Masakatsu Tsubota

Synthesis of copper/copper oxide nanoparticles by solution plasma

This paper describes the synthesis of copper/copper oxide nanoparticles via a solution plasma, in which the effect of the electrolyte and electrolysis time on the morphology of the products was mainly examined. In the experiments, a copper wire as a cathode was immersed in an electrolysis solution of a K2CO3 with the concentration from 0.001 to 0.50 M or a citrate buffer (pH = 4.8), and was melted by the local-concentration of current. The results demonstrated that by using the K2CO3 solution, we obtained CuO nanoflowers with many sharp nanorods, the size of which decreased with decreasing the concentration of the solution. Spherical particles of copper with/without pores formed when the citrate buffer was used. The pores in the copper nanoparticles appeared when the applied voltage changed from 105 V to 130 V, due to the dissolution of Cu2O.

Global evaluation of closed-loop electron dynamics in quasi-one-dimensional conductors using polarization vortices

We evaluate the quasi-one-dimensional (1D) electron dynamics in a NbSe3 ring crystal using polarization vortex pulses with various azimuthal distributions. The single particle relaxation component reveals a large anisotropy on the crystal, indicating that the electrons in the ring maintain their 1D character. The results also suggest that the polarization vortex evaluates the global polarization property of the closed-loop electron that plays an important role in the quantum correlation phenomena such as the Aharonov-Bohm effect.

Aharonov-Bohm effect in charge-density wave loops with inherent temporal current switching

The Aharonov-Bohm (AB) effect has been accepted and has promoted interdisciplinary scientific activities in modern physics. To observe the AB effect in condensed matter physics, the whole system needs to maintain phase coherence, in a tiny ring of the diameter 1 µm and at low temperatures below 1 K. We report that AB oscillations have been measured at high temperature 79 K by use of charge-density wave (CDW) loops in TaS3 ring crystals. CDW condensate maintained macroscopic quantum coherence, which extended over the ring circumference 85 µm. The periodicity of the oscillations is h/2e in accuracy within a 10 % range. The observation of the CDW AB effect implies Frohlich superconductivity in terms of macroscopic coherence and will provide a novel quantum interference device running at room temperature.

Field-Induced Discommensuration in Charge Density Waves in o-TaS3

We report a synchrotron X-ray study of charge density waves (CDWs) in an o-TaS3 crystal. We found that two independent CDWs coexist in the temperature range of 130 - 50 K. These waves are incommensurate and commensurate CDWs with longitudinal wave vectors qc ¼ 0:252cand 0:250c � , respectively. The temperature and electric current dependences of the intensity of the two CDW satellites were measured. We found that the commensurate CDW was converted to the incommensurate CDW at 80 K by inducing current flow. Our observation was interpreted in terms of the dynamics of topological defects. We determined the edge dislocation configuration from the electric current dependence of the intensity of the two CDWs. The result implies for the first time that discommensurations are induced in the commensurate CDW by applying an electric field.

Surface morphology of a glow discharge electrode in a solution

This paper describes the surface morphology of a glow discharge electrode in a solution. In the experiments detailed in the paper, the effects of electrolysis time, solution temperature, voltage, electrolyte concentration, and surface area on the size of nanoparticles formed and their amount of nanoparticles produced were examined to study the surface morphologies of the electrodes. The results demonstrated that the amount of nanoparticles produced increased proportionally with the electrolysis time and current. When the voltages were below 140 V, surfaces with nanoparticles attached, called “Particles” type surfaces, were formed on the electrode. These surfaces changed and displayed ripples, turning into “Ripple” type surfaces, and the nanoparticle sizes increased with an increase in the amount of nanoparticles produced. In contrast, at voltages over 160 V, the surfaces of the electrodes were either “Random” or “Hole” type and the particle sizes were constant at different amount of nanoparticles produced.

Pulse height reduction effects of single-crystal CVD diamond detector for low-energy heavy ions

The performance of a diamond detector made of single-crystal diamond grown by chemical vapour deposition was studied for heavy ions, having energy of 3 MeV. Energy peaks of these low-energy ions were clearly observed. However, the pulse height for individual incident ion decreases with increasing atomic number of the ions. For understanding this pulse height reduction effect, we calculated the amount of ionizing and non-ionizing energy loss of incident ions in the diamond detector. The results of our calculation suggest the contribution of charge loss mechanisms other than the recombination effect of electron-hole pairs produced along the ionized track. We also mentioned the incomplete charge collection near the boundary region between the metal electrode and the diamond surface.

Ripple formation on a nickel electrode during a glow discharge in a solution

We investigated ripple formation on a nickel electrode during a glow discharge in a solution. A nickel wire was partially melted to produce nanoparticles during glow discharge electrolysis. When the electrolysis time was over 30 min, a ripple pattern was formed on the electrode surface, and particle size increased. In this study, we investigated the relationship between the ripple formation and crystal orientation of the electrode. As a result, the ripple patterns were formed on all planes, except (111)- and (100)-oriented planes; their direction was [001].

High-performance diamond radiation detectors produced by lift-off method

For stable semiconductor detector operation under harsh environments, an ideal single-crystal diamond without a charge trapping centre is required. For this study, a self-standing single-crystal CVD diamond was fabricated using a lift-off method. The reduction of charge trapping factors such as structural defects, point defects, and nitrogen impurities, was attempted using 0.2% of low-methane concentration growth and using a full metal seal chamber. A high-quality self-standing diamond with strong free-exciton recombination emission was obtained. Charge collection efficiencies were 100.1% for holes and 99.8% for electrons, provided that and . Energy resolutions were 0.38% for both holes and electrons. We produced a high-performance diamond radiation detector using the productive lift-off method.

Single-crystal CVD diamond detector for high-resolution particle spectrometry

The performance of a single-crystal diamond detector, grown by chemical vapour deposition, as an energy spectrometer for charged particles was studied. The detector was able to identify four different energies of -particles (5.389, 5.443, 5.486, and 5.545 MeV) thanks to a superior intrinsic energy resolution of (full width at half maximum). The electrode configuration, specifically the electric field configuration inside the diamond crystal, and the electrode materials, strongly affect the energy resolution for charged particles. The charge collection efficiency inside the diamond crystal was for both electrons and holes.

Anisotropic magnetoresistance of charge-density wave ino−TaS3

We report magnetoresistance of charge-density wave (CDW) in