Maria Bardosova

Synthetic opals made by the Langmuir–Blodgett method

Monodispersive synthetic opal particles were formed by the method of Stober et al. [J. Colloid Interface Sci. 26 (1968) 62] and were made hydrophobic by reacting them with 3-(trimethoxysilyl)propyl methacrylate. Groups of particles were dissolved in chloroform and were spread at the air/water interface using a Nima trough. Each group studied consisted of particles, which had almost identical diameters. Isotherms were obtained and these are illustrated. The use of an optimum value of surface pressure and a high level of hydrophobicity made it possible to deposit good quality multilayers by the Langmuir–Blodgett method but we found that the Langmuir–Schaefer method was easier to use for less hydrophobic particles. The layers obtained were studied by scanning electron microscopy and we present the images obtained from these results.

Erasing diffraction orders: Opal versus Langmuir-Blodgett colloidal crystals

The optical transmission of photonic crystals self-assembled from colloidal nanospheres in opals and assembled from two-dimensional colloidal crystals in a periodic stack by the Langmuir-Blodgett technique has been compared. Elimination of all related zero order diffraction resonances other than that from growth planes and broadening and deepening of the remaining one-dimensional diffraction resonance have been observed for samples prepared by the Langmuir-Blodgett approach, which are explained in terms of the partial disorder of a crystal lattice.The optical transmission of photonic crystals self-assembled from colloidal nanospheres in opals and assembled from two-dimensional colloidal crystals in a periodic stack by the Langmuir-Blodgett technique has been compared. Elimination of all related zero order diffraction resonances other than that from growth planes and broadening and deepening of the remaining one-dimensional diffraction resonance have been observed for samples prepared by the Langmuir-Blodgett approach, which are explained in terms of the partial disorder of a crystal lattice.

(2+1)-dimensional photonic crystals from Langmuir-Blodgett colloidal multilayers

Angle-resolved transmission spectra of multilayers of two-dimensional colloidal crystals prepared by the Langmuir-Blodgett technique have been studied. In contrast to the light diffraction in three-dimensional colloidal crystals, optical spectra revealed only very weak correlation between layers in the Langmuir-Blodgett multilayers. Two reasons for the observed transmission minima have been identified: the diffraction at a stack of layers and the scattering of the incident beam by guided modes of the two-dimensional colloidal crystals.

Enhanced Bragg reflections from size-matched heterostructure photonic crystal thin films prepared by the Langmuir-Blodgett method

The Langmuir-Blodgett method was used to engineer photonic crystal thin films of an AB architecture. Structures were studied by transmittance and reflectance spectroscopies. For an AB structure in which the silica particle diameter B is twice that of A, reflectance features associated with the first order Bragg peak for the “A” domain are only observed when the structure is probed from the A side of the structure. Furthermore, this feature is enhanced in intensity compared to that for a structure consisting solely of A particles. These findings are attributed to a matching of first and second order Bragg processes.

Understanding of transmission in the range of high-order photonic bands in thin opal film

Diffraction in the face centered cubic lattice cannot explain some minima observed in the transmission spectra of self-assembled opal films. Here, we compared them with minima observed in the transmission spectra of a hexagonal close packed monolayer of spheres of the same diameter. The identity of the sphere packing on the surface of the opal film and in the sphere monolayer was demonstrated by the light diffraction at the sample surfaces. It was shown that excitation of surface propagating modes in the opal film is responsible for the formation of additional minima in opal film transmission.

Ordered layers of monodispersive colloids

We discuss both organic and inorganic monodispersive colloids having diameters of the order of a few hundred nm. The use of emulsion polymerisation and the Stober technique to produce organic and inorganic particles respectively is described. The application of ordered layers of such particles in photonics is discussed with particular reference to obtaining a photonic bandgap and the theoretical treatments of this question are briefly reviewed. There follows a review of the principal methods which have been employed to form good ordered multilayers of these materials. The so called inverted structures made by filling the interstices of these multilayers with another compound and then etching out the original particles are described. The results of some of the more important optical studies of both original multilayers and inverted multilayers are given.

Langmuir-Blodgett assembly of colloidal photonic crystals using silica particles prepared without the use of surfactant molecules.

This short communication reports the observation that in contrast to most previously reported procedures, it is possible to prepare 3D photonic crystal structures from silica particles that have not been deliberately treated with surfactant molecules, using the Langmuir-Blodgett method. We find that colloidal particles prepared simply via the Stöber method with diameters in the range 180-360 nm and dispersed in ethanol, may be effectively floated at the air/water interface and compressed into close packed layers prior to depositing the layers on a substrate. We also find, by comparing structures made with both particles treated with the surfactants 3-(trimethoxysilyl) propyl methacrylate or (3-aminopropyl)triethoxysilane and particles which have not been treated with any surfactant species, that the position of the Bragg peak and the reflectivity of the sample does not appear to be influenced by the presence of the surfactant molecules.

A facile method for the synthesis of highly monodisperse silica@gold@silica core–shell–shell particles and their use in the fabrication of three-dimensional metallodielectric photonic crystals

We report here (i) a method for the synthesis of highly monodisperse silica@gold@silica core–shell–shell (CSS) particles (<6% deviation in size) with coherent outer silica shells of directly tunable thickness and porosity, (ii) the fabrication of three unit cell thick (12 layers) metallodielectric photonic crystals (MDPCs) from these particles and (iii) their angle-resolved optical reflectance properties demonstrating the influence of dielectric contrast modification and metal plasmonic modes on photonic band gap properties. The synthetic route presented describes the use of two alkylamines, the first, 1,3-diaminopropane (DAP), as a surface manipulating agent, and the second, N,N-dimethyldodecylamine (DMDDA), as a catalyst for the outer silica shell formation, for the reproducible synthesis of monodisperse CSS particles avoiding the formation of the unwanted side-products such as core-free silica particles and aggregated particles with multiple cores. A rational chemical reaction mechanism describing the pathways involved in the formation of coherent silica shells, demonstrating the roles of both the amines, is proposed. The creation of partial wetting/de-wetting sites on gold nanoparticle surfaces by the adsorbed DAP molecules, the surface silanol modification by DAP and the slow hydrolysis–condensation reactions catalyzed by DMDDA are found to be responsible for the selective deposition of silica (heterogeneous nucleation) only onto the existing silica@gold core–shell particles leading to the formation of monodisperse CSS particles. The optical reflectance of the MDPC formed from these CSS particles shows an angle-dependent blue-shift that perfectly obeys the Bragg–Snell law predictions for photonic crystals. The dielectric contrast modification and the possible metal plasmonic mode-coupling in the MDPC also result in a high gap-to-midgap ratio (23%) as compared to the PC made of neat silica particles of comparable size (9%).

Using network science and text analytics to produce surveys in a scientific topic

The use of science to understand its own structure is becoming popular, but understanding the organization of knowledge areas is still limited because some patterns are only discoverable with proper computational treatment of large-scale datasets. In this paper, we introduce a framework to combine network-based methodologies and text analytics to construct the taxonomy of science fields. The methodology is illustrated with application to two topics: complex networks (CN) and photonic crystals (PC). We built citation networks using data from the Web of Science and used a community detection algorithm for partitioning to obtain science maps for the two topics. We also created an importance index for text analytics, which is employed to extract keywords that define the communities and, combined with network topology metrics, to generate dendrograms of relatedness among subtopics. Interesting patterns emerging from the analysis included identification of two well-defined communities in PC area, which is consistent with the known existence of two distinct communities of researchers in the area: telecommunication engineers and physicists. With the methodology, it was also possible to assess the interdisciplinary nature and time evolution of subtopics defined by the keywords. The automatic tools described here are potentially useful not only to provide an overview of scientific areas but also to assist scientists in performing systematic research on a specific topic.

Large Area 2D and 3D Colloidal Photonic Crystals Fabricated by a Roll-to-Roll Langmuir–Blodgett Method

We present our results on the fabrication of large area colloidal photonic crystals on flexible poly(ethylene terephthalate) (PET) film using a roll-to-roll Langmuir-Blodgett technique. Two-dimensional (2D) and three-dimensional (3D) colloidal photonic crystals from silica nanospheres (250 and 550 nm diameter) with a total area of up to 340 cm(2) have been fabricated in a continuous manner compatible with high volume manufacturing. In addition, the antireflective properties and structural integrity of the films have been enhanced via the use of a second roll-to-roll process, employing a slot-die coating of an optical adhesive over the photonic crystal films. Scanning electron microscopy images, atomic force microscopy images, and UV-vis optical transmission and reflection spectra of the fabricated photonic crystals are analyzed. This analysis confirms the high quality of the 2D and 3D photonic crystals fabricated by the roll-to-roll LB technique. Potential device applications of the large area 2D and 3D colloidal photonic crystals on flexible PET film are briefly reviewed.