Marcin Sobczyk

Optical spectroscopy of Sm3+ doped Na2O–ZnO–La2O3–TeO2 glasses

Telluride glasses with the composition xSm2O3-(7-x)La2O3-3Na2O-25ZnO-65TeO2 (where x=0.1, 1, 2, 5 and 7 mol%) were obtained by the melt quenching technique. Electronic absorption and fluorescence spectra as well as fluorescence dynamics of the Sm(3+)-doped title glasses are presented and analysed in detail. A Judd-Ofelt intensity analysis of the absorption spectrum at 300 K has been applied for determination of Ωλ parameters (Ω2=3.10, Ω4=3.80, Ω6=1.61×10(-20) cm(2)) which in turn have been used for calculations of the radiative transition probabilities (AT), the natural (radiative) lifetimes (τR) of the (4)G5/2 level of Sm(3+), the fluorescence branching ratios (β) and the emission cross-sections (σem). The τR value of the (4)G5/2 level amount to 1546 μs and is slightly higher than the measured decay time of 1306 μs. With the increasing of Sm2O3 concentration from 0.1 to 7.0 mol% the experimental lifetime of the fluorescent level decreases from 1306 to 41 μs. An analysis of the non-radiative decay was based on the cross-relaxation mechanisms. The optical achieved results indicate that the investigated glasses are potentially applicable as an orange and/or red laser host.

Tunable lasers based on diode pumped Tm-doped vanadates Tm:YVO4, Tm:GdVO4, and Tm:LuVO4

Thulium doped vanadates Tm:YVO4 (5 at.% Tm/Y, grown by the Czochralski technique), Tm:GdVO4 (2 and 6 at.% Tm/Gd, grown by the floating-zone technique), and Tm:LuVO4 (3 at.% Tm/Y, grown by the floating-zone technique) were investigated as an active medium for diode pumped tunable laser operating around 1.9 μm. For thulium laser tuning single 1.5mm thick Brewster-angled birefringent quartz plate (Lyot filter) was placed in simple 80mm long linear quasi-hemispherical resonator. For thulium doped vanadates pumping a fibre-coupled (core diameter 400 μm) temperature-tuned laser diode operating in range from 799 up to 810nm was used (max available power 20 W). All tested crystals were investigated under CW and pulsed pumping. Under pulsed pumping (4% duty-cycle, reduced heat generation) lasing and laser tuning was demonstrated with all available samples. Lasers were tunable in following wavelength ranges: Tm:YVO4 5 at.% Tm/Y (1841 - 1927 nm), Tm:GdVO4 2 at.% Tm/Gd (1830 - 1982 nm), 6 at.% Tm/Gd (1850 - 2010 nm), and Tm:LuVO4 3 at.% Tm/Lu (1860 - 1940 nm). Under CW pumping only Tm:GdVO4 crystal was lasing (lasing of Tm:YVO4 and Tm:LuVO4 was not reached under elevated pumping duty factor). Using Tm:GdVO4 (2 at.% Tm/Gd) the power up to 2.6W and slope effciency ~ 30% (with respect to absorbed power at 808nm under lasing condition) was obtained at wavelength 1.91 μm. Tunable operation with greater that 1W output and 130nm tuning range (1842 - 1972 nm) was demonstrated for Tm:GdVO4 (2 at.% Tm/Gd) pumped at 802 nm.