Marcos Lado

Spatial and seasonal patterns of fluorescent organic matter in Lake Kinneret (Sea of Galilee) and its catchment basin

Lake Kinneret (Sea of Galilee) is one of the major water resources in Israel. The origin and characteristics of natural organic matter (NOM) in the lake and its tributary rivers were studied using fluorescence excitation emission matrices (EEM) and parallel factor analysis. Two humic-like and one proteinous components were sufficient to describe EEM variability among 167 water samples collected between 2/2005 and 9/2006. The two humic-like components showed different relations in lake and riverine samples. Their vertical distribution in the lake was affected by seasonal stratification and distance from water surface, presumably reflecting the release of humic-like matter from sediments, its production via NOM transformation in the bottom layers, and its photodegradation in the upper layers. Vertical distribution of the proteinous component, indicating biological activity at upper water layers, did not correlate with that of the humic-like components. Dissolved organic carbon concentrations did not show any vertical stratification, emphasizing the power of EEM to explore NOM dynamics.

Soil structure changes: aggregate size and soil texture effects on hydraulic conductivity under different saline and sodic conditions.

Hydraulic conductivity of soil is strongly dependent on soil structure, which can be degraded during wetting and leaching. It was hypothesised that this structural degradation is dependent on initial aggregate size distribution and soil texture. The general aim of this study was to investigate the effects of aggregate sizes and soil textures, and their interactions, on the structural degradation and saturated hydraulic conductivity (Ks) of smectitic soils under different saline and sodic conditions. The studied soils were clay and loamy sand soils with low (~4.5) or high (~10) exchangeable sodium percentages (ESP), and with aggregate sizes in the ranges: (i) <1 mm (small aggregates); or (ii) 2–4 mm (large aggregates). The Ks values of the samples in a column after slow or fast pre-wetting were determined by means of a constant head device. Different wetting rates and leaching under various saline and sodic conditions had no effect on the Ks of the loamy sand; however, the Ks values of this soil with large aggregates were an order of magnitude greater than those of the soil with small aggregates. In contrast, in the clay soil with large aggregates, the Ks values after fast pre-wetting were significantly smaller than those after slow pre-wetting, probably because of aggregate slaking. No significant effects of the wetting rates on Ks were found in clay soil with small aggregates. An increase in the ESP in the clay soil decreased the Ks by a factor of 1.5 for the large aggregates and by an order of magnitude for the small aggregates, mainly as a result of increased clay swelling. Leaching the clay soil with deionised water significantly decreased the Ks values, partly because of clay dispersion. Although significant structural degradation of the clay soil occurred during leaching, the Ks values were smaller in the soils with small aggregates than in those with large aggregates, indicating the importance of the initial aggregate size on Ks even in soils that are prone to structural damage.

Effect of soil wetting conditions on seal formation, runoff, and soil loss in arid and semiarid soils - a review

Soil surface sealing is one of the main causes for low infiltration rate (IR) and high runoff and soil loss under raindrop impact conditions in arid and semiarid regions. Many studies have focused on the effects of soil properties on seal formation under fast wetting conditions. However, in the field, soils can be exposed to different wetting conditions, before an intense rainfall event, which can affect the role of the soil properties on seal formation. The present paper reviews the effects of different initial wetting conditions and their interactions with soil properties on seal formation, IR, runoff, and soil loss in smectitic soils. Fast wetting of soil causes aggregate slaking, which enhances seal formation, runoff, and soil loss under rainfall, mainly in soils with > 40% clay content. An increase in clay content of the soil increases aggregate strength, but at the same time increases the slaking forces. Hence, in soils with low clay content (  40% clay content and high aggregate stability, slaking plays an important role in aggregate breakdown and seal formation. An increase of raindrop kinetic energy, from 8 to 15.9 kJ/m3, decreased the effect of the slaking forces on seal formation and runoff. It was suggested that the effects of raindrop kinetic energy and of the slaking forces on aggregate disintegration and seal formation are complementary. An increase in soil exchangeable sodium percentage (ESP), from 0.9 to 20.4%, decreased the effect of slaking forces on seal formation and runoff production under rainfall with 15.9 kJ/m3 kinetic energy. Probably, increasing the ESP increased the soil dispersivity, and therefore diminished the effect of the slaking forces on aggregate disintegration and seal formation. Aging (the time since wetting) of soil increased the stability of soil structure, decreased the seal formation, maintained high IR, and diminished soil loss amounts. These effects of soil aging depend on both the prewetting rate of the soil and soil texture.

Long-Term Uptake of Phenol-Water Vapor Follows Similar Sigmoid Kinetics on Prehydrated Organic Matter- and Clay-Rich Soil Sorbents

Typical experimental time frames allowed for equilibrating water-organic vapors with soil sorbents might lead to overlooking slow chemical reactions finally controlling a thermodynamically stable state. In this work, long-term gravimetric examination of kinetics covering about 4000 h was performed for phenol-water vapor interacting with four materials pre-equilibrated at three levels of air relative humidity (RHs 52, 73, and 92%). The four contrasting sorbents included an organic matter (OM)-rich peat soil, an OM-poor clay soil, a hydrophilic Aldrich humic acid salt, and water-insoluble leonardite. Monitoring phenol-water vapor interactions with the prehydrated sorbents, as compared with the sorbent samples in phenol-free atmosphere at the same RH, showed, for the first time, a sigmoid kinetics of phenol-induced mass uptake typical for second-order autocatalytic reactions. The apparent rate constants were similar for all the sorbents, RHs and phenol activities studied. A significant part of sorbed phenol resisted extraction, which was attributed to its abiotic oxidative coupling. Phenol uptake by peat and clay soils was also associated with a significant enhancement of water retention. The delayed development of the sigmoidal kinetics in phenol-water uptake demonstrates that long-run abiotic interactions of water-organic vapor with soil may be overlooked, based on short-term examination.