Marwan Al-Haik

Enhancement of thermal and electrical properties of carbon nanotube polymer composites by magnetic field processing

We show that the thermal and electrical properties of single wall carbon nanotube (CNT)-polymer composites are significantly enhanced by magnetic alignment during processing. The electrical transport properties of the composites are mainly governed by the hopping conduction with localization lengths comparable to bundle diameters. The bundling of nanotubes during the composite processing is an important factor for electrical, and in particular, for thermal transport properties. Better CNT isolation will be needed to reach the theoretical thermal conductivity limit for CNT composites.

Role of polyethylene glycol integrity in specific receptor targeting of carbon nanotubes to cancer cells.

We demonstrate that dispersion of single walled carbon nanotubes (SWNTs) by ultrasonication with phospholipid-polyethylene glycol (PL-PEG) fragments it, thus interfering with its ability to block nonspecific uptake by cells. However, unfragmented PL-PEG promoted specific cellular uptake of targeted SWNTs to two distinct classes of receptors expressed by cancer cells. Since fragmentation is a likely consequence of ultrasonication, a technique commonly used to disperse SWNTs, this maybe a concern for certain applications such as drug delivery.

Adhesion energy in carbon nanotube-polyethylene composite: Effect of chirality

This work presents a study of the adhesion energy between carbon nanotube-polyethylene matrix based on molecular dynamics simulations. Specifically, the study focuses on the influence of carbon nanotube chirality on adhesion energy. It is observed that composites that utilize nanotubes with smaller chiral angles achieve higher adhesion energy, and tend to have smaller diameter and longer cylindrical axes compared to those with larger chiral angles. A zigzag nanotube (zero-chiral angle) undergoes considerable deformation to achieve an equilibrium configuration that has relatively maximum adhesion energy. On the other hand, the armchair nanotube (30° chiral angle) deforms moderately to reach equilibrium with minimal adhesion bonds to the polyethylene matrix.

On and off-axis tension behavior of fiber reinforced polymer composites incorporating multi-walled carbon nanotubes

This investigation experimentally examines the role of multi-walled carbon nanotubes (MWCNTs) on the tension (on-axis tension test) and in-plane shear (off-axis tension test) behaviors of carbon fiber reinforced polymer composites. Both pristine and chemically functionalized MWCNTs were utilized with four different loadings: 0.1, 0.5, 1.0, and 1.5 wt% of epoxy. Our investigation showed that with 1.5 wt% functionalized MWCNTs, failure strain, ultimate strength, and toughness of the off-axis tension test are improved by 39%, 51%, and 121%, respectively. On the contrary, limited improvements were observed for the on-axis tested samples with functionalized or pristine MWCNTs.

Electrical conductivity of synergistically hybridized nanocomposites based on graphite nanoplatelets and carbon nanotubes

In this investigation, a recent model for assessing the electrical conductivity of nanocomposites comprising a single type of conductive nanofiller was expanded to cases with mixtures of nanofillers. The extended model considers electron tunneling as the effective mechanism for insulator-conductor transition. The model was validated with relevant experimental data based on a mono-nanofiller. Using the extended model, the effective electrical conductivity of a nanocomposite comprising both graphite nanoplatelets and carbon nanotubes was investigated. It was observed that the hybridized nanocomposites filled with a mixture of these conductive nanofillers attain, synergistically, enhanced electrical conductivities at lower volume fractions. The lower filler contents assist in preserving the intrinsic properties of the host polymer in support of several applications. It was also observed that the relative aspect ratios of the conductive fillers play significant roles on the electrical conductivity of the hybrid nanocomposite. Simulations revealed that, generally, the addition of minimal amounts of a higher aspect ratio auxiliary phase to a lower aspect ratio main phase enhances the electrical conductivity of the composite by orders of magnitude.

Enhanced vibration damping of carbon fibers-ZnO nanorods hybrid composites

In this study, ZnO nanorods are grown on the surface of polyacrylonitrile based carbon fibers using a low temperature hydrothermal synthesis technique. Bi-layered carbon fiber-ZnO nanorod hybrid composite with epoxy matrix is prepared and tested for vibrational attenuations using dynamic mechanical analysis. Results revealed that the growth of ZnO nanorods on top of carbon fiber increases the damping performance by 50% while causing a slight decrease (∼7%) on the storage modulus. The enhanced damping of the hybrid composites can be related to the frictional mechanisms between the ZnO nanorod/epoxy and nanorod/nanorod interfaces combined with piezoelectric effect of ZnO.

Viscoplastic analysis of structural polymer composites using stress relaxation and creep data

Abstract A structural carbon based composite material has been investigated for its high temperature viscoplastic properties using a model based on an overbearing stress concept and using the data obtained from load relaxation and creep. The time dependent viscoplastic properties were obtained at several load and temperature levels. An elastic–viscoplastic constitutive model (proposed by Gates) was used for the modeling efforts. The model is based on an overstress concept appropriate to inelastic properties of composites. The materials parameters for the model are obtained from a set of load relaxation experiments. The model predictions have been compared to the results of creep tests. The results show that the model is capable of predicting the creep behavior at shorter time periods and lower temperatures. As the temperature is increased or as the creep is prolonged the model predictions deviate from the experimental results.

Hybrid Carbon Fibers/Carbon Nanotubes Structures for Next Generation Polymeric Composites

Pitch-based carbon fibers are commonly used to produce polymeric carbon fiber structural composites. Several investigations have reported different methods for dispersing and subsequently aligning carbon nanotubes (CNTs) as a filler to reinforce polymer matrix. The significant difficulty in dispersing CNTs suggested the controlled-growth of CNTs on surfaces where they are needed. Here we compare between two techniques for depositing the catalyst iron used toward growing CNTs on pitch-based carbon fiber surfaces. Electrochemical deposition of iron using pulse voltametry is compared to DC magnetron iron sputtering. Carbon nanostructures growth was performed using a thermal CVD system. Characterization for comparison between both techniques was compared via SEM, TEM, and Raman spectroscopy analysis. It is shown that while both techniques were successful to grow CNTs on the carbon fiber surfaces, iron sputtering technique was capable of producing more uniform distribution of iron catalyst and thus multiwall carbon nanotubes (MWCNTs) compared to MWCNTs grown using the electrochemical deposition of iron.

Investigating the energy harvesting capabilities of a hybrid ZnO nanowires/carbon fiber polymer composite beam

Hybrid piezoelectric composite structures that are able to convert mechanical energy into electricity have gained growing attention in the past few years. In this work, an energy harvesting composite beam is developed by growing piezoelectric zinc oxide nanowires on the surface of carbon fiber prior to forming structural composites. The piezoelectric behavior of the composite beam was demonstrated under different vibration sources such as water bath sonicator and permanent magnet vibration shaker. The beam was excited at its fundamental natural frequency (43.2 Hz) and the open circuit voltage and the short circuit current were measured to be 3.1 mV and 23 nA, respectively. Upon connecting an optimal resistor (1.2 kΩ) in series with the beam a maximum power output 2.5 nW was achieved.

Patterning the Stiffness of Elastomeric Nanocomposites by Magnetophoretic Control of Cross-linking Impeder Distribution

We report a novel method to pattern the stiffness of an elastomeric nanocomposite by selectively impeding the cross-linking reactions at desired locations while curing. This is accomplished by using a magnetic field to enforce a desired concentration distribution of colloidal magnetite nanoparticles (MNPs) in the liquid precursor of polydimethysiloxane (PDMS) elastomer. MNPs impede the cross-linking of PDMS; when they are dispersed in liquid PDMS, the cured elastomer exhibits lower stiffness in portions containing a higher nanoparticle concentration. Consequently, a desired stiffness pattern is produced by selecting the required magnetic field distribution a priori. Up to 200% variation in the reduced modulus is observed over a 2 mm length, and gradients of up to 12.6 MPa·mm−1 are obtained. This is a significant improvement over conventional nanocomposite systems where only small unidirectional variations can be achieved by varying nanoparticle concentration. The method has promising prospects in additive manufacturing; it can be integrated with existing systems thereby adding the capability to produce microscale heterogeneities in mechanical properties.