María-Cruz Navarrete

In situ salinity measurements in seawater with a fibre-optic probe

We have successfully proved the feasibility of an optical salinity meter for marine applications in a two-week measurement campaign, carried out for the realization of in situ salinity measurements in seawater. An optical instrument (optode), in which the main element is a fibre-optic refractive-index sensor based on surface plasmon resonance (SPR), has been developed for that purpose, and has been especially designed to be able to operate in realistic conditions. The performance of the optode has been evaluated on an oceanographic ship in the Baltic Sea, close to the Vistula estuarine area. The obtained results (in different tests, such as depth-profiling, towing and stationary measurements) show good correlation with the data provided by a commercial probe. Although the device is currently a part of a more complex measuring platform and uses an axial spectrograph as detector, the output power measurement used and the simplicity of its conception allow us to conceive a closed, extremely compact set-up which can be in principle commercially competitive with existing sensors.

Surface plasmon resonance sensors based on uniform-waist tapered fibers in a reflective configuration

We present a configuration for surface plasmon resonance sensors based on uniform-waist tapered optical fibers and reflective elements. Once the fiber is tapered fulfilling the adiabatic criterion, a multilayer including a metallic medium is asymmetrically deposited on the uniform waist of the fiber. This feature provides the resonant excitation of multiple surface plasma waves. In addition, a mirror is produced at the fiber tip by a chemical Tollens reaction. In this way, the sensor operates in a reflective mode, more convenient for dip probes. When these sensors are spectrally interrogated, a high sensitivity of 10-4 refractive index units per nanometer is attained. These devices can be advantageously used for any kind of chemical sensing and biosensing.

Sensing properties of asymmetric double-layer-covered tapered fibers.

A novel, to our knowledge, device based on a tapered optical fiber with a double-layer deposition including a metallic media is presented, and its properties are studied. The main novelty of the device consists of the introduction of a dielectric layer, whereas the systems depicted in the literature are simply metal-coated tapered fibers. The presence of the dielectric layer permits one to tune the response of the device to the refractive index of the surrounding medium. We have proved the suitability of this scheme for refractive-index sensing by depicting two measurement modes, namely, total power attenuation and spectral transmittance.

Multiple surface-plasmon resonance in uniform-waist tapered optical fibers with an asymmetric double-layer deposition

Novel devices consisting of uniform-waist tapered optical fibers with asymmetric double-layer (metal plus dielectric) depositions have been recently proposed as refractive-index sensors. We study the properties of light transmission by use of this kind of devices, and we specifically perform a detailed study of the generation of surface-plasma waves in the structures. We show that multiple surface plasmons are excited for specific combinations of the constructive parameters of the devices and for specific ranges of the refractive index of the surrounding medium. The behavior also depends on the wavelength and the state of polarization of the incident light. The use of uniform-waist tapers allows for control of constructive parameters and an increase in the interaction length with the outer medium. We show how the plasmons are excited in the region of the taper waist by a coupling with the cladding modes guided in that area. This characterization shows the importance of the presence of a dielectric layer for selection of the operating range of the device. The results are useful for the design of new sensors.

A fibre-optic temperature sensor based on the deposition of a thermochromic material on an adiabatic taper

A fibre-optic sensor has been developed for the measurement of temperature, especially of liquids. The device is conceived as part of an all-optical CTD probe for the control of the physical parameters of a marine medium. The dependence on temperature of the optical properties (specifically, absorbance) of a thermochromic material, namely lophine (2,4,5-triphenylimidazole), is the basis of the sensor. The sensor presents some significant differences with respect to other similar sensors proposed in the literature: the use of adiabatic, long, tapered optical fibres with adjustable geometric parameters; the use of LED illumination in the 800?nm range; improvements in the deposition technique, etc. The sensors show a linear behaviour over the desired temperature range, and their sensitivity is high. Also, the dependence of the response of the sensor with variations of the geometry of the tapers is discussed. Specifically, we have performed measurements with different diameters of the taper waist, and we show the dependence of the slope of the response curve with that parameter.

Plasmonic Sensors Based on Doubly-Deposited Tapered Optical Fibers

A review of the surface plasmon resonance (SPR) transducers based on tapered fibers that have been developed in the last years is presented. The devices have proved their good performance (specifically, in terms of sensitivity) and their versatility and they are a very good option to be considered as basis for any kind of chemical and biological sensor. The technology has now reached its maturity and here we summarize some of the characteristics of the devices produced.

Absorption as a selective mechanism in surface plasmon resonance fiber optic sensors.

A new concept of surface plasmon resonance fiber optic sensor is presented. By tuning the plasmon resonance to a wavelength for which the outer medium is absorptive, a significant variation of the spectral transmittance of the device is produced as a function of the concentration of the analyte. With this mechanism, selectivity can be achieved without the need of any functionalization of the surfaces or the use of recognizing elements, which is a very interesting feature for any kind of chemical sensor or biosensor. Doubly deposited uniform-waist tapered fibers are well suited for the development of these new sensors. Multiple surface plasmon resonance, obtainable in those structures, can be used for the development of microspectrometers based on this principle.

Moving the wavelength detection range in surface plasmon resonance sensors based on tapered optical fibers

It is shown how the design possibilities offered by double-layer uniform-waist tapered optical fibers (DLUWTs) permit to move the wavelength detection range to adapt the response of the sensors to varied conditions. In particular, we have obtained very good experimental curves showing that we can achieve plasmon resonances in the C-band of the optical communications, around 1.5 μm, for the range of refractive indices of aqueous media, highly interesting in the biosensors field. Also, we show results for other interesting wavelength region, around 500 nm, where we can take advantage of the absorption peaks of the analytes. Finally, we explore the possibilities of using InN as a dielectric material for the second layer of the deposition. These results contribute to considerably expand the applicability and performance of SPR fiber sensors.

DL-UWTs: novel devices for chemical and biological sensing

Although many optical fiber sensors have been proposed for chemical, environmental or biological measurements, it seems that the potential of this kind of devices has not been fully exploited. In this paper we discuss the possibilities of doubly-deposited uniform-waist tapered fibers (DL-UWTs) for the development of new sensors that can become a new standard in the field of Surface Plasmon Resonance (SPR) based sensors and contribute to the extension of the range of application of fiber technology to the mentioned fields. We also compare different configuration and evaluate some relevant features of DL-UWTs, as the possibility of fully independence of polarization or the excitation of multiple plasmons.

Theoretical method for the study of plasmon generation in hybrid multilayer-optical fiber structures

A theoretical method is presented for the determination of the behavior of devices based on the deposition of multilayer structures on polished optical fibers. Plasmon generation in metallic layers is modeled. The method is based on the Rayleigh expansion of the electric fields and permits us to determine their distribution over the whole structure by an application of boundary conditions. Once the distribution is known, the power transmitted by the fiber can be computed as a function of the geometrical and refractive parameters of the device. The method is versatile and can be used as a theoretical tool for the design of devices of that type used for many different purposes. We present real experimental results obtained with an operative sensor that agree with the theoretical predictions of our technique and prove its suitability.