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Featured researches published by Matthias Frebel.


Journal of Organometallic Chemistry | 1986

Übergangsmetall-substituierte acylphosphane und phosphaalkene: VIII. Dicarbonylcyclopentadienyleisen-substituierte phosphaalkene mit Fe-P-einfachbindung: synthese und struktur

Lothar Weber; Klaus Reizig; Matthias Frebel; Roland Boese; Michael Polk

Abstract Phosphaalkenyliron complexes with covalent metal-phosphorus bonds are synthesized from (η5-C5H5)(CO)2FeP(SiMe3)2 and acid chlorides RC(O)Cl (R = Ph, 2,4,6-Me3C6H2, t-Bu). The molecular structure of (Z)-(η5-C5H5)(CO)2FePC(OSi-Me3)(t-Bu) is established by X-ray structure analysis.


Phosphorus Sulfur and Silicon and The Related Elements | 1992

Cycloaddition Reactions with Metallated Diphosphenes

Lothar Weber; Ewald Lücke; Matthias Frebel; Holger Bastian

Abstract Several types of cycloaddition reactions performed with metal-functionalized diphosphenes are discussed.


Chemische Berichte | 1986

Übergangsmetall-substituierte Acylphosphane und Phosphaalkene, IX. Zur Synthese von Phosphaalkenyl-, Mono- und Diacyl- phosphidokomplexen aus [Bis(trimethylsilyl)phosphido]-dicarbonyl(pentamethylcyclopentadienyl)eisen und Carbonsäurechloriden

Lothar Weber; Klaus Reizig; Matthias Frebel


Chemische Berichte | 1990

Zur Reaktion des Diphosphenyl‐Komplexes (η5‐C5Me5)(CO)2Fe – P=P – Aryl (Aryl = 2,4,6‐tBu3C6H2) mit elektronenarmen Alkenen. Röntgenstrukturanalyse des Diphosphetans

Lothar Weber; Matthias Frebel; Roland Boese


New Journal of Chemistry | 1989

Transition metal substituted diphosphenes. XV. On the dipolar [3 + 2] cycloaddition of carbonylic alkynes to the diphosphene [(h5-C5Me5)(CO)2FeP:PC6H2(CMe3)3-2,4,6]. Synthesis and structure of chelates [cyclic] [(h5-C5Me5)(CO)FeC(O)C(COR1):CR2P:PC6H2(CMe3)3-2,4,6] with 1,2-diphospha-1,3-butadiene ligands.

Lothar Weber; Matthias Frebel; Roland Boese


Organometallics | 1989

Transition-metal-substituted diphosphenes. 16. [1 + 4] Cycloaddition of a diphosphene to .alpha.,.beta.-unsaturated carbonyl compounds: synthesis of dihydro-1,2-.lambda.5-oxaphospholes with exocyclic phosphorus-phosphorus double bonds and x-ray structure analysis of [cyclic] (.eta.5-C5Me5)(CO)2FeP[OCH:CHCH2](:PAr) (Ar = 2,4,6-tert-Bu3C6H2)

Lothar Weber; Matthias Frebel; Roland Boese


Organometallics | 1991

Transition-metal-substituted diphosphenes. XXI, [2 + 2] cycloaddition of a diphosphene to maleimide and N-methylmaleimide. X-ray structure analysis of a 4,5-diphospha-2-azabicyclo[3.2.0]hepta-1,3-dione

Lothar Weber; Matthias Frebel; Achim. Mueller; Hartmut. Boegge


Chemische Berichte | 1989

Übergangsmetall-substituierte Diphosphene, XVII: Dipolare [3 + 2]-Cycloadditionen von Carbonyl-aktivierten Alkinen an (η5-C5Me5)(CO)2RuPPAryl (Aryl = 2,4,6-tBu3C6H2). Erste Beispiele einer σ/π-Umlagerung von Diphosphen-Liganden

Lothar Weber; Matthias Frebel; Roland Boese


Zeitschrift für anorganische und allgemeine Chemie | 1992

Übergangsmetall-substituierte Diphosphene. 25. Spaltung der PP-Bindung eines Diphosphens mit N-Methylmaleinsäureimid. Synthese und Struktur eines Bicyclo[3.1.0]-1-aza-4-phosphahexa-2, 6-dions

Lothar Weber; Matthias Frebel; Roland Boese


Angewandte Chemie | 1987

[1 + 4] Cycloaddition of a Diphosphene to Acrolein: Synthesis and Structure of a Dihydro‐1,2λ5‐oxaphosphole with an Exocyclic PP Bond

Lothar Weber; Matthias Frebel; Roland Boese

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Roland Boese

University of Duisburg-Essen

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