Marta Padoan

Weathering and Relative Durability of Detrital Minerals in Equatorial Climate: Sand Petrology and Geochemistry in the East African Rift

This article investigates how, where, and to what extent the mineralogical and chemical composition of sand-sized sediments is modified by extreme weathering in modern equatorial settings, with the ultimate goal of learning to read climate from the sedimentary record. To single out the weathering effect, we studied the compositional trends of fluvial sands along the western branch of the East African Rift between 5°S and 5°N. The relative durability of different detrital components, as well as potential hydraulic-sorting and grain-size effects, were assessed by comparing samples with similar provenances in different climatic and environmental conditions or of different size classes within the same sample. Sands of equatorial central Africa at the headwaters of the Congo and Nile basins display the full spectrum of petrologic suites characterizing rift-shoulder and volcanic rift provenances. Unlike in arid Arabia, quartzose sands are not restricted to areas where detritus is recycled from prerift sedimentary covers. In a hot humid climate, weathering can effectively obliterate the fingerprint of parent rock lithology and produce a nearly pure quartz residue even where midcrustal basement rocks are being actively uplifted and widely unroofed. In such settings garnet is destroyed faster than hornblende, and zircon faster than quartz. Weathering control on detrital modes is minor only in the rain shadow of the highest mountains or volcanoes, where amphibole-dominated quartzofelicdspathic metamorphiclastic sands (Rwenzori Province) or clinopyroxene-dominated feldspatholithic volcaniclastic sands (Virunga Province) are generated. Our detailed study of the Kagera basin emphasizes the importance of weathering in soils at the source rather than of progressive maturation in temporary storage sites during stepwise transport and shows that the transformation of diverse parent rocks into a quartzose “white sand” may be completed in one sedimentary cycle in hydromorphic soils of subequatorial lowlands. Micas and heavy minerals, which are less effectively diluted by recycling than main framework components, offer the best key to identify the original source-rock imprint. The different behavior of chemical indexes such as the CIA (a truer indicator of weathering) and the WIP (markedly affected by quartz dilution) helps us to distinguish strongly weathered first-cycle versus polycyclic quartz sands.

Provenance of Passive-Margin Sand (Southern Africa)

This study investigates the petrographic, mineralogical, geochronological, and geochemical signatures of river sands across southern Africa. We single out the several factors that control sand generation, including weathering and recycling, and monitor the compositional changes caused by chemical and physical processes during fluvial transport from cratonic sources to passive-margin sinks. Passive-margin sands have two first-cycle sources. Quartz and feldspars with amphibole, epidote, garnet, staurolite, and kyanite are derived from crystalline basements exposed at the core of ancient orogens and cratonic blocks (dissected continental block provenance). Volcanic rock fragments, plagioclase, and clinopyroxene are derived from flood basalts erupted during the initial phases of rifting (volcanic rift provenance). First-cycle detritus mixes invariably with quartzose detritus recycled from ancient sedimentary successions (undissected continental block provenance) or recent siliciclastic deposits (e.g., Kalahari dune sands; recycled clastic provenance). U-Pb ages of detrital zircons mirror the orogenic events that affected southern Africa since the Archean. Damara (0.5–0.6 Ga) and Namaqua (1 Ga) age peaks are prominent throughout Namibia, from the Orange mouth to the Namib and Skeleton Coast Ergs, and also characterize Kalahari dunes and sands of the Congo, Okavango, and Zambezi Rivers. Instead, sharp old peaks at 2.1 Ga and 2.6 Ga characterize Limpopo and Olifants sands, matching the age of the Bushveld intrusion and the final assembly of the Zimbabwe and Kaapvaal Cratons, respectively; discordant ages indicate Pb loss during the Pan-African event. Chemical indices confirm that weathering is minor throughout the tropical belt from South Africa and Zimbabwe to Namibia and coastal Angola but major for quartzose sands of the Congo, Okavango, and upper Zambezi Rivers, largely produced in humid subequatorial regions. Recycling of quartzose sediments is extensive in all of these catchments. From Congo to Mozambique, along the >5000-km Atlantic and Indian Ocean rifted margins, polycyclic detritus reaches commonly 50% and locally up to 100%, in line with the estimated incidence of recycling worldwide. Quantitative information provided by provenance studies of modern sands helps us to better understand the relationships between sediment composition and plate-tectonic setting and to upgrade the overly simplified and often misleading current provenance models. This is a necessary step if we want to decipher the stratigraphic record of ancient passive margins and reconstruct their paleotectonic and paleoclimatic history with greater accuracy.

Detrital Fingerprints of Fossil Continental-Subduction Zones (Axial Belt Provenance, European Alps)

Collision orogens such as the Alps or the Himalayas are generated by plate convergence, culminating in attempted subduction of a thinned continental margin. Massive amounts of metamorphic rocks displaying high-pressure parageneses are produced during such relatively brief tectonic events and then rapidly exhumed to form the axial backbone of the new orogen. Sediment composition provides a fundamental key to identify past events of continental subduction, although coupled detrital-geochronology techniques are needed to discriminate neometamorphic and paleometamorphic sources of detritus. Within the Austroalpine Cretaceous and Penninic Eocene axial belts of the Alps, we ideally distinguish three structural levels, each characterized by diagnostic detrital fingerprints. The shallow level chiefly consists of offscraped remnant-ocean turbidites and unmetamorphosed continental-margin sediments and mostly produces lithic to quartzolithic sedimentaclastic sands yielding very poor heavy mineral suites including ultrastable minerals. The intermediate level includes low-grade metasediments and polymetamorphic basements and sheds quartzolithic to feldspatholithoquartzose metamorphiclastic sands yielding moderately rich epidote-amphibole suites with chloritoid or garnet. The deep level contains eclogitic remnants of continent-ocean transitions and supplies feldspatholithoquartzose/feldspathoquartzose high-rank metamorphiclastic to lithic ultramaficlastic sands yielding rich to extremely rich suites dominated by garnet, hornblende, or epidote, depending on protoliths (continental vs. oceanic) and pressure/temperature paths during exhumation. Although widely overprinted under greenschist-facies or amphibolite-facies conditions, occurrence of ultradense eclogite in source areas is readily revealed by the heavy mineral concentration (HMC) index, which mirrors the average density of source rocks in the absence of hydraulic-sorting effects. Rather than the pressure peak reached at depth, the metamorphic index (MI) and hornblende color index (HCI) reflect peak temperatures reached at later stages, when subduction is throttled by arrival of thicker continental crust and geothermal gradients increase, as documented in detritus derived from the Tauern window and Lepontine Dome. Experience gained from modern sediments provides fundamental help to decrypt the information stored in the sedimentary record and thus to identify and reconstruct subduction events of the past.

A detrital record of the Nile River and its catchment

This research uses analyses from Nile catchment rivers, wadis, dunes and bedrocks to constrain the geological history of NE Africa and document influences on the composition of sediment reaching the Nile delta. Our data show evolution of the North African crust, highlighting phases in the development of the Arabian–Nubian Shield and amalgamation of Gondwana in Neoproterozoic times. The Saharan Metacraton and Congo Craton in Uganda have a common history of crustal growth, with new crust formation at 3.0 – 3.5 Ga, and crustal melting at c. 2.7 Ga. The Hammamat Formation of the Arabian–Nubian Shield is locally derived and has a maximum depositional age of 635 Ma. By contrast, Phanerozoic sedimentary rocks are derived from more distant sources. The fine-grained (mud) bulk signature of the modern Nile is dominated by input from the Ethiopian Highlands, transported by the Blue Nile and Atbara rivers. Detrital zircons in the Nile trunk are predominantly derived from Phanerozoic cover rocks. Most detritus from the upstream White Nile is trapped in the Sudd marshes and contributes little to the Nile trunk. Therefore, the White Nile downstream is dominated by locally derived Phanerozoic cover. The White Nile proximal to the Gezira Fan is influenced by the fans Blue Nile signature. Supplementary material: Sample information, analytical methods and data tables are available at https://doi.org/10.6084/m9.figshare.c.3569490

Clay mineralogy in southern Africa river muds

Abstract The composition, morphology and crystal order of clay minerals in silt-sized sediments carried in suspensions from 25 major rivers across tropical southern Africa have been studied by X-ray diffractometry and scanning and transmission electron microscopy. Our goal was to determine the spatial variability of clay-mineral associations in diverse geological settings, and in climatic conditions ranging from humid Angola and Zambia to hyperarid Namibia and the Kalahari. Specific attention was paid to the micromorphology and chemical composition of smectite particles. The relative abundance of smectites, illite/mica, kaolinite and chlorite enabled identification of regions characterized by different physical and chemical processes: (1) negligible chemical weathering is documented in Namibia, where river muds mostly contain illite/mica or smectite derived from Damara metasedimentary or Etendeka volcanic rocks; (2) kaolinite documenting intense weathering, reaches a maximum in the Okavango, Kwando and Upper Zambezi, sourced in subequatorial Angola and Zambia; (3) suspended-load muds in the Limpopo and middle Zambezi catchments display intermediate features, with varied assemblages and smectite compositions reflecting diverse parent lithologies. Clay mineralogy and chemical composition are confirmed as a most effective tool to unravel present and past climatic conditions on a continental scale.

Controls on sand ramp formation in southern Namibia

Sand ramps have the potential to provide rich palaeoenvironmental information in dryland regions wherein proxy records are typically scarce. However, current knowledge of the geomorphic controls and processes of sand ramp formation is limited. This study provides a data-rich examination of the key factors controlling sand ramp formation. The location and morphology of 75 sand ramps in southern Namibia are examined. The sediments and chronologies of 10 sand ramps are studied in detail using 51 OSL dates and 83 grain-size and LOI samples. Heavy mineral assemblages are used to determine the provenance of 10 samples and OSL sensitivity is used to explore geomorphic processes of 8 samples. Sand ramp morphology can be grouped into one of four classes of increasing size and complexity and is closely linked to the available accommodation space. Heavy mineral assemblages indicate local sediment sources and all 75 studied sand ramps are within 4 km of a large ephemeral river channel or within 5.5 km of a dune field. Therefore, accommodation space and sediment supply are identified as the primary controls of sand ramp formation. Sedimentology and OSL sensitivity suggest a complex interplay of aeolian, fluvial and colluvial processes contribute to sand ramp formation with large variability observed between ramps. Three of the ten dated sand ramps have been present in the Namibian landscape for >100 ka. Eight sand ramps show episodic deposition between >75-12 ka and five show evidence of surface reworking over the past 2 ka. Environmental sensitivity is likely to be linked to the size and availability of the accommodation space. Therefore, individual sand ramps are expected to reflect local environmental conditions, recording when an abundant sediment supply coincided with available accommodation space, whilst a regional analysis of multiple sand ramps with chronometric data offers the potential to identify larger scale palaeoenvironmental controls of sediment supply.