Masaji Kato

Slake durability and mineralogical properties of some pyroclastic and sedimentary rocks

Abstract Slake durability of rocks is an important property of rock-mass and rock-materials in geotechnical practice. The slake durability of rocks is closely related to their mineralogical composition. In this paper, mineralogical examinations and slake durability tests for argillaceous clastic rocks, especially pyroclastic rocks, sandstones and mudstones of Neogene Tertiary age from Japan, were performed in order to assess the slake durability and rock alteration process of these rocks as well as to understand the relationship between mineralogy and durability. The mineral composition and textural features of the rocks were studied by means of optical microscopy (OM), X-ray diffractometry (XRD), electron microprobe analysis (EPMA), and scanning electron microscopy (SEM). In addition, the slake durability test was carried out by using the standard testing method of ISRM [Int. J. Rock Mech. Min. Sci. 16 (1979) 148] in distilled water and in the aqueous solutions with dissolved electrolytes of NaCl and CaCl 2 . The pyroclastic rocks and tuffaceous sandstone, rich in di-octahedral and tri-octahedral Fe smectite, respectively, show distinctively different slaking behaviors. The pyroclastic rocks show relatively high slaking (Id 2 =55.5% and Id 10 =10.5%) than the tuffaceous sandstone (Id 2 =94.1% and Id 10 =87.8%, refer to text for Id 2 and Id 10 ). This difference in the slake durability observed in these rocks is due to the microscopic occurrences of smectite present in the interspaces between the particles (pyroclastic rocks) and zeolite cementing the interspaces (tuffaceous sandstone) as alteration minerals. In addition, the durability results of tuffaceous sandstone show that the slake durability decreases as the degree of weathering increases (weathered material Id 2 =88.7% and Id 10 =65.3%). Furthermore, two mudstones of Miocene and Pliocene ages, having different clay mineral compositions (smectite vs. illite+chlorite), show the lowest and the highest slake durability among the tested clastic rocks. Hard mudstone shows the highest (Id 2 =98.1% and Id 10 =95.5%) while the soft mudstone shows the lowest (Id 2 =33.9% and Id 6 =0.4%.) slake durability. Thus, the slake durability of pyroclastic and sedimentary rocks is greatly affected by their mineral composition and texture, and is closely related to their alteration history. Slake durability is also affected by the kind of dissolved electrolyte and its concentration in the aqueous solution, providing some useful information for geotechnical practice.

Permeability of Granite Including Macro-Fracture Naturally Filled with Fine-Grained Minerals

Information on the permeability of rock is essential for various geoengineering projects, such as geological disposal of radioactive wastes, hydrocarbon extraction, and natural hazard risk mitigation. It is especially important to investigate how fractures and pores influence the physical and transport properties of rock. Infiltration of groundwater through the damage zone fills fractures in granite with fine-grained minerals. However, the permeability of rock possessing a fracture naturally filled with fine-grained mineral grains has yet to be investigated. In this study, the permeabilities of granite samples, including a macro-fracture filled with clay and a mineral vein, are investigated. The permeability of granite with a fine-grained mineral vein agrees well with that of the intact sample, whereas the permeability of granite possessing a macro-fracture filled with clay is lower than that of the macro-fractured sample. The decrease in the permeability is due to the filling of fine-grained minerals and clay in the macro-fracture. It is concluded that the permeability of granite increases due to the existence of the fractures, but decreases upon filling them with fine-grained minerals.

Three-dimensional pore geometry and permeability anisotropy of Berea sandstone under hydrostatic pressure: connecting path and tortuosity data obtained by microfocus X-ray CT

Abstract Void space and permeability are two primary factors controlling the movement and storage of fluids in rock and sediments. To investigate fluid flow anisotropy in Berea sandstone, permeability was measured in three perpendicular directions under effective confining pressure as a function of pore pressure. Permeability anisotropy was observed slightly in the normal and in two parallel directions to the bedding planes. We introduced microfocus X-ray computed tomography (CT) as a non-destructive tool and the three-dimensional medial axis (3DMA) method to quantify the flow-relevant geometric properties of the voids structure. Using this apparatus and structure analysis software, we obtained the distributions of pore size, throat size and the number of connecting paths between two faces in an arbitrary region of Berea sandstone. Using these data, we also evaluated the number of connecting paths between two faces and tortuosity within an arbitrary region, and discussed the relationship between permeability anisotropy and voids geometry.