Mark R. Cooper

Age constraints and geochemistry of the Ordovician Tyrone Igneous Complex, Northern Ireland: implications for the Grampian orogeny

Abstract: The Tyrone Igneous Complex is one of the largest areas of ophiolitic and arc-related rocks exposed along the northern margin of Iapetus within the British and Irish Caledonides. New U–Pb zircon data and regional geochemistry suggest that the Tyrone Plutonic Group represents the uppermost portions of a c. 480 Ma suprasubduction-zone ophiolite accreted onto an outboard segment of Laurentia prior to 470.3 ± 1.9 Ma. The overlying Tyrone Volcanic Group formed as an island arc that collided with the Laurentian margin during the Grampian phase of the Caledonidan orogeny. Early magmatism is characterized by transitional to calc-alkaline, light REE (LREE)-enriched island-arc signatures, with an increasing component of continentally derived material up sequence. Tholeiitic rhyolites with flat to U-shaped REE profiles and LREE-depleted basalts, located stratigraphically below a c. 473 Ma rhyolite of the upper Tyrone Volcanic Group, suggest initiation of intra-arc rifting at c. 475 Ma. Metamorphic cooling ages from the Tyrone Central Inlier imply arc–continent collision before 468 ± 1.4 Ma, with the emplacement of the Tyrone Volcanic Group onto the margin. A suite of 470.3 ± 1.9 Ma to 464.3 ± 1.5 Ma calc-alkaline intrusions are associated with the continued closure of Iapetus. Supplementary material: Geochemical data and petrography are available at http://www.geolsoc.org.uk/SUP18467.

New age constraints for the Ordovician Tyrone Volcanic Group, Northern Ireland

New biostratigraphical evidence and a high-precision isotope dilution thermal ionization mass spectrometry U–Pb zircon age provide refined age constraint for the Ordovician Tyrone Volcanic Group of the Tyrone Igneous Complex. In a graptolite fauna from Slieve Gallion, the presence of Isograptus victoriae lunatus, the index fossil of the victoriae lunatus graptolite zone, indicates a correlation with the Australasian Castlemainian (Ca1) Stage. The U–Pb zircon age of 473 ± 0.8 Ma dates a volcanic arc-related rhyolite body that is stratigraphically below graptolitic mudstones of Slieve Gallion. The U–Pb isotopic and biostratigraphical age constraints closely match an interpolated age for the base of the Middle Ordovician and indicate a Whitlandian age for the upper Tyrone Volcanic Group, which supports the regional correlation with the Ballantrae Complex, Midland Valley Terrane, Scotland.

Episodic arc-ophiolite emplacement and the growth of continental margins: Late accretion in the Northern Irish sector of the Grampian-Taconic orogeny

In order to understand the progressive growth of continental margins and the evolution of continental crust, we must first understand the formation of allochthonous ophiolitic and island-arc terranes within ancient orogens and the nature of their accretion. During the early Paleozoic closure of the Iapetus Ocean, diverse sets of arc terranes, oceanic tracts, and ribbon-shaped microcontinental blocks were accreted to the passive continental margin of Laurentia during the Grampian-Taconic orogeny. In the northern Appalachians in central Newfoundland, Canada, three distinct phases of arc-ophiolite accretion have been recognized. New field mapping, high-resolution airborne geophysics, whole-rock and Nd-isotope geochemistry, and U-Pb zircon geochronology within the Tyrone Volcanic Group of Northern Ireland have allowed all three episodes to now be correlated into the British and Irish Caledonides. The Tyrone Volcanic Group (ca. 475–469 Ma) is characterized by mafic to intermediate lavas, tuffs, rhyolite, banded chert, ferruginous jasperoid, and argillaceous sedimentary rocks cut by numerous high-level intrusive rocks. Geochemical signatures are consistent with formation within an evolving peri-Laurentian island-arc/backarc, which underwent several episodes of intra-arc rifting prior to its accretion at ca. 470 Ma to an outboard peri-Laurentian microcontinental block. Outriding microcontinental blocks played a fundamental role within the orogen, explaining the range of ages for Iapetan ophiolites and the timing of their accretion, as well as discrepancies between the timing of ophiolite emplacement and the termination of the Laurentian Cambrian–Ordovician shelf sequences. Accretion of the Tyrone arc and its associated suprasubduction-zone ophiolite represents the third stage of arc-ophiolite emplacement to the Laurentian margin during the Grampian-Taconic orogeny in the British and Irish Caledonides.

Evolution of the Tyrone ophiolite, Northern Ireland, during the Grampian–Taconic orogeny: a correlative of the Annieopsquotch Ophiolite Belt of central Newfoundland?

The Tyrone Plutonic Group of Northern Ireland represents the upper portions of a tectonically dissected suprasubduction-zone ophiolite accreted to the composite Laurentian margin during the Middle Ordovician. Understanding its development and relationship to the Tyrone Central Inlier, an outboard fragment of relatively high-grade, peri-Laurentian continental crust, is essential for reconstructing the closure of the Iapetus Ocean. The Tyrone Plutonic Group is composed of tectonized layered, isotropic and pegmatitic gabbros, sheeted dolerite dykes and rare pillow lavas. New U–Pb zircon thermal ionization mass spectrometry geochronology has yielded an age of 483.68 ± 0.81 Ma from pegmatitic gabbro. Geochemical characteristics, Nd and Sr isotope systematics, and zircon inheritance indicate that the Tyrone Plutonic Group formed above a north-dipping subduction zone, by the propagation of a spreading centre into a microcontinental block. Synkinematic, calc-alkaline tonalitic to granitic material preserved in the contact zone between the Tyrone Plutonic Group and the Tyrone Central Inlier has produced pressure estimates of 2.3–4.0 ± 0.6 kbar and temperatures of 525–610 °C. Coeval arc–ophiolite accretion at c. 470 Ma may explain how sillimanite-grade metamorphic conditions were reached locally in the underlying Tyrone Central Inlier. Strong temporal, geochemical and lithological similarities exist to the Annieopsquotch Ophiolite Belt of Newfoundland. Supplementary materials: Petrographic photographs, whole-rock, isotopic and mineral geochemical data, and U–Th–Pb isotopic data are available at www.geolsoc.org.uk/SUP18646.

Geochemical evolution of Dalradian metavolcanic rocks: implications for the break-up of the Rodinia supercontinent

Abstract: Neoproterozoic basaltic magmatism in the Dalradian Supergroup of Scotland and Ireland was associated with the break-up of the Rodinia supercontinent. Magmas were erupted in rift-related basins along a strike length of at least 700 km and during a time period of c. 80 Ma. New major and trace element analyses of metabasalts from several formations are presented to trace the variations in magma compositions in time and space. The primary magmas resulted from variable degrees of mixing of melts derived from mantle sources similar to those of normal and enriched mid-ocean ridge basalts; some younger lavas also show evidence of contamination with continental crust. In contrast to speculations about magmatism elsewhere in Rodinia, the evidence here suggests that there was no involvement of a mantle plume in basalt generation. For example, the Scottish promontory of Laurentia drifted rapidly southwards through c. 25° over the duration of the magmatism, with no evidence of significant elevation above sea level, as might be expected from involvement of a plume. Generation of the primary magmas might have taken place predominantly through decompression melting in depleted upper mantle containing enriched streaks and blobs. Both the Dalradian lithostratigraphy and the metabasaltic compositions are consistent with extreme lithospheric stretching and possibly rupture during the earliest phase of magmatism, whereas generation of later magmatism appears to have been associated with major fault systems, possibly on a foundering continental margin. Supplementary material: Chemical analyses of Dalradian metavolcanic rocks (major elements recalculated to 100%, anhydrous) are available at www.geolsoc.org.uk/SUP18468.

A U–Pb age for the Late Caledonian Sperrin Mountains minor intrusions suite in the north of Ireland: timing of slab break-off in the Grampian terrane and the significance of deep-seated, crustal lineaments

An intrusion of trachy-andesite, representative of a newly discovered suite of high-K–Ba–Sr, calc-alkaline minor intrusions (termed herein the Sperrin Mountains suite), hosted within the Grampian terrane in the north of Ireland, has been dated by U–Pb zircon at 426.69 ± 0.85 Ma (mid-Silurian; Wenlock–Ludlow boundary). Geochemistry reveals a close association with the Fanad, Ardara and Thorr plutons of the Donegal Batholith and the Argyll and Northern Highlands Suite of Scotland. The deep-seated Omagh Lineament appears to have limited eastward propagation of the Sperrin Mountains suite from beneath the main centre of granitic magmatism in Donegal. A Hf depleted mantle model age (TDMHf) of c. 800 Ma for trachy-andesite zircons indicates partial melting from a source previously separated from the mantle. Whole-rock geochemistry of the suite is consistent with a model of partial melting, triggered by slab break-off, following thrusting of Ganderia–Avalonia under the Southern Uplands–Down–Longford accretionary prism (i.e. Laurentian margin). The new age constrains the timing of this event in the north of Ireland and is consistent with the petrogenesis of Late Caledonian high-K granites, appinites and minor intrusions across the Caledonides of northern Britain and Ireland. Supplementary material: Geochemical data are available at www.geolsoc.org.uk/SUP18600.

Stratigraphic, geochemical and U–Pb zircon constraints from Slieve Gallion, Northern Ireland: a correlation of the Irish Caledonian arcs

Recent Ar–Ar and U–Pb zircon geochronology from across the British and Irish Caledonides has revealed a prolonged period of arc-ophiolite formation (c. 514–464 Ma) and accretion (c. 490–470 Ma) to the Laurentian margin during the Grampian orogeny. The Slieve Gallion Inlier of Northern Ireland, an isolated occurrence of the Tyrone Volcanic Group, records the development of a peri-Laurentian island arc–backarc and its obduction to an outboard microcontinental block. Although a previous biostratigraphic age constraint provides a firm correlation of at least part of the volcanic succession to the Ca1 Stage of the Arenig (c. 475–474 Ma), there is uncertainty on its exact statigraphic position in the Tyrone Volcanic Group. Earliest magmatism is characterized by light rare earth element (LREE) depleted island-arc tholeiite. Overlying deposits are dominated by large ion lithophile and LREE-enriched, hornblende-phyric and feldspathic calc-alkaline basaltic andesites and andesitic tuffs with strongly negative ϵNdt values. Previously published biostratigraphic age constraints, combined with recent U–Pb zircon geochronology and new petrochemical correlations, suggest that the Slieve Gallion Inlier is equivalent to the lower Tyrone Volcanic Group. Temporal and geochemical correlations between the Slieve Gallion Inlier and Charlestown Group of Ireland suggest that they may be part of the same arc system, which was accreted at a late stage (c. 470 Ma) in the Grampian orogeny. A switch from tholeiitic volcanism to calc-alkaline dominated activity within the Lough Nafooey Group of western Ireland occurred prior to c. 490 Ma, some 15–20 Myr earlier than at Tyrone and Charlestown. Supplementary materials: Sampling and geochemical results (major elements, loss on ignition, trace elements, REE and Nd isotopes) are available at www.geolsoc.org.uk/SUP18640.

Intrusion history of the Portrush Sill, County Antrim, Northern Ireland: evidence for rapid emplacement and high-temperature contact metamorphism

The gabbroic Portrush Sill in Northern Ireland, part of the North Atlantic Igneous Province, intruded Lower Jurassic mudstones and siltstones about 55 Ma ago. We used petrologic observations and geochemical analyses to study how the sill interacted with the sedimentary rocks. Field relationships show that an Upper Sill and numerous associated Minor Intrusions were emplaced in the sedimentary host rocks before intrusion of the Main Sill, some 10 m above its upper contact. Geochemical analyses reveal two magma contamination processes: Nb and Ta anomalies, coupled with incompatible element enrichment, record contamination by deep crustal rocks, whereas Li, Pb and Ba anomalies reveal a superficial contamination through fluid circulation at the contact between magmatic and sedimentary rocks. Analysis of mineral assemblages and geochemical data from the contact aureole demonstrate uniform metamorphic conditions between the two main intrusions and an absence of a thermal gradient. The identification of pyrrhotite by magnetization analyses and of orthopyroxene by microprobe analyses indicates very high temperatures, up to 660°C. Thermal modelling explains these temperatures as the coupled effects of the Main Sill and the earlier intruded Upper Sill and Minor Intrusions. Even though the chemical composition of the Main Sill suggests another type of parental liquid, all three units were emplaced in a very short time, certainly less than five years.

Refined model of incremental emplacement based on structural evidence from the granodioritic Newry igneous complex, Northern Ireland

Although many intrusions are now known to have been incrementally emplaced, the mechanisms through which this takes place are generally poorly understood. The Newry igneous complex was incrementally emplaced within the Southern Uplands-DownLongford terrane of Northern Ireland during late Caledonian sinistral transtension. This study uses a variety of new and existing data and techniques to provide a fuller and firmer understanding of incremental emplacement than has previously been available, addressing both deep-crustal processes and those operating within the emplacement site. Host-rock orientations suggest that some of the accommodation space for the Newry igneous complex was generated due to pullapart tectonics operating within the Southern Uplands-Down-Longford terrane. Local host-rock deflections, concentric igneous foliations, and concentric linear anisotropy of magnetic susceptibility (AMS) fabrics show that inflation due to magma overpressure also generated significant space. Strong AMS fabrics close to the boundaries of some magma pulses in turn suggest that inflation was accomplished by injection of individual magma pulses and was thus incremental. The dome-like orientations of mineral foliations within plutons and the truncation of steep local host-rock tracts by the Newry igneous complex imply that the complex consists of four laccolithic bodies. On a larger scale, it is suggested that the deep-seated Argyll and Newry lineaments represent faults that allowed magma generated at depth to ascend to the crustal level of the Southern UplandsDown-Longford tract boundaries. It is also inferred that sinistral movement along the Argyll and Newry lineaments may have produced the releasing bend within the Southern Uplands-Down-Longford terrane. Higher in the crust, reduced confining pressure resulted in tectonic opening along this releasing bend. This local stress field induced horizontal magma flow and emplacement of the Newry igneous complex as laccolithic bodies. This study suggests that simplistic emplacement models should largely be abandoned in favor of holistic models incorporating the multiple interdependent processes operating during magma ascent and emplacement.

The ‘Clay-with-Flints’ deposit in Northern Ireland: reassessment of the evidence for an early Paleocene ignimbrite

Reassessment of key geological sections, field relationships and petrographical characteristics of the Northern Ireland ‘Clay-with-Flints’ and ‘Donalds Hill Ignimbrite Formation’ show they formed dominantly by sedimentary processes. The involvement of a previously postulated pyroclastic flow during early Paleocene time is not recognized and, as such, the Donalds Hill Ignimbrite Formation stratigraphic term is discounted. Instead a multistage model of formation by sedimentary accumulation and remobilization is presented and the term Clay-with-Flints is retained. Regionally, two dominant facies are recognized in most Clay-with-Flints sections. Facies 1 was formed by an initial accumulation of flints on a chalk landscape undergoing karstification, and involved deposition of a clay matrix derived predominantly from contemporaneous erosion of subtropical soil horizons formed mainly on basalt. In Facies 2, evidence is observed for widespread remobilization of Facies 1 deposits by high-density mudflows driven by the advancement of the Antrim Lava Group, which caused the blockage of subsurface and marginalization of surface drainage. A stratigraphical constraint imposed by the presence of a supposed ignimbrite in this part of the North Atlantic Igneous Province has been problematic, but this is resolved by its identification as a diachronous, sedimentary deposit that formed until buried by either the lower or upper formations of the Antrim Lava Group.