Mario Sprovieri

African monsoon variability during the previous interglacial maximum

Abstract Little is known about centennial- to millennial-scale climate variability during interglacial times, other than the Holocene. We here present high-resolution evidence from anoxic (unbioturbated) sediments in the eastern Mediterranean Sea that demonstrates a sustained ∼800-yr climate disturbance in the monsoonal latitudes during the Eemian interglacial maximum (∼125 ka BP). Results imply that before and after this event, the Intertropical Convergence Zone (ITCZ) penetrated sufficiently beyond the central Saharan watershed (∼21°N) during the summer monsoon to fuel flooding into the Mediterranean along the wider North African margin, through fossil river/wadi systems that to date have been considered only within a Holocene context. Relaxation in the ITCZ penetration during the intra-Eemian event curtailed this flux, but flow from the Nile – with its vast catchment area – was not affected. Previous work suggests a concomitant Eurasian cooling event, with intensified impact of the higher-latitude climate on the Mediterranean basin. The combined signals are very similar to those described for the Holocene cooling event around 8 ka BP. The apparent type of concurrent changes in the monsoon and higher-latitude climate may reflect a fundamental mechanism for variability in the transfer of energy (latent heat) between the tropics and higher latitudes.

Reconstructing past planktic foraminiferal habitats using stable isotope data: a case history for Mediterranean sapropel S5

Abstract A high-resolution stable O and C isotope study is undertaken on all planktic foraminiferal species that are reasonably continuous through an Eemian sapropel S5 from the western side of the eastern Mediterranean. The data are considered within a context of high-resolution isotope records for two further S5 sapropels from the central and easternmost sectors of the basin, alkenone-based sea surface temperature records for all three sapropels, and planktic foraminiferal abundance records for the same sample sets through all three sapropels. Results are compared with similar data for Holocene sapropel S1. The adopted approach allows distinction between species that are most suitable to assess overall changes in the climatic/hydrographic state of the basin, including depth-related differentiations and the main seasonal developments, and species that are most affected by variable biological controls or local/regional and transient physico–chemical forcings. It is found that a-priori assumptions about certain species’ palaeohabitats, based on modern habitat observations, may become biased when non-analogue conditions develop. In the case of Mediterranean sapropel S5, these consisted of enhanced freshwater dilution, elevated productivity, shoaling of the pycnocline between intermediate and surface waters, and stagnation of the subsurface circulation. Under these conditions, some species are found to ‘shift’ into habitat settings that differ considerably from those occupied today. The present multiple-species approach can identify such ‘anomalous responses’, and thus offers a sound background for further shell-chemistry investigations and quantitative interpretation of the isotopic profiles. We capitalise on the latter potential, and offer the first quantitative estimates of monsoon flooding into the Mediterranean during the deposition of Eemian sapropel S5.

Palaeoceanographic significance of the Tethyan ‘Livello Selli’ (Early Aptian) from the Hybla Formation, northwestern Sicily: biostratigraphy and high-resolution chemostratigraphic records

High-resolution micropalaeontological and chemostratigraphic records for the Hauterivian–Aptian succession outcropping at Calabianca (NW Sicily) provide new insight into the palaeoclimatic and palaeoceanographic evolution of the Tethys Ocean. Calcareous nannofossil and planktonic foraminiferal biostratigraphy together with δ13C chemostratigraphy allowed the identification of a hiatus in the Barremian and a major one including most of the Upper Aptian, the entire Lower Albian and part of the Middle Albian. The Livello Selli equivalent was identified on the basis of lithology and well constrained by calcareous plankton biostratigraphy as well as by the δ13C curve. The multi-proxy record from the Calabianca section is consistent with previous documentation of Tethyan sections, and others worldwide. Early Aptian global events, such as black shale deposition, nannoconid crisis, C isotopic negative spike and positive excursion associated with the OAE1a, increase in abundance of leupoldinids and clavate hedbergellids are superimposed on local/regional events, being strictly related to climate changes and increased run-off. Based on micropalaeontological results and geochemical proxies (Ba, P, V, Ni), the Livello Selli equivalent is interpreted as a high-productivity event associated with variable but overall anoxic/dysoxic conditions in the lower water column. The onset of new physical, chemical and biological conditions in the oceans and of the mid-Cretaceous greenhouse climate are interpreted as consequences of the superplume episode.

The middle Eocene climatic optimum event in the Contessa Highway section, Umbrian Apennines, Italy

We report a high-resolution paleomagnetic investigation constrained by new qualitative and semiquantitative analyses of planktic and benthic foraminifera, nannofossil assemblages, integrated with oxygen and carbon isotope measurements, for the middle Eocene Scaglia limestones of the Contessa Highway section, central Italy. Calcareous plankton assemblages enable recognition of several biostratigraphic events from planktic foraminiferal zone P11 to the lower part of zone P15 and from calcareous nannofossil zone NP15 to the upper part of zone NP17, which results in refi nement of the magnetobiostratigraphy of the Contessa Highway section. Correlation of the paleomagnetic polarity pattern with the geomagnetic polarity time scale provides a direct age interpretation for strata around the middle Eocene Scaglia limestones of the Contessa Highway section, from chrons C21n (47 Ma) through to subchron C18n.1n (38.5 Ma). Bulk carbon isotope values indicate a distinct carbon isotopic shift at 40 Ma that is interpreted to represent the fi rst evidence in the Northern Hemisphere of the middle Eocene climatic optimum, which has recently been observed as a stable isotope anomaly in multiple records from the Indian-Atlantic sector of the Southern Ocean. This demonstrates a global response of the carbon cycle to the proposed transient increased pCO 2 levels during the late middle Eocene and consequent global CO 2 -driven climate change.

Mercury in fishes from Augusta Bay (southern Italy): Risk assessment and health implication

Our study reports on the total mercury (HgT) concentrations measured in the muscles and livers of several benthic, demersal and pelagic fish species caught inside and outside of Augusta Bay (southern Italy), a semi-enclosed marine area, highly contaminated by the uncontrolled (since the 1950s to 1978s) discharge of the largest European petrochemical plant. Mercury levels in fish tissues are discussed with regard to specific habitat, size and/or age of the specimens and HgT distribution in the bottom sediments. Results suggest a still active Hg release mechanism from the polluted sediments to the marine environment. Also, the high HgT concentrations measured in fishes caught in the external area of the bay imply a potential role of Augusta Bay as a pollutant source for the Mediterranean ecosystem. Finally, values of hazard target quotient (THQ) and estimated weekly intake (EWI) demonstrate that consumption of fishes caught inside the bay represents a serious risk for human health. Also, data indicate that intake of fishes caught from the external area of the bay, especially for that concern demersal and benthic species, could be represent a significant component of risk for the local population.

Integrated stratigraphy of the Oligocene pelagic sequence in the Umbria-Marche basin (northeastern Apennines, Italy): A potential Global Stratotype Section and Point (GSSP) for the Rupelian/Chattian boundary

The Oligocene represents an important time period from a wide range of perspectives and includes significant climatic and eustatic variations. The pelagic succession of the Umbria-Marche Apennines (central Italy) includes a complete and continuous sequence of marly limestones and marls, with volcaniclastic layers that enable us to construct an integrated stratigraphic framework for this time period. We present here a synthesis of detailed biostratigraphic, magnetostratigraphic, and chemostratigraphic studies, along with geochronologic results from several biotite-rich volcaniclastic layers, which provide the means for an accurate and precise radiometric calibration of the Oligocene time scale. From this study, the interpolated ages for the Rupelian/Chattian stage boundary, located in the upper half of Chron 10n at meter level 188 in the Monte Cagnero section, and corresponding to the O4/O5 planktonic foraminiferal zonal boundary, are 28.36 Ma (paleomagnetic interpolation), 28.27 ± 0.1 Ma (direct radioisotopic dating), and 27.99 Ma (astrochronological interpolation). These ages appear to be slightly younger than those reported in recent chronostratigraphic time scale compilations. The Monte Cagnero section is a potential candidate for defining the Chattian Global Stratotype Section and Point (GSSP) and some reliable criteria are here proposed for marking the Rupelian/Chattian boundary according to International Union of Geological Sciences (IUGS) recommendations.

Astronomic calibration of the late Eocene/early Oligocene Massignano section (central Italy)

We present an astronomically tuned polarity timescale for the late Eocene/early Oligocene based on a cyclic limestone/marls sedimentary succession exposed at Massignano, Italy (GSSP for the Eocene-Oligocene boundary). Here we applied spectral analysis techniques to the high-resolution magnetic susceptibility record. The results provide clear evidence of a regular and cyclic signal that allows us to discard a stochastic mechanism as controlling these fluctuations. Conversely, these outcomes reveal the presence of stable and notable periodicities that are in tune with those associated with orbital forcing. Through a cyclostratigraphic analysis of the rhythmic sedimentary alternations and combination with the results of time series analysis of the proxy record, we refine the late Eocene portion of the GPTS. Through astronomical tuning of the rhythmic sedimentary alternations to recent astronomically calculated variations of Earths orbit we recalibrated the polarity boundaries ages and the main stratigraphic events recognized throughout the sedimentary record. Among these, an age of 33.714 Ma is proposed for the E/O boundary.

Orbitally modulated black shale deposition in the upper Albian Amadeus Segment (central Italy): a multi-proxy reconstruction

Abstract The upper Albian Amadeus Segment, which falls within Oceanic Anoxic Event 1c, exhibits cyclical alternations of marls/black shales and carbonate-rich beds that record evidence of orbital climate and sedimentary dynamics. A combined micropalaeontological (planktic and benthic foraminifera, and palynomorphs) and geochemical (stable isotopes, clay mineralogy, and major element distribution) investigation allowed recognition of a remarkable influence of continental material within the black shales. Moreover, the palaeoproductivity record is characterised by a non-linear response to the orbital forcing. The micropalaeontological and geochemical record suggests that upper Albian bedded cycles in the Marne a Fucoidi Formation resulted from interplay of changes in atmospheric and hydrological parameters of the western Tethys and its drainage basin. In particular, deposition of the black shales occurred during precession minima, in times of increased precipitation, enhanced continental runoff and stratification of the upper water column. In this respect, the black shales of the Amadeus Segment share similarities with the Neogene Eastern Mediterranean sapropels.

Orbitally forced paleoenvironmental and paleoclimate changes in the late postevaporitic Messinian of the central Mediterranean Basin

Paleoenvironmental and paleoclimate changes that occurred during the late postevaporitic stage of the Mediterranean Basin in the Messinian foreland domain of the Adriatic region offer a new perspective on the relationship between orbital forcing and climate response. The magnetic susceptibility record of the Fonte dei Pulcini A section (Maiella Mountains, Italy) allows us to orbitally tune the record between 5.394 and 5.336 Ma and to temporally constrain the paleoenvironmental and paleoclimate changes evidenced by quantitative paleontological (palynomorphs, ostracods, and calcareous nannofossils), stable isotope (δ 18 O and δ 13 C), and X-ray diffraction (XRD) analyses. The base of the Fonte dei Pulcini A section is characterized by Paratethyan ostracods and dinocysts, which point to the late Messinian Lago-Mare biofacies ( Loxocorniculina djafarovi zone) of the Mediterranean Messinian stratigraphy. From paleontological and geochemical (δ 18 O) analyses, there is no evidence of a marine incursion in the Fonte dei Pulcini A section. The major changes in terms of paleodepth, paleosalinity, evaporation versus precipitation, aridity versus humidity, and reworking processes occurred in the upper part of the Fonte dei Pulcini A section, during the last Messinian insolation cycle (i-cycle 511/512), which is characterized by high-amplitude oscillations. In contrast, the lower part of the Fonte dei Pulcini A section, which was deposited during relatively low-amplitude insolation cycles, is characterized by more stable environmental conditions. Comparing summer insolation with the paleoenvironmental changes at the Fonte dei Pulcini A section, we identify delays of several thousands of years between orbital forcing and climate response.

Distribution of rare earth elements in marine sediments from the Strait of Sicily (western Mediterranean Sea): Evidence of phosphogypsum waste contamination

Concentrations of rare earth elements (REE), Y, Th and Sc were recently determined in marine sediments collected using a box corer along two onshore-offshore transects located in the Strait of Sicily (Mediterranean Sea). The REE+Y were enriched in offshore fine-grained sediments where clay minerals are abundant, whereas the REE+Y contents were lower in onshore coarse-grained sediments with high carbonate fractions. Considering this distribution trend, the onshore sediments in front of the southwestern Sicilian coast represent an anomaly with high REE+Y concentrations (mean value 163.4 μg g(-1)) associated to high Th concentrations (mean value 7.9 μg g(-1)). Plot of shale-normalized REE+Y data of these coastal sediments showed Middle REE enrichments relative to Light REE and Heavy REE, manifested by a convexity around Sm-Gd-Eu elements. These anomalies in the fractionation patterns of the coastal sediments were attributed to phosphogypsum-contaminated effluents from an industrial plant, located in the southern Sicilian coast.