Maria Page Womack

A survey of N2H+ in dense clouds: Implications for interstellar nitrogen and ion-molecule chemistry

Spectra of the N 2 H + J=1→0, J=3→2 and 15 NNH + and N 15 NH + J=1→0 rotational transitions have been obtained toward a sample of star-forming and cold dark clouds in the Galaxy. Toward the star-forming regions, line profiles are relatively narrow (typically 1-5 km/s) and show no evidence of line wings, in contrast to the spectra of HCO + . The apparent absence of N 2 H + in hot, shocked gas suggests that this ion may be a selective tracer of extended, quiescent material

Formaldehyde in Comets C/1995 O1 (Hale-Bopp), C/2002 T7 (LINEAR), and C/2001 Q4 (NEAT): Investigating the Cometary Origin of H2CO

Observations offormaldehyde (H2CO) have been conducted toward comets C/1995 O1 (Hale-Bopp), C/2001 Q4 (NEAT), and C/2002 T7 (LINEAR) using the Arizona Radio Observatory (ARO) 12 m telescope at 1.2 and 2 mm. Aperture synthesis maps of H2CO at 3 mm were made using the Berkeley-Illinois-Maryland Association (BIMA) interferometer toward comet Hale-Bopp. These data indicate that the production rate of H2CO is � 3:7 ; 10 28 s � 1 at � 1 AU in comet Hale-Bopp, using a simple Monte Carlo model, if a nuclear origin for the molecule is assumed. However, maps of H2CO in Hale-Bopp, in comparison with CO, show an extended distribution (rs � 15,000 km) with small-scale structure oriented roughly along the comet-Sun direction. This result suggests a source of H2CO other than the comet nucleus. The extended source of formaldehyde is probably grains composed of a mixture of silicates and organicmaterial.Theproductionrate forH2CO increasestoQ � 1:4 ; 10 29 s � 1 assuming suchanextended grain source. This value implies a Q/Q(H2O) � 1:4%, which is similar to the production rate ratio of Q/Q(H2O) � 4% derived from in situ measurements of H2CO in comet Halley. Production rates for H2CO toward comets C/2002 T7 (LINEAR) and C/2001 Q4 (NEAT) are 1:4 ; 10 27 and 5:6 ; 10 26 s � 1 , respectively, modeled using the extended grain source. The spectra of H2CO measured toward comet C/2002 T7 (LINEAR) show evidence for a second velocity component, most likely arising from comet fragmentation. Subject headingg astrobiology — comets: individual (Hale-Bopp (C/1995 O1), NEAT (C/2001 Q4), LINEAR (C/2002 T7)) — radio lines: solar system — techniques: interferometric

Ion abundances and implications for photochemistry in comets Halley (1986 III) and Bradfield (1987 XXIX)

Spectra of the plasma tails of comets P/Halley (1986 III) and P/Bradfield (1987 XXIX, also 1987s) were recorded using the Ohio State University Image Dissector Scanner (IDS) on the Perkins 1.8 m telescope at the Lowell Observatory. The ionic species CO+, N2+, CH+, and H2O+ were identified in these spectra and column densities for them were calcd. from measured fluxes. The obsd. abundance ratios of CO+/H2O+ in comets Halley and Bradfield are consistent with predictions by photochem. models, provided that CO+ and H2O+ are produced primarily from photoionization of CO and H2O, resp. However, the obsd. N2+/H2O+ ratios are at least an order of magnitude lower and the obsd. CH+/H2O+ ratios are a factor of 100 higher, than theor. results. The abundance ratio N2/CO was derived in the plasma tail of Bradfield from N2+ and CO+ data, and found to be an order of magnitude higher than a value measured in Halley. The relative ion abundances of CH+, N2+, and H2O+ in Halley are consistent with in situ measurements obtained from the Giotto spacecraft. Fluorescence efficiencies have been recalcd. for optical transitions of N2+, CH+, NH, CH, OH+, and CO and are also presented. [on SciFinder(R)]

Observational constraints on solar nebula nitrogen chemistry - N2/NH3

Observations of N2(+) and NH2 in Comet Halley and N2H(+) and NH3 in nine Galactic star-forming regions are used to determine the average N2/NH3 abundance ratio in these objects. For Comet Halley, N2/NH3 of about 0.1 is found, and for the quiescent gas in a sample of star-forming regions, N2/NH3 of about 170 +/- 100. The cometary N2/NH3 ratio corrected for gas-phase elemental nitrogen depletion in Comet Halley indicates that the gas component in the comet-forming region of the solar nebula was N2/NH3 of about 4. It is concluded that more realistic models which include condensation fractionation effects are required before the N2 and NH3 abundances in comet volatiles can be related to star-forming regions.

Millimeter-wavelength spectroscopy of CO, HCN, H2CO, and CH3OH in C/1996 B2 (Hyakutake)

Abstract Millimeter-wavelength spectra were obtained of CO, HCN, H2CO, and CH3OH in comet C/1996 B2 (Hyakutake) with the NRAO 12m telescope on Mar 21, 1996 UT. The emission of CO, H2CO, and HCN was mapped in the coma when the comet was ∼0.16 AU from the Earth, providing a detailed look at the behavior of these species in the inner coma. The mapping data reveal that line profiles, velocity offsets and spatial profiles are not alike for all four molecules. Each coma species shows properties of its own as if they were not determined by their interaction with the water molecules. This preliminary report shows that excitation conditions are the most important factor in shaping the observed lines. Also presented are production rates for these species near perigee.

Pre- and postperihelon abundances of gas and dust in comet Halley

Photometrically calibrated spectra of comet P/Halley (1986 III) were recorded between 1985 September 12-1986 June 10 using the Ohio State University Image Dissector Scanner on the Perkins 72 inch telescope at the Lowell Observatory. Column densities of CN, C3, CH, C2, and NH2 were calculated from measured fluxes in these spectra, and molecular scale lengths were deduced from the radial distribution of CN, C3, C2, and NH2. Production rates were computed using the new scale lengths and a Haser model analysis. Continuum emission at 4260 A was used to derive gas-to-dust ratios. The data indicate than comet Halley was approximately 2-5 times more abundant in gas and dust at postperihelion than preperihelion. On 1986 June 8 we observed the onset of a cometary ourburst which appeared very strong in dust production. The gas-to-dust ratios appeared to be subject to changes as a result of short-term outbursts but otherwise did not exhibit any systematic dependence on heliocentric distance. Reflectivity gradients of the continuum were also measured from the spectra. While most of the continua were red, blue continua were also observed which may be correlated with dust outbursts.

NH3 and NH2 in the coma of Comet Brorsen-Metcalf

Evidence consistent with NH3 ice in the nucleus of Comet Brorsen-Metcalf as the source of the NH2 observed in the comet coma is presented. The distribution of NH2 is symmetric and shows no evidence for jet structure at the 3-sigma significance level above background emission. An azimuthal average of the NH2 image produces an NH2 surface brightness profile for Comet Brorsen-Metcalf which yields a factor of about-10 improvement in the signal-to-noise ratio over previous 1D long-slit NH2 observations, and provides a significant constraint on the NH2 photodissociation time scale in comets. A Monte Carlo simulation of the comet coma, assuming that NH2 is the primary source of NH2, is described and compared with the observations. For an observed production rate, Q(H2O) is approximately equal to 7 x 10 exp 28 molecules/s, collisional effects on the NH3 and NH2 outflow had at most an approximately 10-percent effect on the NH2 surface brightness profile. Because Comet Brorsen-Metcalf showed no significant dust or gas production rate variability, it is argued that steady state conditions best match the comet at the time of the observations.

A CCD Image Archive Of Comet C/1995 O1 (Hale-Bopp): Dust Expansion Velocities

An optical archive of comet Hale-Bopp was obtained over 28 nights from June 1996 to May 1997 covering a range of heliocentric distances of r = 4.12 − 0.91. The CCD images were obtained with the 0.8-m University of Washington Manastash Ridge Observatory and the 0.25-m Pennsylvania State University at Eriemobile observatory. The reduced images clearly document the evolution of features of the coma, which were dominated by radial jetsfrom r = 4.1 − 2.3 AU, curved fan-shaped jets from r = 1.2 − 1.0 AU, and arcs or shells for 0.9 < r < 1.0 AU. We present the images and derive an average dust expansion velocity of Vdust = 0.67 ± 0.07 km s−1 from measurements of the arc features. The images in thearchive will be made available to other researchers for further study.

A search for interstellar ch3d: limits to the methane abundance in orion-kl

A search has been performed for interstellar CH3D via its J(K) = 1(0) - 0(0) transition at 230 GHz and its J(K) = 2(0) - l(0) and J(K) = 2(1) - 1(1) lines at 465 GHz using the NRAO 12 m and CSO 10 m telescopes towards Orion-KL. This search was done in conjunction with laboratory measurements of all three transitions of CH3D using mm/sub-mm direct absorption spectroscopy. The molecule was not detected down to a 3 sigma level of T(A) less than 0.05 K towards Orion, which suggests an upper limit to the CH3D column density of N less than 6 x 10(exp 18)/sq cm in the hot core region and a fractional abundance (with respect to H2) of less than 6 x 10(exp -6). These measurements suggest that the methane abundance in the Orion hot core is f less than 6 x 10-4, assuming D/H approximately 0.01. Such findings are in agreement with recent hot core chemical models, which suggest CH4/H2 approximately 10(exp -4).

N2H+ in the Orion ambient ridge : cloud clumping versus rotation

The IRAM 30-m telescope is used to obtain spectra of the J = 1 yields 0 transition of N2H(+) over a 2 x 2 arcsec area toward the Orion-KL/IRc2 star-forming region with 26-arcsec angular resolution. The N2H(+) emission, which exclusively traces the ridge gas, exhibits multiple radial velocities which appear to arise from the presence of at least four clouds of quiescent material. It is argued that the velocity structure of N2H(+) does not uniformly change across OMC-1 and, consequently, is inconsistent with the presence of large-scale differential rotation of the extended ridge along the SW-NE axis about IRc2. The coincidence of the two larger clouds with star-forming activity in Orion-KL suggests that either the quiescent gas is being pushed apart or that the star formation may have been triggered by a cloud-cloud interaction.