Maria E. Nadal

Optical Reflectance of Metallic Coatings: Effect of Aluminum Flake Orientation

A set of aluminum-flake pigmented coatings having different flake orientations was prepared using various spraying conditions. The flake surface topography and the orientations of individual flakes were determined from images obtained by laser scanning confocal microscopy. Reflectance measurements were carried out to quantify the optical properties of the coatings. Both a Gaussian distribution (used to represent the measured flake orientation distribution) and a topographic map (including local surface roughness and orientation) of the flakes were then used as input to a ray scattering model to calculate the optical reflectance of each coatings Flake orientation distributions and examples of measured optical reflectance as a function of scattering angle are shown, and the latter are compared to calculated reflectance values.

NIST reference goniophotometer for specular gloss measurements

The measurement of specular gloss consists of comparing the luminous reflectance from a test specimen to that from a gloss standard, under the same geometric conditions. The reference goniophotometer described here was designed and characterized to comply with the geometric and spectral conditions specified in the international documentary standards for specular gloss measurements at the standard geometries of 20, 60, and 85°. In addition, this instrument measures the bi-directional luminous reflectance and transmittance for incident angles from 0 to 85°. The goniophotometer and the measurement procedures used to determine the specular gloss of nonmetallic samples are described in this paper, as well as the characterization of the instrument and uncertainty analysis. The minimum relative expanded uncertainty (k=2) for the reference goniophotometer is 0.3%.

New primary standard for specular gloss measurements

A new primary specular gloss standard has been developed at the National Institute of Standards and Technology to overcome the disadvantages of black glass. This new standard is a high-purity BaK50 glass with good mechanical durability and homogeneity. In addition, the index of refraction nD=1.5677 is close to the value specified for the theoretical standard, and the dispersion characteristics are similar to black glass.

Measurements and predictions of light scattering by clear coatings

Comparisons are made between calculated and measured angle-resolved light-scattering distributions from clear dielectric isotropic epoxy coatings over a range of rms roughness conditions, resulting in strongly specular scattering to diffuse scattering characteristics. Calculated distributions are derived from topography measurements performed with interferometric microscopes. Two methods of calculation are used. One determines the intensity of scattered light waves with a phase integral in the Kirchhoff approximation. The other is based on the reflection of light rays by locally flat surfaces. The angle-resolved scattering distributions for the coatings are measured with the spectral trifunction automated reference reflectometer (STARR) developed by the National Institute of Standards and Technology. Comparisons between measured and calculated results are shown for three surfaces with rms roughness values of approximately 3, 150, and 800 nm for an angle of incidence of 20 degrees .

New NIST reference goniospectrometer

Coatings can be classified by either their appearance, such as glitter, or by their function, such as corrosion protection. However, pigments are currently being manufactured with new and unique appearance attributes that can not be characterized by traditional methods. These coatings may exhibit differences in their perceived color with changes in the illumination or viewing angle, or both. Properties such as these have become rudimentary in the production of currency, cosmetics, and retroreflective materials. The primary impetus of goniospectrometry at NIST is to develop accurate measurement protocols for reproduction and quality control of appearance attributes, such as color matching, by determining the minimum set of illumination and viewing geometries needed to accurately characterize the perceived color. Here, we present a new goniospectrometer developed at NIST that allows the measurement of the complete bi-directional reflectance distribution function (BRDF) for colored surfaces with the objective of differentiating between the scattering mechanisms in the coating. The illumination is provided by a monochromator with a spectral resolution of 0.05 nm between 360 nm and 780 nm. The sample can be moved about 3 different axes, allowing illumination and viewing for any direction within the hemisphere about the sample, including grazing angles, with accuracy better than 0.01° for each axis. This equipment will become the future provider of standard BRDF measurements at NIST, for the characterization of complex surfaces like gonioapparent coatings or retroflective surfaces.

Modeling the appearance of special effect pigment coatings

Metallic and pearlescent coatings are becoming increasingly important in automotive, currency, and cosmetic applications. These coatings consist of metallic or dielectric platelets suspended in a binder, and are often applied between a pigmented basecoat, and a transparent topcoat. The scattering properties of these composite coatings vary depending upon the incident and viewing directions, as well as the wavelength. The complex nature of the scattering arises from the competition between multiple scattering sources: front surface reflection from the topcoat, reflection from the platelets, diffuse scattering from the pigmented undercoat, and scattering between platelets. The complex interplay between multiple scattering sources affects the ability to achieve quality control during the preparation of these coatings. In addition, the topcoat surface morphology, the properties of the pigmented basecoat, and the intrinsic properties, concentration, and angular distribution of the platelets influence the final appearance of the coating. In this paper, we will present models for light scattering from front surface facet reflection, subsurface flake reflection, and diffuse subsurface scattering. Experimental scattering measurements on pearlescent coatings show that the polarization can be well described in different geometry regimes by these different scattering sources. The models can be used to extract the slope distribution function of the flakes from the intensity data, but some aspects of the results behave inconsistently. Comparison is also made between experimental and calculated diffuse reflectance spectra. These results are intended to enable improved characterization of special effect coatings necessary for quality control and appearance modeling applications.

2007 Topical Meeting on Optical Interference Coatings:Manufacturing Problem

Measurements are described on the experimental filters submitted to the Third Optical Thin Film Manufacturing Problem in which the object was to produce multilayers with a measured colorimetric performance that is as close as possible to that specified. The perceived colors of the coating, when illuminated with randomly polarized light incident at 7 degrees by a source representing average daylight with a correlated color temperature of approximately 6500 K, were to be yellow and blue, respectively, in light reflected from its two surfaces, and the color was to appear white when viewed in transmission mode. Eleven teams from 7 different countries submitted a total of 18 samples.

Topical Meeting on Optical Interference Coatings (OIC’2001): manufacturing problem

Measurements are presented of the experimental filters submitted to the first optical thin-film manufacturing problem posed in conjunction with the Topical Meeting on Optical Interference Coatings, in which the object was to produce multilayers with spectral transmittance and reflectance curves that were as close as possible to the target values that were specified in the 400- to 600-nm spectral region. No limit was set on the overall thickness of the solutions or the number of layers used in their construction. The participants were free to use the coating materials of their choice. Six different groups submitted a total of 11 different filters for evaluation. Three different physical vapor deposition processes were used for the manufacture of the coatings: magnetron sputtering, ion-beam sputtering, and plasma-ion-assisted, electron-beam gun evaporation. The solutions ranged in metric thickness from 758 to 4226 nm and consisted of between 8 and 27 layers. For all but two of the samples submitted, the average rms departure of the measured transmittances and reflectances from the target values in the spectral region of interest was between 0.98% and 1.55%.

Colorimetric characterization of pearlescent coatings

This paper describes recent developments at the National Institution of Standards and Technology in the colorimetric characterization of pearlescent coatings. The goal of this research is to develop a measurement protocol for the accurate color characterization of these coatings using an understanding of their scattering mechanism as a guide. The bi-directional reflectance of a series of samples has been measured for the visible region at incident angle of 15°, 25°, 45°, 65°, and 75° and viewing angles of +/- 80° at 5° steps. This large ensemble of measurements show general trends in the color variations with incident and viewing angles that are being used to define a preliminary subset of measuring geometries that will provide sufficient information to characterize the angle dependent color travel in pearlescent coatings.

2004 Optical Society of America's Topical Meeting on Optical Interference Coatings: manufacturing problem

Results are presented for the second Optical Society of Americas Optical Interference Coatings Manufacturing Problem. The participants were asked to produce multilayer coatings which, in the 450-650 nm spectral region and for light incident at 60 degrees, would have transmittances of 0.7 and 0.3 for p- and s-polarized light, respectively. Three different teams each submitted four solutions. Three different deposition processes were used to produce these coatings. The smallest average departure from the target transmission values was 0.79%. A number of interesting conclusions can be drawn from this exercise.