Marcin Pietrzykowski

Selected Physico-Chemical Properties of Zinc and Lead Ore Tailings and their Biological Stabilisation

The following work focuses on problems and possibilities for revegetation of zinc and lead ore tailings in the Mining and Metallurgic Plant ‘Boleslaw’ in Poland, and on selected physical and chemical properties also regarding the vegetation, which spontaneously appears on the ponds. It was found that main factors impeding the development of vegetation are excessive contents of Zn, Pb, and Cd, as well as eolian erosion and deficiency of macroelements. The results of biological fertilisation tests were discussed in particular with regard to the deficiency of macroelements and the immobilisation of Zn, Pb, and Cd. Pot and field experiments permitted determination of this kind of interaction with doses of mineral fertilization ensuring plant growth. Plants were introduced to the sediment without a layer of insulation. The obtained results, along with some thorough research into the conditions prevailing on the sedimentation ponds, may be used as a basis for the biological stabilisation of this kind of waste material.

Linking heavy metal bioavailability (Cd, Cu, Zn and Pb) in Scots pine needles to soil properties in reclaimed mine areas.

This work deals with bioaccumulation of Zn, Pb, Cu and Cd in foliage of Scots pine, grown on mine soils. Regression models were used to describe relationships between pine elements bioavailability and biological (dehydrogenase activity) and physico-chemical properties of mine soils developed at different parental rocks. Concentration of trace elements in post-mine ecosystems did not differ from data for Scots pine on natural sites. We conclude that, in this part of Europe in afforested areas affected by hard coal, sand, lignite and sulphur mining, there is no risk of trace element concentrations in mine soils. An exception was in the case of Cd in soils on sand quarry and hard coal spoil heap located in the Upper Silesia region, which was more due to industrial pressure and pollutant deposition than the original Cd concentration in parental rocks.

Soil organic matter, C and N accumulation during natural succession and reclamation in an opencast sand quarry (southern Poland)

Abstract The work presents study results on the formation of humus horizons, the accumulation of organic carbon and nitrogen as well as humus composition in successional and reclaimed soils in a sand mine cast in southern Poland. Research plots were designed in chronosequence: 5, 17, 20 and 25 years. Increased thickness of humus horizon and accumulation of organic carbon was reported both in successional soils and in reclaimed soils. However, in corresponding age groups of reclaimed soils these characteristics were two times as high as in successional soils. The estimated accumulation rate of organic carbon (Corg) was three times higher and total nitrogen (Nt) five times higher in reclaimed soils than in successional soils. In both types of soils there was an increase in the amount of carbon trapped with humic and fulvic acid (CHa + CFa) and structure of humic acids. Studies indicated that reclamation treatment significantly accelerated soil-formation in opencast sand mine.

Soil quality index as a tool for Scots pine (Pinus sylvestris) monoculture conversion planning on afforested, reclaimed mine land

In Central Europe, a large portion of post-mining sites were afforested with Scots pine, which is characterized by good adaptability and a tolerance for poor habitat at the beginning of forest ecosystem development. Conversion of monoculture on mine sites into more biodiverse mixed hardwood forests, especially on more fertile deposits, can be an emerging need in this part of Europe in next decades. The ability to classify the forests at these post-mining sites will facilitate proper species selection as well as the management and formation of the developed ecosystem’s stability. This work describes the guidelines that can be followed to assess reclaimed mine soil (RMS) quality, using the mine soil quality index (MSQI) and a classification of developed forest sites as a basis of tree-stand species selection and conversion of pine monocultures. The research was conducted on four post-mining facilities (lignite, hard coal, sulphur, and sand pit mining areas) on different RMS substrates dominant in Central Europe. Soil quality assessment takes into account the following features of the soil: texture soil nutrients (Ca, Mg, K, Na, P); acidity (pH KCl); and Corg-to-Nt ratio in the initial organic horizon. An analysis was conducted of classification systems using the MSQI validation correlation (at p =0.05) with vegetation features affected by succession: aboveground biomass of forest floor and ecological indicators of vascular plants (calculated on the basis of Ellenberg’s (2009) system). Eventually, in the analysed data set, the MSQI ranged from 0.270 for soils on quaternary sands to 0.720 for a mix of quaternary loamy sands with neogene clays. Potential forest habitat types and the role of the pine in the next generation of tree stands on different RMS parent rock substrate were proposed.

Scots pine needles macronutrient (N, P, K, CA, MG, and S) supply at different reclaimed mine soil substrates—as an indicator of the stability of developed forest ecosystems

A main objective of restoration and afforestation at post-mining sites is establishing a long-term sustainable ecosystem which depends on adaptations of tree species and which in turn depends on the soil nutrient flux. The nutrient concentration (nitrogen (N), P, K, Ca, Mg, and sulfur (S)) of Scots pine needles was investigated in reclaimed mine soils (RMS) located at the following post-mining sites: a sand mine pit, spoil heap from a lignite mine, spoil heap from a S mine, and a carbonaceous spoil heap from an underground coal mine. The control plots were arranged on natural forest sites adjacent to the post-mining sites. A higher level of foliar nutrients was noted in the carbonaceous RMS, while lower levels were found in RMS on the spoil heap following lignite mining. The characteristics of the substrate were found to exert greater effect than mineral fertilization (performed at the onset of reclamation) on the tree stand characteristics, needle length and foliar nutrient concentration. While the soils and trees were most deficient in N, negative symptoms have not been noted to this date in tree stands at reclaimed mine sites. Trophic ratings were recommended based on statistical correlations and groupings between N and P contents in needles and needles length (mean length of 300 needles) while nutrient ratings were recommended from statistical differences and groupings of the RMS substrates.

Simulation of Birch and Pine Litter Influence on Early Stage of Reclaimed Soil Formation Process under Controlled Conditions.

The impact of litter decomposition on chemical substrate properties and element leaching during early soil formation in afforested post-mine sites and the influence of different tree species are key issues in new ecosystem development. Scots pine ( L.) and common birch ( Roth) are important pioneering species used in afforestation of post-mine sites in central and eastern Europe. The aim of this study was to assess the impact of litter decomposition of these species on the chemical properties of mine soil substrates. The impact of litter decomposition on soil properties was tested on quaternary and neogene substrates with different textures (sands, loams, and mixtures of clays and sands) in a controlled incubation experiment using PVC columns. Simulation of precipitation and leaching was undertaken for 10 wk at a temperature of 16°C with distilled water (200 mL wk) through cylinders with litter, substrate + litter, and control substrate (no litter). Filtrated water solution was collected once a week for laboratory analysis, and the concentrations of dissolved organic C, total N, K, Ca, Mg, and P were determined. The study results indicate a stronger impact of the common birch on the chemical properties of reclaimed mine soils compared with pine. After the experiment, birch litter caused significant changes in pH in quaternary sands, concentration of P in quaternary loams (Ql) and mixtures of neogene clays and quaternary sands (QsNc), exchangeable Ca in QsNc, and Mg in Ql and QsNc compared with pine litter. Birch, in comparison to pine, may affect the intensity of early-stage soil-forming processes by increasing nutrient availability and transport into the soil profile, which may affect the development of soil microbial communities. This process results in different soil properties under the two tree species.

Assessment of english oak (Quercus robur L.) growth in varied soil-substrate conditions of reclaimed Piaseczno sulfur mine dump

Abstract This study presents selected tree stand features and stand productivity of the English oak (Quercus robur L.) growing in the conditions of a reclaimed external dump of Piaseczno sulfur mine in Tarnobrzeg mining area. Following 40 years of growth in the dump, the oak trees reached first and second bonitation class and good growth parameters. The oak obtained the highest stand volume and basal area on sandy soils and loamy-sand substrates. A significant negative correlation between high clay content in soil cores and tree stand parameters was observed, indicating unfavourable impact on tree growth. The results confirmed the usefulness of the English oak as the main (target) species in the conditions of sulfur dumps, and the suitability of its introduction with preliminary identification of micro-habitat differentiation.

Tree species affects the concentration of total mercury (Hg) in forest soils: Evidence from a forest soil inventory in Poland

This study was performed to test the hypothesis that tree species significantly affects mercury (Hg) sequestration in forest soils. We analyzed the effect of seven dominant tree species (Scots pine, black alder, Norway spruce, silver birch, deciduous oak, silver fir, and European beech on the concentrations and pools of Hg in a range of forest soils in Poland. We set up 277 sample plots representing dominant tree species in Poland. Soil samples were taken and analyzed for total Hg content, soil texture, and soil C and nitrogen (N) content. Concentrations of total Hg in forest soil (organic and mineral horizons) varied by several orders of magnitude as a result of natural variations in organic matter, sand content, and altitude. Spatial analysis revealed that maximum concentrations (mg kg-1) and stocks (mg m-2) of Hg were related to mountain stands at higher elevations with loamy soils and greater accumulation of soil organic matter. The stocks of Hg in the investigated soil profiles increased in the order of: pine (12 mg m-2) ≈ birch (15 mg m-2) < oak (21 mg m-2) ≈ alder (24 mg m-2) < beech (45 mg m-2) ≈ spruce (50 mg m-2) < fir (66 mg m-2). Simple analysis of variance suggested an important effect of dominant tree species on Hg concentrations and stocks in entire soil profiles, but multiple regression analysis showed that dominant tree species had a significant effect on accumulation of Hg in soil, but only in the organic horizon; in mineral soil the Hg was content was related to C content, soil texture and altitude. The organic horizon had greater accumulation of Hg under coniferous tree species (Scots pine, silver fir and Norway spruce) and European beech when compared with deciduous oak, black alder, and silver birch.

Soil Quality Indices for Evaluation of Acid Mine Spoil

Abstract Planting vegetation is a common practice for reclamation of mine spoils but can be hindered due to poor physical properties, nutrient deficiency, and the chemically hostile nature of the substrate. Sulfide-bearing minerals (e.g., pyrite) decompose to produce acid conditions when exposed and can result in elevated levels of metals and metalloids. Reclamation practices thus may need to neutralize acidity and/or slow the rate of sulfide oxidation, provide organic and inorganic fertilization, and may be enhanced by revegetating with species that are tolerant to acid mine spoil conditions. Full restoration of spoils requires the establishment of a functional ecosystem, thus assessment and monitoring should include the physical, chemical, and ecological status of the spoil substrate. Amendment strategies, plant establishment, and assessment of soil quality indices in reclaimed acidic spoils are presented.

Reclamation of Mine Lands in Poland

Abstract In the chapter characterization of the reclamation activity and implementation in the mine industry branches in Poland were presented. The reclaim practice legal grounds and standards in Poland and the resulting splits on various phases of reclamation and development stages were analyzed. The balance of the surface area occupied by the exploitation of mineral resources and coal returned after restoration by the extractive industry were discussed, and the characteristics of the main technical conditions and natural reclamation activities at different types of mining, with particular emphasis on prevailing in Poland toward the forest restoration, were presented. We present the existing divisions and classifications of postmining areas in Poland, based on an assessment of the degree of difficulties of biological reclamation, and the effects of restoration. A special section devoted to the technical and biological stabilization of the objects with the most difficult degree of reclamation, including tailings dumps and combustion waste landfills.