Marta Franchini

Magmatic characteristics of the Paleocene Cerro Nevazón region and other Late Cretaceous to Early Tertiary calc-alkaline subvolcanic to plutonic units in the Neuquén Andes, Argentina

Abstract Voluminous Late Cretaceous–Early Tertiary calc-alkaline magmatism in the northwest part of the Neuquen province, Argentina, is characterized by a NS-trending belt of olivine basalt-augitic andesite volcanic and amphibole-rich diorite subvolcanic facies that were grouped in the Neuquen-Mendoza volcanic province. Of samples associated with skarn mineralization in the Cerro Nevazon area, two were dated by K/Ar in amphibole and one by Ar/Ar in plagioclase; together, they yield ages between 60.1±1.6 and 56.0±1.7 Ma. The igneous rocks contain normally zoned plagioclase (64–74%), amphibole (magnesiohastingsite and edenite; 15–20%), biotite (5–10%), quartz (4–18%), minor enstatite–ferrosilite (Wo2.5–3En71–73Fs24–25), and augite (Wo42–43En42–43Fs14–15), with accessory magnetite, minor ilmenite, apatite, sphene, and traces of zircon. The fractionation of calcic plagioclase+olivine+pyroxene±magnetite±ilmenite is responsible for the evolution of the parental magmas, which originated in approximately 10% melting of a mantle source contaminated by fluids from the oceanic subducted lithosphere, with sparse or no residual garnet. The gabbro rare earth element patterns are similar to those of the Antuco volcano (37°25′S) and other Quaternary basaltic rocks from the southern volcanic zone (CSVZ) of the Andes (37–41°5′S) emplaced in a relatively thin continental crust (≈30 km). Although the Cerro Nevazon granitoids share some geochemical signatures with the Paleogene Caicayen igneous units, also located in the northwestern region of Neuquen, they have different evolutionary styles, as expressed by the lack of amphibole fractionation and less Cs enrichment in the Caicayen rocks. With similar SiO2 contents, the Upper Cretaceous–Paleocene Campana Mahuida subvolcanic rocks from the same region are richer in incompatible trace elements (K, Rb, Sr, Ba, Nb, La, Ce, Yb, Th, and U) than either the Nevazon or Caicayen units, which suggests that their parental magmas were contaminated with crustal material. The low Fe2O3/FeO ratios in the Nevazon igneous rocks, combined with the presence of ilmenite in most rocks and the low Mg/(Mg+Fe+2) ratios in mafic minerals, suggest that the Nevazon magmas evolved under more reduced conditions than did the Caicayen or Campana Mahuida magmas.

Mineral reactions associated with hydrocarbon paleomigration in the Huincul High, Neuquén Basin, Argentina

Bleaching of red beds by the migration of reducing pore fluids is a widespread phenomenon, with most previous work on the topic focused on detailed studies in the southwestern United States, and to a lesser extent Germany. Herein, we report on widespread bleaching of Cretaceous red beds in the Neuquen Basin and the relationship of this bleaching to hydrocarbon migration. In the Cerro Granito area of the Huincul High, Neuquen Basin, the basal deposits of the Neuquen Group (Candeleros and Huincul Formations) are bleached. This alteration was apparently controlled by fluid and host-rock composition as well as by the intensity and span of the fluid-rock interaction. Red, fine-grained sandstones and mudstones of the Candeleros Formation were deposited in fluvial and swamp environments and contain authigenic hematite, Na-rich corrensite, micro- and mesoquartz, calcite, and analcite. Coarse-grained sandstones and mudstones of the Huincul Formation, which overlie the Candeleros Formation, were deposited in a braided fluvial system, under more humid and acidic conditions than the Candeleros Formation. Sandstones are similar in composition and texture to the Candeleros sandstones, except they contain less basic volcanic detritus and lack corrensite. Bleached facies in both formations contain bitumen and clusters of calcite + bitumen concretions, and partially dissolved detrital clasts and most cements, including early Fe-oxides, which resulted in an increase in secondary porosity and bleaching of the red beds. Alteration of the Candeleros Formation is confined to medium- to coarse-grained sandstone in which corrensite is partially dissolved and its interlayer charge is satisfied by Ca instead of Na, as in corrensite from the red sandstones. Extensive dissolution occurred in the Huincul Formation, which favored the precipitation of new authigenic minerals such as smectite, mixed-layer chlorite-smectite, and pyrite. Bleaching and associated alteration most likely resulted from interaction of hydrocarbons with the red beds. Hydrocarbon paleomigration in the Cerro Granito area occurred in higher-permeability portions of the Candeleros and Huincul Formations. The seal provided by the Lisandro Formation was breached during uplift driven by Tertiary tectonism, resulting in the exhumation of the Huincul and Candeleros Formations. This study highlights the importance of a variety of alterations, including complex clay mineral paragenesis, contemporaneous with bleaching of the red beds. Such alterations can potentially be used to provide evidence for the passage of chemically reducing fluids associated with hydrocarbons in other regions, including cases where the original red color has been completely removed.