Martin Fally

Neutron optical beam splitter from holographically structured nanoparticle-polymer composites.

We report a breakthrough in the search for versatile diffractive elements for cold neutrons. Nanoparticles are spatially arranged by holographical means in a photopolymer. These grating structures show remarkably efficient diffraction of cold neutrons up to about 50% for effective thicknesses of only 200   μm. They open up a profound perspective for next generation neutron-optical devices with the capability to tune or modulate the neutron diffraction efficiency.

Holographic scattering in photopolymer-dispersed liquid crystals

Strong polarization-conserving holographic scattering was observed in a photopolymer-dispersed liquid crystal film fabricated from the UV curable mixture of commercially available constituents. During the photopolymerization process a bright corona of diffracted light evolves around the pump beam. The intensity of the rotationally symmetric light distribution increases upon exposure. By rotating the sample, two characteristic diffraction rings appear which can be explained by the Ewald sphere construction. Our results demonstrate that the associated parasitic holograms are very pronounced. Hence, their presence must be accounted for whenever preparing and utilizing holographic polymer-dispersed liquid crystals in any application.

Holographic scattering as a technique to determine the activation energy for thermal fixing in photorefractive materials

We introduce holographic scattering as a technique to determine the activation energy for thermal fixing of refractive index patterns in photorefractive crystals. After recording a parasitic hologram at ambient temperature, we measured the time dependence of the transmitted intensity at the fixing temperature, to determine the time constant. The temperature dependence of the latter allowed us to evaluate the thermal activation energy. For comparison, we performed an equivalent experiment employing the standard two-wave mixing method. The values obtained using the two techniques agree very well.

Photopolymerizable nanocomposite photonic materials and their holographic applications in light and neutron optics

We present an overview of recent investigations of photopolymerizable nanocomposite photonic materials in which, thanks to their high degree of material selectivity, recorded volume gratings possess high refractive index modulation amplitude and high mechanical/thermal stability at the same time, providing versatile applications in light and neutron optics. We discuss the mechanism of grating formation in holographically exposed nanocomposite materials, based on a model of the photopolymerization-driven mutual diffusion of monomer and nanoparticles. Experimental inspection of the recorded grating’s morphology by various physicochemical and optical methods is described. We then outline the holographic recording properties of volume gratings recorded in photopolymerizable nanocomposite materials consisting of inorganic/organic nanoparticles and monomers having various photopolymerization mechanisms. Finally, we show two examples of our holographic applications, holographic digital data storage and slow-neutron beam control.

Mirrors for slow neutrons from holographic nanoparticle-polymer free-standing film-gratings

We report on successful tests of holographically arranged grating-structures in nanoparticle-polymer composites in the form of 100 microns thin free-standing films, i.e. without sample containers or covers that could cause unwanted absorption/incoherent scattering of very-cold neutrons. Despite their large diameter of 2 cm, the flexible materials are of high optical quality and yield mirror-like reflectivity of about 90% for neutrons of 4.1 nm wavelength.

Nanoparticle polymer composite volume gratings incorporating chain transfer agents for holography and slow-neutron optics

We demonstrate twofold enhancement of the saturated refractive index modulation (Δn(sat)) recorded in a photopolymerizable nanoparticle-acrylate polymer composite film by incorporating thiols acting as chain transfer agents. The chain transfer reaction of thiols with (meth)acrylate monomer reduces the polymer crosslinking density and facilitates the mutual diffusion of nanoparticles and monomer during holographic exposure. These modifications provide increased density modulations of nanoparticles and the formed polymer, resulting in the enhancement of Δn(sat) as high as 1.6×10(-2) at a wavelength of 532 nm. The incorporation of thiols also leads to shrinkage suppression and to improvement of the gratings spatial frequency response. Such simultaneous improvement is very useful for holographic applications in light and neutron optics.

Out-of-phase mixed holographic gratings : a quantative analysis

We show, that by performing a simultaneous analysis of the angular dependencies of the +/- first and the zeroth diffraction orders of mixed holographic gratings, each of the relevant parameters can be obtained: the strength of the phase grating and the amplitude grating, respectively, as well as a potential phase between them. Experiments on a pure lithium niobate crystal are used to demonstrate the applicability of the analysis.

The photo-neutronrefractive effect

Abstract.Since its discovery in 1966, the photorefractive effect, i.e. the change of the refractive index upon illumination with light, has been studied extensively in various materials and has turned out to play a key role in modern optical technologies like photonics. This article focuses on substances that change their refractive index for neutrons when irradiated with light. In analogy to light optics, we call them photo-neutronrefractive. After a short introduction to the relevant concepts of neutron optics, two materials exhibiting this effect, a photopolymer and an electrooptic crystal, are presented. Further, we discuss the progress made concerning the development of creating light-induced gratings for neutron diffraction, which culminated in the setup of an interferometer for cold neutrons. Experiments performed on photo-neutronrefractive materials are surveyed and the variety of corresponding results obtained is presented, including a discussion of their impact on material science, neutron optics, and the foundations of physics.

An experimental study on the validity of diffraction theories for off-Bragg replay of volume holographic gratings

We show that experiments clearly verify the assumptions made by the first-order two-wave coupling theory for one dimensional lossless unslanted planar volume holographic gratings using the beta-value method rather than Kogelnik’s K-vector closure method. Apart from the fact that the diffraction process is elastic, a much more striking difference between the theories becomes apparent particularly in the direction of the diffracted beam in off-Bragg replay. We therefore monitored the direction of the diffracted beam as a function of the off-Bragg replay angle in two distinct cases: [a] the diffracted beam lies in the plane of incidence and [b] the sample surface normal, the grating vector and the incoming beam do not form a plane which calls for the vectorial theory and results in conical scattering.

Three-port beam splitter for slow neutrons using holographic nanoparticle-polymer composite diffraction gratings

Diffraction of slow neutrons by nanoparticle-polymer composite gratings has been observed. By carefully choosing grating parameters such as grating thickness and spacing, a three-port beam splitter operation for slow neutrons—splitting the incident neutron intensity equally into the ±1st and the 0th diffraction orders—has been realized. As a possible application, a Zernike three-path interferometer is briefly discussed.