Martin Steinbrück

Reflooding experiments with LWR-type fuel rod simulators in the QUENCH facility

Abstract The QUENCH experiments at the Karlsruhe Research Center are carried out to investigate the hydrogen generated during reflooding of an uncovered Light Water Reactor (LWR) core. The QUENCH test bundle is made up of 21 fuel rod simulators approximately 2.5 m long. The Zircaloy-4 rod cladding is identical to that used in PWRs (Pressurized Water Reactors) with respect to material and dimensions. Pellets are made of zirconia to simulate UO2. After a transient phase with a heating rate of 0.5–1 K s−1 water of approx. 395 K is admitted from the bottom when the test bundle has reached its pre-determined temperature. Except for the flooding (quenching) phase, the QUENCH test phases are conducted in an argon/steam atmosphere at 3 g s−1 each. The results of the first two experiments, QUENCH-01 (with pre-oxidation of 300 μm oxide layer thickness at the cladding outside surface) and QUENCH-02 (reference test without pre-oxidation), are compared in the paper. The pre-oxidized LWR fuel rod simulators of QUENCH-01 were quenched from a maximum temperature of ∼1870 K. In the second bundle experiment, QUENCH-02, quenching started at ∼2500 K. Pre-oxidation apparently prevented a temperature escalation in the QUENCH-01 test bundle, while the QUENCH-02 test bundle experienced a temperature excursion which started in the transient phase and lasted throughout the flooding phase. The different behavior of the two experiments is also reflected in hydrogen generation. While the bulk of H2 was produced during pre-oxidation of test QUENCH-01 (30 g), the largest amount, i.e. 170 g, of hydrogen was generated during the reflooding phase of test QUENCH-02, at a maximum production rate of 2.5 g s−1 as compared to 0.08 g s−1 in test QUENCH-01. Similarities between the two experiments exist in the thermo-hydraulics during the quench phase, e.g. in the cooling behavior, the quench temperatures, and quench velocities.

Results of the QUENCH-09 Experiment Compared to QUENCH-07 with Incorporation of B4C Absorber

Abstract The purpose of the QUENCH experimental program at the Karlsruhe Research Center is to investigate the hydrogen source term that results from quenching an uncovered core, to examine the physicochemical behavior of overheated fuel elements under different flooding/cooling conditions, and to create a database for model development and code improvement. The QUENCH-07 and -09 test bundles consisted of 21 rods, 20 of which were electrically heated over a length of 1.024 m. The Zircaloy-4 rod cladding and the grid spacers were identical to those used in Western-type light water reactors (LWRs), whereas the fuel was represented by ZrO2 pellets. In both experiments the central rod was made of an absorber rod with B4C pellets and stainless steel cladding and of a Zircaloy-4 guide tube. Failure of the absorber rod cladding was detected at the same temperature in both experiments, i.e., at ~1555 to 1585 K. After a B4C oxidation phase at ~1720 to 1780 K and a subsequent transient test phase to well above 2000 K, cooling of the test bundle was accomplished by injecting saturated steam at the bottom of the test section. The presence of the B4C absorber material in the central rod triggers the formation of eutectic melts, i.e., melts that are formed far below the melting point of metallic Zircaloy (~2030 K), and the oxidation of boron/carbon/zirconium-containing melt can lead to increased amounts of hydrogen and to production of CO, CO2, and CH4 compared to a bundle without a control rod. The total amount of hydrogen released during the flooding, i.e., cooling, phase was, however, significantly larger in QUENCH-09 (~0.400 kg) than in QUENCH-07 (~0.120 kg). It is conjectured that it is mainly the period of steam starvation prior to the cooling phase of QUENCH-09 (steam flow reduction from 3.3 to 0.4 g/s for a duration of ~11 min) that caused the enhanced zirconium oxidation in the cooling phase of QUENCH-09. This is the revised and updated version of the paper that was presented at the 2004 International Meeting on LWR Fuel Performance in Orlando, Florida, on September 19-22, 2004, under the title “Results of the QUENCH-09 Experiment Compared to QUENCH-07 (LWR-Type Test Bundles with B4C Absorber).”

Hydrogen Generation in Reflooding Experiments with LWR-Type Rod Bundles (QUENCH Program)

Abstract The QUENCH bundle experiments together with pertinent separate-effects tests are run to investigate the hydrogen source term resulting from water injection into an uncovered core of a light water reactor for emergency cooling. The test bundle consists of 21 fuel rod simulators, 20 of which are heated electrically over a length of 1024 mm. The center rod is either an unheated fuel rod simulator or a control rod containing B4C absorber material. The Zircaloy-4 rod cladding and the grid spacers are identical to those used in pressurized water reactors, whereas the fuel is represented by ZrO2 pellets. After transient heating to 2000 K and above, cooling of the test bundle is accomplished by injecting water or steam into the bottom of the test section. Hydrogen generation during cooling was found either to stop almost immediately or to increase for a certain time. Increased hydrogen generation was found in those tests in which local melting occurred, probably as a result of oxidation of the melt containing zirconium. Hydrogen release in the flooding/cooling phase of all QUENCH experiments performed so far seems to be insensitive to the coolant (water or steam) under similar test conditions.

Investigation of Core Degradation (COBE).

Abstract The COBE project started in February 1996 and finished at the end of January 1999. The main objective was to improve understanding of core degradation behaviour during severe accidents through the development of computer codes, the carrying out of experiments and the assessment of the computer codes’ ability to reproduce experimental behaviour. A major effort was devoted to quenching behaviour and a substantial achievement of the project was the design and commissioning of a new facility for the simulation of quenching of intact fuel rods. Two tests, carefully scaled to represent realistic reactor conditions, were carried out in this facility and the hydrogen generated during the quenching process was measured using two independent measuring systems. The codes were able to reproduce the results in the first test, where little hydrogen was generated but not the second test, where the extra steam produced during quenching caused an invigorated Zircaloy oxidation and a substantial hydrogen generation. A number of smaller parametric experiments allowed detailed models to be developed for the absorption of hydrogen and the cracking of cladding during quenching. COBE also investigated other areas concerned with late-phase phenomena. There was no experimental activity – the work included code development and the analysis of experimental data available to the project partners – either from open literature or from other projects such as Phebus-FP. Substantial improvement was made in the codes’ ability to simulate heat transfer in debris beds and molten pools and increased understanding was reached of control rod material interactions, the swelling of irradiated fuel and the movement of molten material to the lower head.

Influence of the Temperature History on Secondary Hydriding and Mechanical Properties of Zircaloy-4 Claddings: An Analysis of the QUENCH-LOCA Bundle Tests

Two out-of-pile bundle tests, QUENCH-L0 and QUENCH-L1, were performed recently at Karlsruhe Institute of Technology (KIT) in the framework of the QUENCH-LOCA program devoted to the investigation of the so-called secondary hydriding of the cladding. The overall objective of this bundle test series is the investigation of ballooning, burst and secondary hydrogen uptake of the cladding under representative design basis accident conditions as well as detailed post-test investigation of cladding mechanical properties to analyze the material behavior with respect to embrittlement. The program was started in 2010 with the QUENCH-L0 commissioning test using 21 electrically heated rods with as-received Zircaloy-4 claddings followed in 2012 by the QUENCH-L1 reference test using the same material. These two tests differ in 1) heat-up rate during the first transient and 2) presence of a cool-down phase before quenching. The maximum heating rate reached during QUENCH-L0 was only 2.5 K/s, whereas the transient phase of QUENCH-L1 was performed with the maximum rate of 7 K/s. The state of the QUENCH-L0 bundle was practically “frozen” immediately after the transient phase by fast injection of two-phase fluid. The reference test QUENCH-L1, was performed with a typical cooling phase after the transient phase. It provides data on Zircaloy-4 cladding embrittlement based on more prototypical temperature history. Post-test neutron radiography and tomography revealed formation of hydrogen bands around the oxidized inner cladding surface in vicinity of the burst openings for both tests. However, the concentration of hydrogen absorbed inside these bands was different for both tests: whereas the maximum hydrogen concentration for QUENCH-L0 reached 2560 wppm, the corresponding value for QUENCH-L1 was only 1690 wppm. Complementary model calculations confirm that the differences in hydrogen concentrations are mainly related to the differences in temperature sequences. Subsequent tensile tests with tube segments at room temperature revealed the dependence of the mechanical behaviour on hydrogen concentration: tubes with hydrogen contents above 1500 wppm were simultaneously double ruptured along the hydrogen bands, whereas tubes with hydrogen concentrations below 1500 wppm failed at the middle of burst openings.Copyright

Nanocrystalline diamond protects Zr cladding surface against oxygen and hydrogen uptake: Nuclear fuel durability enhancement

In this work, we demonstrate and describe an effective method of protecting zirconium fuel cladding against oxygen and hydrogen uptake at both accident and working temperatures in water-cooled nuclear reactor environments. Zr alloy samples were coated with nanocrystalline diamond (NCD) layers of different thicknesses, grown in a microwave plasma chemical vapor deposition apparatus. In addition to showing that such an NCD layer prevents the Zr alloy from directly interacting with water, we show that carbon released from the NCD film enters the underlying Zr material and changes its properties, such that uptake of oxygen and hydrogen is significantly decreased. After 100–170 days of exposure to hot water at 360 °C, the oxidation of the NCD-coated Zr plates was typically decreased by 40%. Protective NCD layers may prolong the lifetime of nuclear cladding and consequently enhance nuclear fuel burnup. NCD may also serve as a passive element for nuclear safety. NCD-coated ZIRLO claddings have been selected as a candidate for Accident Tolerant Fuel in commercially operated reactors in 2020.

Experimental investigation of the late phase of spent fuel pool accidents

Experimental programmes have been carried out in order to investigate the behaviour of nuclear fuel components in high-temperature air atmosphere, which characterises the main conditions of the late phase of spent fuel pool accidents. The tests provided new data on the oxidation of zirconium cladding in different atmospheres, on the oxidation and release of ruthenium from fuel pellets and on the integral behaviour of fuel bundles. The integral test confirmed that water injection into the spent fuel storage pool is the right measure to terminate a severe accident.

H2 PERMEATION BEHAVIOR OF Cr2AlC AND Ti2AlC MAX PHASE COATED ZIRCALOY-4 BY NEUTRON RADIOGRAPHY

Hydrogen uptake by nuclear fuel claddings during normal operation as well as loss of coolant during design basis and severe accidents beyond design basis has a high safety relevance because hydrogen degrade the mechanical properties of the zirconium alloys applied as cladding material. Currently, claddings with enhanced accident tolerance are under development. One group of such accident tolerant fuel (ATF) claddings are zirconium alloys with surface coatings reducing corrosion and high-temperature oxidation rate, as well as the chemical heat and hydrogen release during hypothetical accidents. The hydrogen permeation through the coating is an important parameter ensuring material safety. In this work, the hydrogen permeation of Ti2AlC and Cr2AlC MAX phase coatings on Zircaloy-4 is investigated by means of neutron radiography. Both coatings are robust hydrogen diffusion barriers that effectively suppress hydrogen permeation into the matrix.

Safest Roadmap for Corium Experimental Research in Europe

Severe accident facilities for European safety targets (SAFEST) is a European project networking the European experimental laboratories focused on the investigation of a nuclear power plant (NPP) s ...

SAFEST ROADMAP FOR CORIUM EXPERIMENTAL RESEARCH IN EUROPE

SAFEST (Severe Accident Facilities for European Safety Targets) is a European project networking the European corium experimental laboratories with the objective to establish coordination activitie ...