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Markus Brym

Technical University of Berlin

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Publication

Featured researches published by Markus Brym.

Chemical Communications | 2007

A new type of heteroleptic complex of divalent lead and synthesis of the P-plumbyleniophosphasilene, R2SiP–Pb(L): (L = β-diketiminate)

Shenglai Yao; Stefan Block; Markus Brym; Matthias Driess

The synthesis and structures of the first heteroleptic beta-diketiminato complexes of lead(II) with terminal phenolato, bis(trimethylsilyl)amido, bis(trimethylsilyl)phosphanido and silylidenephosphanido ligands are reported; 207Pb NMR spectroscopic data indicate that lead(II) can serve as a sigma-donor or acceptor centre, depending on the electronegativity of the terminal ligand.

Journal of the American Chemical Society | 2006

A new type of N-heterocyclic silylene with ambivalent reactivity.

Matthias Driess; Shenglai Yao; Markus Brym; Christoph van Wüllen; Dieter Lentz

Angewandte Chemie | 2007

From a Stable Silylene to a Mixed‐Valent Disiloxane and an Isolable Silaformamide–Borane Complex with Considerable Silicon–Oxygen Double‐Bond Character

Shenglai Yao; Markus Brym; Christoph van Wüllen; Matthias Driess

Angewandte Chemie | 2006

Low-Valent Silicon Cations with Two-Coordinate Silicon and Aromatic Character

Matthias Driess; Shenglai Yao; Markus Brym; Christoph van Wüllen

Angewandte Chemie | 2007

Consecutive insertion of a silylene into the P4 tetrahedron: facile access to strained SiP4 and Si2P4 cage compounds.

Yun Xiong; Shenglai Yao; Markus Brym; Matthias Driess

Angewandte Chemie | 2006

A Heterofulvene‐Like Germylene with a Betain Reactivity

Matthias Driess; Shenglai Yao; Markus Brym; Christoph van Wüllen

Journal of the American Chemical Society | 2007

An Isolable Silanoic Ester by Oxygenation of a Stable Silylene

Shenglai Yao; Yun Xiong; Markus Brym; Matthias Driess

Angewandte Chemie | 2006

Synthesis of a "half"-parent phosphasilene R2Si=PH and its metalation to the corresponding P-zinciophosphasilene [R2Si=PM].

Matthias Driess; Stefan Block; Markus Brym; Michael T. Gamer

Chemistry-an Asian Journal | 2008

A Series of Isolable Silanoic Thio-, Seleno-, and Telluroesters (LSi(X)OR) with Donor-Supported SiX Double Bonds (L=β-Diketiminate; X=S, Se, Te)

Shenglai Yao; Yun Xiong; Markus Brym; Matthias Driess

Angewandte Chemie | 2006

Ein Heterofulven‐analoges Germylen mit Betain‐Reaktivität

Matthias Driess; Shenglai Yao; Markus Brym; Christoph van Wüllen

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Matthias Driess

Ruhr University Bochum

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Shenglai Yao

Technical University of Berlin

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Christoph van Wüllen

Kaiserslautern University of Technology

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Stefan Block

Technical University of Berlin

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Yun Xiong

Technical University of Berlin

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Dieter Lentz

Free University of Berlin

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Michael T. Gamer

Karlsruhe Institute of Technology

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