate, an unstable yellow pigment used by Vincent van Gogh and other painters. With LEDification, museum lighting is moving from using halogen to LED lamps. LED light sources have a significantly different spectral composition than halogen lamps. To understand the impact of these differences on pigment stability, the wavelength dependence of pigment discoloration was determined. Contrary to the expectation that lower wavelength photons induce more damage than higher wavelength ones, UV (394 nm), blue, and cyan light all lead to similar levels of discoloration of a pigment for the same level of radiant power. By understanding this wavelength dependence, it becomes possible to create white light LED lamps with a spectral composition tuned to minimize the degradation effect. An existing LED solution with a modified emission indeed resulted in 30% less color change in the experiment than halogen. Furthermore, a method is proposed to optimize the LED spectra by tuning to the properties of each specific artifact. Simulations show that this can reduce the damage of the light source by 45% in specific cases.