Markku Kuittinen

Metamaterials with tailored nonlinear optical response.

We demonstrate that the second-order nonlinear optical response of noncentrosymmetric metal nanoparticles (metamolecules) can be efficiently controlled by their mutual ordering in an array. Two samples with minor change in ordering have nonlinear responses differing by a factor of up to 50. The results arise from polarization-dependent plasmonic resonances modified by long-range coupling associated with metamolecular ordering. The approach opens new ways for tailoring the nonlinear responses of metamaterials and their tensorial properties.

Atomic layer deposited titanium dioxide and its application in resonant waveguide grating

We demonstrate good optical quality TiO(2) thin films grown by atomic layer deposition at 120 degrees C. The optical properties were studied using spectroscopic ellipsometry and prism coupling methods. The refractive index was 2.27, and the slab waveguide propagation loss was less than 1dB/cm at 1.53microm. A high quality resonant waveguide grating was fabricated using a thin TiO(2) layer on top of a SiO(2) grating.

Single-layer one-dimensional nonpolarizing guided-mode resonance filters under normal incidence

We demonstrate that properly designed one-dimensional guided-mode resonance filters (GMRFs) with only one grating layer can exhibit a nonpolarizing resonant filtering effect under normal incidence. A sinusoidal profile nonpolarizing GMRF is realized by photoinduced surface-relief grating formation on thin films of polymer-azobenzene complexes and subsequent atomic layer deposition, showing the feasibility of fabrication of such compact GMRFs.

Refractive index and extinction coefficient dependence of thin Al and Ir films on deposition technique and thickness

We show that the optical properties of thin metallic films depend on the thickness of the film as well as on the deposition technique. Several thicknesses of electron-beam-gun-evaporated aluminium films were measured and the refractive index and the extinction coefficient defined using ellipsometry. In addition, the refractive indexes and the extinction coefficients of atomic-layer-deposited iridium were compared with those of evaporated iridium samples.

Enhanced optical absorptance of metals using interferometric femtosecond ablation

The enhanced optical absorptance in metals was recently demonstrated using femtosecond laser-induced surface structuring. This structuring was obtained by simply focusing the light to the sample surface. Here we demonstrate more efficient absorptance enhancement using interferometric ablation. This interferometric ablation technique produces deeper surface structures and, consequently, higher absorption than structures obtained by just focusing the light to the surface. We also show the measured reflectance spectra over visible region for unaltered and structured stainless steel and copper samples.

Second-harmonic generation from metal nanoparticles: resonance enhancement versus particle geometry.

We demonstrate that optical second-harmonic generation (SHG) from arrays of noncentrosymmetric gold nanoparticles depends essentially on particle geometry. We prepare nanoparticles with different geometrical shapes (L and T) but similar wavelengths for the polarization-dependent plasmon resonances. In contrast to recent interpretations emphasizing resonances at the fundamental frequency, the T shape leads to stronger SHG when only one, instead of both, polarization component of the fundamental field is resonant. This is explained by the character of plasmon oscillations supported by the two shapes. Our numerical simulations for both linear and second-order responses display unprecedented agreement with measurements.

Dipole limit in second-harmonic generation from arrays of gold nanoparticles

We present a multipolar tensor analysis of second-harmonic generation from arrays of noncentrosymmetric gold nanoparticles. In contrast to earlier results, where higher multipoles and symmetry-forbidden signals arising from sample defects play a significant role, the present results are completely dominated by symmetry-allowed electric-dipole tensor components. The result arises from significant improvement in sample quality, which suppresses the higher-multipole effects and enhances the overall response by an order of magnitude. The results are a prerequisite for metamaterials with controllable nonlinear properties.

A wide-angle antireflection surface for the visible spectrum

A surface consisting of periodically arranged nanopyramids producing wide-angle broad-band antireflection properties is presented. The reflectance of silicon dioxide is reduced below 0.45% over the visible spectral range (380-760 nm) for viewing angles from 0 degrees to 40 degrees . The surface is designed by using rigorous diffraction theory and fabricated first in silicon by exploiting its strong crystalline orientation and by using the wet etching process. The structure is transferred from silicon to transparent silicon dioxide by using nano-imprint lithography and proportional reactive ion etching.

Laboratory demonstration of a mid-infrared AGPM vector vortex coronagraph

Context. Coronagraphy is a powerful technique to achieve high contrast imaging, hence to image faint companions around bright targets. Various concepts have been used in the visible and near-infrared regimes, while coronagraphic applications in the mid-infrared nowadays remain largely unexplored. Vector vortex phase masks based on concentric subwavelength gratings show great promise for such applications. Aims. We aim at producing and validating the first high-performance broadband focal plane phase mask coronagraphs for applications in the mid-infrared regime, and in particular the L band with a fractional bandwidth of ∼16% (3.5–4.1 μm). Methods. Based on rigorous coupled wave analysis, we designed an annular groove phase mask (AGPM) producing a vortex effect in the L band, and etched it onto a series of diamond substrates. The grating parameters were measured by means of scanning electron microscopy. The resulting components were then tested on a mid-infrared coronagraphic test bench. Results. A broadband raw null depth of 2 × 10 −3 was obtained for our best L-band AGPM after only a few iterations between design and manufacturing. This corresponds to a raw contrast of about 6 × 10 −5 (10.5 mag) at 2λ/D. This result is fully in line with our projections based on rigorous coupled wave analysis modelling, using the measured grating parameters. The sensitivity to tilt and focus has also been evaluated. Conclusions. After years of technological developments, mid-infrared vector vortex coronagraphs have finally become a reality and live up to our expectations. Based on their measured performance, our L-band AGPMs are now ready to open a new parameter space in exoplanet imaging at major ground-based observatories.

Rotating optical fields : experimental demonstration with diffractive optics

Transversally sharply structured optical fields are discussed, which rotate upon propagation without any lateral expansion of the intensity profile. Finite-aperture approximations of such fields, realizable with phase-only and complex-amplitude recording, are demonstrated. Recording of at least some of the amplitude information (rather than neglecting it completely) is shown to improve the field quality considerably, in particular close to the element. Lohmann-coded binary-phase diffractive elements with restricted amplitude recording are fabricated by electron beam lithography and reactive ion etching. The experimental results are in good agreement with theory.