Marta Serrano

On anisotropy of ferritic ODS alloys

Abstract Ferritic oxide dispersion strengthened (ODS) alloys are candidate materials to be used as cladding for long term fast reactors, due to their high strength at high temperature and good swelling and irradiation resistances. The fabrication of cladding tubes is usually made by a succession of cold deformation steps where a deformation induced anisotropic microstructure could take place, which would affect the mechanical behaviour of the tube. The characterisation of this microstructural anisotropy is one of the key issues in the development of cladding ODS tubes. In this paper, the microstructural anisotropy of a Fe–14Cr–ODS extruded bar and a Fe–12Cr–ODS plate is characterised and its effect on the mechanical properties is analysed by tensile, impact and small punch testing. In both materials, a reduction of the ductility is observed in the transverse specimens. In addition, the fracture behaviour seems to be strongly dependent on the location of the crack plane regarding the elongated grained microstructure.

Solvent-free lipase-catalyzed synthesis of a novel hydroxyl-fatty acid derivative of kojic acid

The aim of this work was the synthesis of a novel hydroxyl-fatty acid derivative of kojic acid rich in kojic acid monoricinoleate (KMR) which can be widely used in the cosmetic and food industry. The synthesis of KMR was carried out by lipase-catalysed esterification of ricinoleic and kojic acids in solvent-free system. Three immobilized lipases were tested and the best KMR yields were attained with Lipozyme TL IM and Novozym 435. Since Lipozyme TL IM is the cheapest, it was selected to optimize the reaction conditions. The optimal reaction conditions were 80 °C for the temperature, 1:1 for the alcohol/acid molar ratio, 600 rpm for stirring speed and 7.8% for the catalyst concentration. Under these conditions, the reaction was scaled up in a 5×10⁻³ m³ stirred tank reactor. ¹H-¹³C HMBC-NMR showed that the primary hydroxyl group of kojic acid was regioselectively esterified. The KMR has more lipophilicity than kojic acid and showed antioxidant activity that improves the oxidation stability of biodiesel.

The Application of Miniaturized Three-Point-Bend Specimens for Determination of the Reference Temperature of JRQ Steel

This contribution deals with determination of the reference temperature of JRQ steel using miniaturized specimens. The dimensions of used miniaturized specimens were 3 × 4 × 27 mm (thickness × width × length). This specimen type offers the utilization of limited amount of test material or broken halves of precracked Charpy and larger specimens. The test material comes from the broken halves of 0.5T SEB specimens previously tested for purposes of the reference temperature determination in Ciemat, Madrid. The fracture toughness tests of specimens were performed in the transition region of the steel according to the recommendations of standard ASTM E1921 and according Wallin’s recommended temperature range for miniaturized specimens. The determined reference temperature of the Master Curve was very similar to the determined ones from three-point-bend specimen of sizes 0.2T, 0.4T and 0.5T. The obtained results confirm a necessity of conduct of tests at low temperatures and testing sufficient number of specimens in order to generate enough valid data for determination of the reference temperature.Copyright