Maria Geraga

The geological links of the ancient Delphic Oracle (Greece): A reappraisal of natural gas occurrence and origin

Recent studies have speculated that the prophetic powers of Pythia, the woman of the Delphic Oracle, at the Temple of Apollo in Greece, were induced by hydrocarbon vapors, specifically ethylene, rising from bedrock fissures at the intersection of the E-W Delphi fault with the NNW-SSE Kerna fault, and producing neurotoxic effects, including trance and delirium. New surveys including gas flux from soil, gas in groundwater, and isotopic analyses of spring scales, provide the experimental confirmation of the gas release in the Delphi area. Presently, methane, ethane, and carbon dioxide are being released from a thermogenic (catagenetic) hydrocarbon-prone environment. This environment is not prone to biogenic production of ethylene in amounts inducing neurotoxic effects (hundreds or thousands of ppmv). A WNW-ESE–trending subsidiary fault within the Delphi fault zone, extending for ∼2 km, passes under the Temple of Apollo and shrine of Athena. The Temple of Apollo, located above this fault, may have been the site of enhanced degassing in the past. If gas-linked neurotoxic effects upon Pythia need to be invoked, they should be sought in the possibility of oxygen depletion due to CO2-CH4 exhalation in the indoor temple. Alternatively, a plausible geological explanation behind the natural presence of sweet scents could be the occurrence of aromatic hydrocarbons, such as benzene, dissolved in the groundwater spring.

Illegal trawling and induced invasive algal spread as collaborative factors in a Posidonia oceanica meadow degradation

Posidonia oceanica, a key seagrass species of the Mediterranean Sea, shows clear signs of regression throughout the Mediterranean and illegal trawling is recognized as one of the main causes. We examined the condition of a P. oceanica meadow in Alykes Bay (Zakynthos Island, western Greece), a typical Mediterranean littoral area where illegal trawling is common practice, in respect to the total area affected, and in terms of possible ecological substitution. A side scan sonar (SSS) survey of the seafloor provided an image of the condition of the meadow and biological sampling evaluated the ecological status in affected meadow areas. SSS images revealed that trawling has a serious effect on the meadow, with 11% of the vegetated area being abraded, and the affected areas were also found to be fully colonized by the invasive alga Caulerpa racemosa. Moreover, unusually high densities of the polychaete Sabella pavonina were detected in the affected areas among C. racemosa fronds. Recolonization by P. oceanica of the affected meadow areas that have been colonized by C. racemosa seems improbable considering the allelopathic interactions between the species, with the alga displaying phytotoxic properties through caulerpenyne production and deterioration of the sediment quality.

An Automatic Target Detection Algorithm for Swath Sonar Backscatter Imagery, Using Image Texture and Independent Component Analysis

In the present paper, a methodological scheme, bringing together common Acoustic Seabed Classification (ASC) systems and a powerful data decomposition approach, called Independent Component Analysis (ICA), is demonstrated regarding its suitability for detecting small targets in Side Scan Sonar imagery. Traditional ASC systems extract numerous texture descriptors, leading to a large feature vector, the dimensionality of which is reduced by means of data decomposition techniques, usually Principal Component Analysis (PCA), prior to classification. However, in the target detection issue, data decomposition should point towards finding components that represent sub-ordinary image information (i.e., small targets) rather than a dominant one. ICA has long been proved to be suitable for separating targets from a background, and this study represents a novel exhibition of its applicability to Side Scan Sonar (SSS) images. The present study attempts to build a fully automated target detection approach that combines image based feature extraction, ICA, and unsupervised classification. The suitability of the proposed approach has been demonstrated using an SSS data-set containing more than 70 manmade targets, most of them metallic, validated through a marine magnetic survey or ground truthing inspection. The method exhibited very good performance as it was able to detect more than 77% of the targets and it produced less than seven false alarms per km2. Moreover, it was compared to cases where, in the exact same methodological scheme, no decomposition technique is used, or PCA is employed instead of ICA, achieving the highest detection rate, but, more importantly, producing more than six times less false alarms, thus proving that ICA successfully manages to maximize target to background separation.

Seasonal and spatial variations of water quality, substrate and aquatic macrophytes based on side scan sonar, in an eastern Mediterranean lagoon (Kaiafas, Ionian Sea)

Temporal and spatial variations of environmental and water quality parameters and their relations with macrobenthic flora were investigated in an eastern Mediterranean lagoon. Kaiafas is a mesohaline lagoon, which is influenced by point and diffused sources from the adjacent agricultural land and the nearby city. Water samples were analyzed for physicochemical parameters, microbial load and primary production, on a seasonal and spatial scale, while heavy metal concentrations were measured into two different sediment cores. An overall analysis of seasonal dynamics of water parameters and Chl-a based on trophic index TSI pointed out the lagoon as eutrophic. According to water quality parameters the lagoon was separated into two parts. The southern sector of the lagoon which was more affected by human activities showed higher nutrients, Chl-a, heavy metals and total Coliforms concentrations. Sediment texture and distribution of macrophytes were detected through the acoustic side scan sonar method, which proved to be a promising tool for defining and monitoring vegetation coverage of shallow lagoons. A number of distinct echo types and three different sediment types were revealed on the basis of the backscatter level and the variability of low and high backscatter areas. Furthermore, the extension and the coverage of Potamogeton pectinatus and Chara hispida f. corfuensis were successively depicted by combining the data of SSS and ground truthing samples. Meadows of P. pectinatus were established to the lagoon limits where high turbidity and silty substrate occurred, while C. hispida f. corfuensis was limited in deep and high transparent waters with sandy substrate.

Litter composition and source contribution for 80 beaches in Greece, Eastern Mediterranean: A nationwide voluntary clean-up campaign

Litter that accumulates in the marine environment is recognized as a global environmental problem with numerous adverse effects. Despite Greece having more than 16,000 km of coastline, studies on litter composition and sources on its beaches are scarce and fragmentary. Therefore, this study aimed to quantify beach-stranded litter by type of material (plastic, glass, paper, aluminum, other metals, building materials, rope) on 80 Greek beaches, and to explore the relationships between different litter materials and marine- and land-based sources. Field work and data collection were accomplished with the participation of 10,938 and 15,748 volunteers in 2006 and 2007, respectively, and were integrated in the nationwide campaign of voluntary beach clean-ups: “Clean up the Med.” The participation of thousands of volunteers of different ages and social backgrounds in the data collection process not only led to the realization of a national level survey, but also played a significant role in raising public awareness on marine environmental issues, and in promoting a sense of responsibility in protecting marine resources. Plastic was the most abundant litter material found on the surveyed beaches (43–51%), followed by paper (13–18%) and aluminum (7–12%). Onshore and nearshore recreational activities, such as bathing and recreational boating, appeared to be the most dominant litter sources, as they affect the majority (56) of the surveyed beaches, suggesting that environmental education and awareness could reduce the beach-litter pollution problem. Navigation seemed to be the dominant source of marine-based litter, affecting more than half (46) of the surveyed beaches.

Holocene Climatic Optimum centennial-scale paleoceanography in the NE Aegean (Mediterranean Sea)

Combined micropaleontological and geochemical analyses of the high-sedimentation gravity core M-4G provided new centennial-scale paleoceanographic data for sapropel S1 deposition in the NE Aegean Sea during the Holocene Climatic Optimum. Sapropel layer S1a (10.2–8.0 ka) was deposited in dysoxic to oxic bottom waters characterized by a high abundance of benthic foraminiferal species tolerating surface sediment and/or pore water oxygen depletion (e.g., Chilostomella mediterranensis, Globobulimina affinis), and the presence of Uvigerina mediterranea, which thrives in oxic mesotrophic-eutrophic environments. Preservation of organic matter (OM) is inferred based on high organic carbon as well as loliolide and isololiolide contents, while the biomarker record and the abundances of eutrophic planktonic foraminifera document enhanced productivity. High inputs of terrigenous OM are attributed to north Aegean borderland riverine inputs. Both alkenone-based sea surface temperatures (SSTs) and δO18G. bulloides records indicate cooling at 8.2 ka (S1a) and ~7.8 ka (S1 interruption). Sapropelic layer S1b (7.7–6.4 ka) is characterized by rather oxic conditions; abundances of foraminiferal species tolerant to oxygen depletion are very low compared with the U. mediterranea rise. Strongly fluctuating SSTs demonstrate repeated cooling and associated dense water formation, with a major event at 7.4 ka followed by cold spells at 7.0, 6.8, and 6.5 ka. The prominent rise of the carbon preference index within the S1b layer indicates the delivery of less degraded terrestrial OM. The increase of algal biomarkers, labile OM-feeding foraminifera and eutrophic planktonic species pinpoints an enhanced in situ marine productivity, promoted by more efficient vertical convection due to repeated cold events. The associated contributions of labile marine OM along with fresher terrestrial OM inputs after ~7.7 ka imply sources alternative/additional to the north Aegean riverine borderland sources for the influx of organic matter in the south Limnos Basin, plausibly related to the inflow of highly productive Marmara/Black Sea waters.

Uranium and other natural radionuclides in the sediments of a Mediterranean fjord-like embayment, Amvrakikos Gulf (Ionian Sea), Greece.

The distribution of the natural radionuclides ((238)U, (232)Th, (226)Ra, (40)K) and the artificial (137)Cs was studied in sediment cores collected from Amvrakikos Gulf, a seasonal anoxic marine basin, using γ-ray spectrometry. The activity of radionuclides, along with the concentrations of Fe and Mn, were also studied in relation to the total organic carbon and the granulometric fractions of the sediments. The results obtained revealed higher (238)U activity concentrations in all the examined sediment samples compared to the world and Greek average values for soil. The high activity values of (238)U are attributed, besides the lattice-held fraction, to phosphate fertilizer inputs in the Gulf via major rivers and/or to alteration processes of phosphate ores located mainly in the drainage basin of the river Louros. The elevated activity values of (40)K could be attributed to the mineralogical composition of the sediments and to phosphate fertilizers containing potassium. Organic matter seems to be a more efficient sorbent for U than clay minerals and amorphous Fe and Mn-oxyhydroxides. Scanning electron microscopy, together with qualitative analysis of some smectites, reveals the occurrence of U, suggesting a limited absorption of U onto clay minerals. The applied BCR sequential extraction procedure revealed that U was found mainly in the refractory phase or associated with organic matter and to a lesser extent as surface-coating oxides, with the exception of one sediment core which is characterized by high content of fresh marine organic matter and presents high percentage of U in the exchangeable fraction.

The Disappearance of Helike-Classical Greece—New Remote Sensing and Geological Evidence

Helike, the Achaean Dodecapolis capital, in the Corinth Gulf, Greece, was, according to historical sources, devastated and disappeared from sight during an earthquake followed by sea invasion on to land in 373/372 B.C. A marine remote sensing survey, which was carried out to examine a landslide following a 6.2 R earthquake in 1995, that affected the coastal and near-shore delta plain zone on which Helike stood, accompanied by onshore borehole data, enabled us to postulate the geological processes leading to the Helike catastrophe. Helike was initially leveled during a 6 to 6.7 R earthquake; it is postulated to have then submerged following a translational landslide caused by liquefaction. This Helike catastrophe model is consistent with historical sources and current views regarding the expected geological hazards magnitude in the Gulf.

Radionuclide activities and elemental concentrations in sediments from a polluted marine environment (Saronikos Gulf-Greece)

The levels and depth distributions of the natural radionuclides 238U, 232Th, 226Ra, 40K and the man-made 137Cs were analyzed by γ-ray spectrometry, while the concentrations of 26 chemical elements were measured by INAA in sediment samples collected from the organic mud layer that covers the Keratsini–Psitalia strait, Saronikos gulf (Greece). The average activity concentration values of 226Ra, 232Th and 40K were lower when compared, whereas that of 238U was comparable to the average Greek and world values. The elemental contamination of the sediments was estimated on the basis of the calculated EF values. The results revealed high EF values of As, Br, Cr, Ni, Sb, Se, Zn ranging from 160 for Br to 10 for Cr, whose main sources are probable related to contaminated sewage outfall from the area of Athens and the Piraeus Harbour.