Matthew G. Jackson

The return of subducted continental crust in Samoan lavas

Substantial quantities of terrigenous sediments are known to enter the mantle at subduction zones, but little is known about their fate in the mantle. Subducted sediment may be entrained in buoyantly upwelling plumes and returned to the Earth’s surface at hotspots, but the proportion of recycled sediment in the mantle is small, and clear examples of recycled sediment in hotspot lavas are rare. Here we report remarkably enriched 87Sr/86Sr and 143Nd/144Nd isotope signatures in Samoan lavas from three dredge locations on the underwater flanks of Savai’i island, Western Samoa. The submarine Savai’i lavas represent the most extreme 87Sr/86Sr isotope compositions reported for ocean island basalts to date. The data are consistent with the presence of a recycled sediment component (with a composition similar to the upper continental crust) in the Samoan mantle. Trace-element data show affinities similar to those of the upper continental crust—including exceptionally low Ce/Pb and Nb/U ratios—that complement the enriched 87Sr/86Sr and 143Nd/144Nd isotope signatures. The geochemical evidence from these Samoan lavas significantly redefines the composition of the EM2 (enriched mantle 2; ref. 9) mantle endmember, and points to the presence of an ancient recycled upper continental crust component in the Samoan mantle plume.

Anomalous sulphur isotopes in plume lavas reveal deep mantle storage of Archaean crust

Basaltic lavas erupted at some oceanic intraplate hotspot volcanoes are thought to sample ancient subducted crustal materials. However, the residence time of these subducted materials in the mantle is uncertain and model-dependent, and compelling evidence for their return to the surface in regions of mantle upwelling beneath hotspots is lacking. Here we report anomalous sulphur isotope signatures indicating mass-independent fractionation (MIF) in olivine-hosted sulphides from 20-million-year-old ocean island basalts from Mangaia, Cook Islands (Polynesia), which have been suggested to sample recycled oceanic crust. Terrestrial MIF sulphur isotope signatures (in which the amount of fractionation does not scale in proportion with the difference in the masses of the isotopes) were generated exclusively through atmospheric photochemical reactions until about 2.45 billion years ago. Therefore, the discovery of MIF sulphur in these young plume lavas suggests that sulphur—probably derived from hydrothermally altered oceanic crust—was subducted into the mantle before 2.45 billion years ago and recycled into the mantle source of Mangaia lavas. These new data provide evidence for ancient materials, with negative Δ33S values, in the mantle source for Mangaia lavas. Our data also complement evidence for recycling of the sulphur content of ancient sedimentary materials to the subcontinental lithospheric mantle that has been identified in diamond-hosted sulphide inclusions. This Archaean age for recycled oceanic crust also provides key constraints on the length of time that subducted crustal material can survive in the mantle, and on the timescales of mantle convection from subduction to upwelling beneath hotspots.

An ancient recipe for flood-basalt genesis

Large outpourings of basaltic lava have punctuated geological time, but the mechanisms responsible for the generation of such extraordinary volumes of melt are not well known. Recent geochemical evidence suggests that an early-formed reservoir may have survived in the Earth’s mantle for about 4.5 billion years (ref. 2), and melts of this reservoir contributed to the flood basalt emplaced on Baffin Island about 60 million years ago. However, the volume of this ancient mantle domain and whether it has contributed to other flood basalts is not known. Here we show that basalts from the largest volcanic event in geologic history—the Ontong Java plateau—also exhibit the isotopic and trace element signatures proposed for the early-Earth reservoir. Together with the Ontong Java plateau, we suggest that six of the largest volcanic events that erupted in the past 250 million years derive from the oldest terrestrial mantle reservoir. The association of these large volcanic events with an ancient primitive mantle source suggests that its unique geochemical characteristics—it is both hotter (it has greater abundances of the radioactive heat-producing elements) and more fertile than depleted mantle reservoirs—may strongly affect the generation of flood basalts.

A precision cranial immobilization system for conformal stereotactic fractionated radiation therapy

PURPOSE Conformal radiotherapy has been shown to benefit from precision alignment of patient target to therapy beam (1, 6, 13). This work describes an optimized immobilization system for the fractionated treatment of intracranial targets. A study of patient motion demonstrates the high degree of immobilization which is available. METHODS AND MATERIALS A system using dental fixation and a thermoplastic mask that relocates on a rigid frame is described. The design permits scanning studies using computed tomography (CT) and magnetic resonance imaging (MR), conventional photon radiotherapy, and high precision stereotactic proton radiotherapy to be performed with minimal repositioning variation. Studies of both intratreatment motion and daily setup reliability are performed on patients under treatment for paranasal sinus carcinoma. Multiple radiographs taken during single treatments provide the basis for a three-dimensional (3D) motion analysis. Additionally, studies of orthogonal radiographs used to setup for proton treatments and verification port films from photon treatments are used to establish day to day patient position variation in routine use. RESULTS Net 3D patient motion during any treatment is measured to be 0.9 +/- 0.4 mm [mean +/- standard deviation (SD)] and rotation about any body axis is 0.14 +/- 0.67 degrees (mean +/- SD). Day-to-day setup accuracy to laser marks is limited to 2.3 mm (mean) systematic error and 1.6 mm (mean) random error. CONCLUSION We conclude that the most stringent immobilization requirements of 3D conformal radiotherapy adjacent to critical normal structures can be met with a high precision system such as the one described here. Without the use of pretreatment verification, additional developments in machine and couch design are needed to assure that patient repositioning accuracy is comparable to the best level of patient immobility achievable.

Preservation of Earth-forming events in the tungsten isotopic composition of modern flood basalts

Isotopes isolated after impact Details about how Earth formed are gleaned from the daughter products of certain short-lived radioactive isotopes found in rocks. Rizo et al. describe subtle tungsten isotope variations in rocks from the very deep mantle in Baffin Island and the Ontong Java Plateau (see the Perspective by Dahl). The results suggest that portions of Earth have remained unmixed since it formed. The unmixed deep mantle rocks also imply that Earths core formed from several large impact events. Science, this issue p. 809; see also p. 768 Tungsten isotope ratios in certain rocks suggest an ancient primordial reservoir and early core formation from large impacts. How much of Earths compositional variation dates to processes that occurred during planet formation remains an unanswered question. High-precision tungsten isotopic data from rocks from two large igneous provinces, the North Atlantic Igneous Province and the Ontong Java Plateau, reveal preservation to the Phanerozoic of tungsten isotopic heterogeneities in the mantle. These heterogeneities, caused by the decay of hafnium-182 in mantle domains with high hafnium/tungsten ratios, were created during the first ~50 million years of solar system history, indicating that portions of the mantle that formed during Earth’s primary accretionary period have survived to the present.

Samoan hot spot track on a “hot spot highway”: Implications for mantle plumes and a deep Samoan mantle source

We report new geochemical data for submarine lavas from the Samoan region that greatly enhance the geochemical data set for volcanoes from the hot spot. Additionally, two volcanoes dredged in the northern Lau Basin, Futuna Island and Manatu seamount, are young (<5 Ma), appear to be genetically related, and may have been generated by melting a component of Samoan mantle that has been advected into the region. We also find evidence for three seamounts and one atoll along the Samoan hot spot track that are not geochemically related to Samoa. We use a plate motion model to show that three non-Samoan hot spots, currently active in the Cook-Austral Islands, provided volcanism to the Pacific Plate now in the Samoan region approximately 10–40 Ma. The four interloping volcanoes in the Samoan region exhibit geochemical affinities with the three hot spots. All three hot spots would have left a depleted, viscous, refractory keel that is coupled to the base of the Pacific lithosphere that has been “rafted” to the Samoan region. Therefore, the new data also have implications for the origin of the Samoan hot spot as its origin has been suggested to be a result of either a deep-seated mantle plume or a consequence of lithospheric cracking. Without major modification of the current “propagating lithospheric cracks” model, it is not clear how such cracks could yield melts from the refractory keel present under the Samoan lithosphere. Instead, a region of buoyantly upwelling mantle, or plume, is suggested to generate the shield stage volcanism in the Samoan region.

Samoa reinstated as a primary hotspot trail

The classical model for the generation of hotspot tracks maintains that stationary and deep-seated mantle plumes impinge on overriding tectonic plates, thereby generating age-progressive trails of volcanic islands and seamounts. Samoa has played a key role in discrediting this model and the very existence of mantle plumes, because early geochronological work failed to demonstrate a linear age progression along this chain of islands. Specifically on Savai9i Island, the bulk of the subaerial volcanics is younger than 0.39 Ma, much younger than the 5.1 Ma age predicted from the classical hotspot model and a constant 7.1 cm/yr Pacific plate motion. This discrepancy led to alternative magma-producing mechanisms that involve the cracking of the lithosphere beneath the Samoan islands, as a result of the extensional regime generated by the nearby Tonga Trench. Here we report 40 Ar/ 39 Ar ages from the submarine flanks of Savai9i Island showing that its volcanic construction began as early as 5.0 Ma and in a true intraplate setting. This reinstates Samoa as a primary hotspot trail associated with a deep mantle plume and a linear age progression.

Nickel and helium evidence for melt above the core-mantle boundary

High 3He/4He ratios in some basalts have generally been interpreted as originating in an incompletely degassed lower-mantle source. This helium source may have been isolated at the core–mantle boundary region since Earth’s accretion. Alternatively, it may have taken part in whole-mantle convection and crust production over the age of the Earth; if so, it is now either a primitive refugium at the core–mantle boundary or is distributed throughout the lower mantle. Here we constrain the problem using lavas from Baffin Island, West Greenland, the Ontong Java Plateau, Isla Gorgona and Fernandina (Galapagos). Olivine phenocryst compositions show that these lavas originated from a peridotite source that was about 20 per cent higher in nickel content than in the modern mid-ocean-ridge basalt source. Where data are available, these lavas also have high 3He/4He. We propose that a less-degassed nickel-rich source formed by core–mantle interaction during the crystallization of a melt-rich layer or basal magma ocean, and that this source continues to be sampled by mantle plumes. The spatial distribution of this source may be constrained by nickel partitioning experiments at the pressures of the core–mantle boundary.

Tungsten-182 heterogeneity in modern ocean island basalts

A mantle story told with metal and gas Differences in isotopic compositions of trace elements can help identify how regions of Earths mantle have evolved over time. Mundl et al. identified several ancient domains that have been isolated from mantle homogenization and thus contain signatures of primordial material. Tungsten and helium isotope values indicate fractionation and isolation of these mantle domains just after Earths formation. The findings help constrain ancient processes such as core formation, but also provide insight into unexplained structures in the lower mantle today. Science, this issue p. 66 Tungsten and helium isotopes from the deep mantle require primordial sequestration of metal. New tungsten isotope data for modern ocean island basalts (OIB) from Hawaii, Samoa, and Iceland reveal variable 182W/184W, ranging from that of the ambient upper mantle to ratios as much as 18 parts per million lower. The tungsten isotopic data negatively correlate with 3He/4He. These data indicate that each OIB system accesses domains within Earth that formed within the first 60 million years of solar system history. Combined isotopic and chemical characteristics projected for these ancient domains indicate that they contain metal and are repositories of noble gases. We suggest that the most likely source candidates are mega–ultralow-velocity zones, which lie beneath Hawaii, Samoa, and Iceland but not beneath hot spots whose OIB yield normal 182W and homogeneously low 3He/4He.

Volatile cycling of H2O, CO2, F, and Cl in the HIMU mantle: A new window provided by melt inclusions from oceanic hot spot lavas at Mangaia, Cook Islands

Mangaia hosts the most radiogenic Pb-isotopic compositions observed in ocean island basalts and represents the HIMU (high µ = 238U/204Pb) mantle end-member, thought to result from recycled oceanic crust. Complete geochemical characterization of the HIMU mantle end-member has been inhibited due to a lack of deep submarine glass samples from HIMU localities. We homogenized olivine-hosted melt inclusions separated from Mangaia lavas and the resulting glassy inclusions made possible the first volatile abundances to be obtained from the HIMU mantle end-member. We also report major and trace element abundances and Pb-isotopic ratios on the inclusions, which have HIMU isotopic fingerprints. We evaluate the samples for processes that could modify the volatile and trace element abundances postmantle melting, including diffusive Fe and H2O loss, degassing, and assimilation. H2O/Ce ratios vary from 119 to 245 in the most pristine Mangaia inclusions; excluding an inclusion that shows evidence for assimilation, the primary magmatic H2O/Ce ratios vary up to ∼200, and are consistent with significant dehydration of oceanic crust during subduction and long-term storage in the mantle. CO2 concentrations range up to 2346 ppm CO2 in the inclusions. Relatively high CO2 in the inclusions, combined with previous observations of carbonate blebs in other Mangaia melt inclusions, highlight the importance of CO2 for the generation of the HIMU mantle. F/Nd ratios in the inclusions (30 ± 9; 2σ standard deviation) are higher than the canonical ratio observed in oceanic lavas, and Cl/K ratios (0.079 ± 0.028) fall in the range of pristine mantle (0.02–0.08).