Maria Luisa Grilli

Optical parameters of oxide films typically used in optical coating production

Wavelength dependencies of refractive indices of thin film materials differ for various deposition conditions, and it is practically impossible to attribute a single refractive index wavelength dependence to any typical thin film material. Besides objective reasons, differences in the optical parameters of thin films may also be connected with nonadequate choices of models and algorithms used for the processing of measurement data. The main goal of this paper is to present reliable wavelength dependencies of refractive indices of the most widely used slightly absorbing oxide thin film materials. These dependencies can be used by other researchers for comparison and verification of their own characterization results.

Radio frequency sputtered Al:ZnO-Ag transparent conductor: A plasmonic nanostructure with enhanced optical and electrical properties

Optimization of metal-based transparent conductors (MTCs) made of silver and aluminium-doped zinc oxide (AZO) prepared by radio-frequency (r.f.) sputtering has been carried out through tuning of metal film properties. The influence of morphology and related plasmonic features of AZO/Ag/AZO MTCs on their optical and electrical performance is demonstrated and it is shown that the nominal thickness of the silver layer itself is not the most crucial value determining the MTC performance. The MTC performance has been optimized by a search of deposition conditions ensuring fractal-type metal layer formation up to a certain coalescence state that enables full gaining from silver optical properties, including its plasmonic features. For 150 W- and 200 W-deposited silver, MTCs with maximum transmittance as high as 83.6% have been obtained. These coatings have a figure of merit as good as 0.01 Ω−1 and a remarkably wide spectral transparency region: transmittance higher than 70% down to 1200 nm for 200W-samples. Modelling of the MTC coatings is proposed additionally, based on variable angle spectroscopic ellipsometric measurements, which takes into account the variation of the optical properties of silver when deposited in various conditions and embedded in a semiconductor stack.

Behavior of optical thin-film materials and coatings under proton and gamma irradiation

Optical materials and coatings are exposed to the flux of energetic particles when used in either space applications or nuclear energy plants. The study of their behavior in such an environment is important to avoid failure of the optical components during their operation. The optical performance of several thin-film materials ((HfO2, Ta2O5, Nb2O5, TiO2, SiO2) and coatings, under irradiation with high-dose gamma rays (5.8 MGy) and exposure to low-energy (60 keV) protons, has been investigated. Some variations of optical properties have been detected in silicon oxide after irradiation, while the other materials are stable in such conditions.

The modification of the characteristics of nanocrystalline ZnO thin films by variation of Ta doping content

Abstract Thin films of Ta-doped ZnO were synthesised via sol–gel spin coating route. The structural and optical properties of the films were evaluated to find out the effect of Ta dopant content. X-ray diffraction results indicated that all samples have hexagonal wurtzite crystal structure with polycrystalline nature. (0 0 2) peak is the most intense peak observed in all samples as well as the highest textured coefficient. Standard deviation results have shown that the kind of nucleation varies from heterogeneous to homogenous with Ta doping content. Additionally, Ta-incorporated ZnO films revealed not only a decreased surface roughness, but also an increased optical transmittance. Direct optical band gap values increased from 3.14 to 3.28 eV, and Urbach energy values decreased from 217 to 147 meV with increasing Ta doping. Refractive index and dielectric constant values were determined by means of two different functions and a significant consistency was found among them. Moreover, the correlation between the optical and structural properties showed that there is a relationship between refractive index and lattice constants of Ta-doped ZnO films.

Solutions for critical raw materials under extreme conditions: A review

In Europe, many technologies with high socio-economic benefits face materials requirements that are often affected by demand-supply disruption. This paper offers an overview of critical raw materials in high value alloys and metal-matrix composites used in critical applications, such as energy, transportation and machinery manufacturing associated with extreme working conditions in terms of temperature, loading, friction, wear and corrosion. The goal is to provide perspectives about the reduction and/or substitution of selected critical raw materials: Co, W, Cr, Nb and Mg.

Optical performance of narrow-band transmittance filters under low-and high-energy proton irradiation

The behaviour of interference optical filters for space applications has been investigated under low- and high-energy proton irradiation. Low-energy protons are expected to be necessary to prove the effects on the coating, whereas the high-energy proton tests shall verify mainly the substrate susceptibility to induced damage. The expected interaction of protons with coating and substrate was simulated by software, to identify the most appropriate conditions for the irradiation experiments. Two different accelerator facilities were used for low- and high- energy protons: 60 keV protons with an integrated fluence of 1012 p+/cm2 and 30 MeV protons with an integrated fluence of 108 p+/cm2. The spectral transmittance of the filters was measured before and after irradiation and, according to simulations, no significant effects were detected in the visible-near infrared spectrum, while some variations appeared at short wavelengths with low-energy irradiation.

Interface plasmonic properties of silver coated by ultrathin metal oxides

Many fields of high technology take advantage of conductor-dielectric interface properties. Deeper knowledge of physical processes that determine the optical response of the structures containing metal-dielectric interfaces is important for improving the performance of thin film devices containing such materials. Here we present a study on optical properties of several ultrathin metal oxides deposited over thin silver layers. Some widely used materials (Al2O3, SiO2, Y2O3, HfO2) were selected for deposition by r.f. sputtering, and the created metal-dielectric structures with two of them, alumina and silica, were investigated in this work using attenuated total reflectance (ATR) technique and by variable-angle spectroscopic ellipsometry (VASE). VASE was performed with a help of a commercial ellipsometer at various incident angles and in a wide spectral range. A home-made sample holder manufactured for WVASE ellipsometer and operational in Otto configuration has been implemented for angle-resolved and spectral ATR measurements. Simultaneous analysis of data obtained by these two independent techniques allows elaboration of a representative model for plasmonic-related phenomena at metal-dielectric interface. The optical constants of the interface layers formed between metal and ultrathin oxide layers are investigated. A series of oxides chosen for this study allows a comparative analysis aimed for selection of the most appropriate materials for different applications.

Thermal conductivity of e-beam and IBS coatings

The development of coatings which show a good thermal conductivity plays an important role in the realization of new laser schemes like the Yb:YAG disk laser. We present results on investigations on the thermal conductivity of different thin film materials produced by conventional thermal evaporation and ion beam sputtering. With the optimized IBS-process high reflecting coatings are produced on the end faces of Yb:YAG disk lasers. A significant reduction of the thermal gradient in the laser disk was observed, which is an essential requirement for high power lasers besides the excellent optical quality of the coating.

Behavior of optical thin-film materials and coatings under proton irradiation

The behavior of optical coatings under low-energy proton irradiation (60 keV) has been investigated, The interaction of protons with coating and substrate was simulated by the SRIM code to understand the effects of proton irradiation.

Optical transmission filters for observation of lightning phenomena in the Earth atmosphere

Very narrowband transmission filters, as parts of an instrument for the study of lightning phenomena, are described. Their performance must be maintained at an incidence angle of ±5.5° and this condition poses some limitations on the minimum bandwidth of the order of a few nanometers. The fabrication of such coatings on large area substrates is quite challenging because of the required thickness accuracy. Moreover, their performance should be not influenced by the environmental conditions in space.