Maurice Arnold

(super 230) Th- (super 234) U and (super 14) C ages obtained by mass spectrometry on corals.

In 1988, Fairbanks conducted a drilling expedition off the south coast of Barbados to recover submerged corals contemporaneous with the last deglaciation. Core recovery was excellent and >30 different samples were dated by conventional β-counting techniques (Fairbanks 1989). At about the same time, we developed, at Lamont, the thermal ionization mass spectrometry (TIMS) technique to obtain precise U-Th ages (Edwards 1988), and to compare them with the 14 C estimates measured on the same samples. A surprising result was that the discrepancy between 14 C and U-Th ages increased through time to ca. 3000–3500 yr at ca. 15,000 14 C BP (Bard et al. 1990a). Because the three youngest samples yielded U-Th ages in agreement with their calibrated 14 C ages, we concluded initially that the TIMS U-Th determinations were not only precise, but also accurate, and that the 14 C vs. U-Th data set could be used for a first-order 14 C calibration.

Radiocarbon calibration by means of mass spectrometric 230Th/234U and 14C ages of corals: an updated database including samples from Barbados, Mururoa and Tahiti

As first shown by Bard et al. (1990a), high-precision 230Th-234U ages can be used successfully to calibrate the radiocarbon time scale beyond the high-precision tree-ring calibration that now reaches 11,900 cal BP (Kromer and Spurk 1998). Using mass spectrometric techniques, we measured 14C and 230Th ages on new samples collected from boreholes drilled off the islands of Tahiti and Mururoa (French Polynesia) in order to complement the database previously obtained on Barbados corals (Bard et al. 1990a, 1993).

The North Atlantic atmosphere-sea surface 14C gradient during the Younger Dryas climatic event

Abstract We attempt to quantify the 14C difference between the atmosphere and the North Atlantic surface during a prominent climatic period of the last deglaciation, the Younger Dryas event (YD). Our working hypothesis is that the North Atlantic may have experienced a measurable change in 14C reservoir age due to large changes of the polar front position and variations in the mode and rate of North Atlantic Deep Water (NADW) production. We dated contemporaneous samples of terrestrial plant remains and sea surface carbonates in order to evaluate the past atmosphere-sea surface 14C gradient. We selected terrestrial vegetal macrofossils and planktonic foraminifera (Neogloboquadrina pachyderma left coiling) mixed with the same volcanic tephra (the Vedde Ash Bed) which occurred during the YD and which can be recognized in North European lake sediments and North Atlantic deep-sea sediments. Based on AMS ages from two Norwegian sites, we obtained about 10,300 yr BP for the ‘atmospheric’ 14C age of the volcanic eruption. Foraminifera from four North Atlantic deep-sea cores selected for their high sedimentation rates ( > 10 cm kyr−1) were dated by AMS (21 samples). For each core the raw 14C ages assigned to the ash layer peak is significantly older than the 14C age obtained on land. Part of this discrepancy is due to bioturbation, which is shown by numerical modelling. Nevertheless, after correction of a bioturbation bias, the mean 14C age obtained on the planktonic foraminifera is still about 11,000–11,100 yr BP. The atmosphere-sea surface 14C difference was roughly 700–800 yr during the YD, whereas today it is 400–500 yr. A reduced advection of surface waters to the North Atlantic and the presence of sea ice are identified as potential causes of the high 14C reservoir age during the YD.

EVIDENCE FOR CHANGES IN THE NORTH ATLANTIC DEEP WATER LINKED TO MELTWATER SURGES DURING THE HEINRICH EVENTS

Abstract Deep sea sediment records from North Atlantic cores (40°N–55°N) provide evidence of several massive iceberg discharges, known as Heinrich events, during the last glacial period. High resolution benthic δ 18 O and δ 13 C records from North Atlantic sediment cores were used to monitor the impact of Heinrich events on thermohaline circulation and to estimate the sensitivity of deep oceanic circulation to changes in freshwater input to the North Atlantic surface waters. Our data indicate that major rearrangements of deep-water masses were directly associated with these massive iceberg discharges. To trace in detail the deep water conditions in the North Atlantic, benthic δ 13 C values in several cores were used to generate time slices before, during and after Heinrich event 4 dated at ∼ 35 ka BP. Although North Atlantic Deep Water continued to form during the oxygen isotope stage 3 at 37 ka BP, deep circulation was characterized by an increased incursion of deep waters of southern origin, which reduced the δ 13 C composition of North Atlantic deep waters, particularly in the eastern Atlantic basin. North Atlantic Deep Water production was reduced during Heinrich Layer 4 (HL4 at ∼ 35 ka BP) synchronously with the changes in the surface water hydrology. Deep convection processes may have occurred in areas not affected by the salinity decrease. Soon after HL4 ( ∼ 33 ka BP) the δ 13 C distribution was similar to that before the event. Similarly, a rapid return to initial δ 13 C values was observed at the end of the most clearly defined Heinrich events (HL5, HL4 and HL1). Comparison between deep circulation patterns corresponding to HL4, the Last Glacial Maximum and Heinrich event 1 indicates that each of these periods was characterized by a different circulation state associated with changes in convection sites.

Variations in Atlantic surface ocean paleoceanography, 50°‐80°N: A time‐slice record of the last 30,000 years

Eight time slices of surface-water paleoceanography were reconstructed from stable isotope and paleotemperature data to evaluate late Quaternary changes in density, current directions, and sea-ice cover in the Nordic Seas and NE Atlantic. We used isotopic records from 110 deep-sea cores, 20 of which are accelerator mass spectrometry (AMS)-14C dated and 30 of which have high (>8 cm /kyr) sedimentation rates, enabling a resolution of about 120 years. Paleotemperature estimates are based on species counts of planktonic foraminifera in 18 cores. The δ18O and δ13C distributions depict three main modes of surface circulation: (1) The Holocene-style interglacial mode which largely persisted over the last 12.8 14C ka, and probably during large parts of stage 3. (2) The peak glacial mode showing a cyclonic gyre in the, at least, seasonally ice-free Nordic Seas and a meltwater lens west of Ireland. Based on geostrophic forcing, it possibly turned clockwise, blocked the S-N flow across the eastern Iceland-Shetland ridge, and enhanced the Irminger current around west Iceland. It remains unclear whether surface-water density was sufficient for deepwater formation west of Norway. (3) A meltwater regime culminating during early glacial Termination I, when a great meltwater lens off northern Norway probably induced a clockwise circulation reaching south up to Faeroe, the northward inflow of Irminger Current water dominated the Icelandic Sea, and deepwater convection was stopped. In contrast to circulation modes two and three, the Holocene-style circulation mode appears most stable, even unaffected by major meltwater pools originating from the Scandinavian ice sheet, such as during δ18O event 3.1 and the Bolling. Meltwater phases markedly influenced the European continental climate by suppressing the “heat pump” of the Atlantic salinity conveyor belt. During the peak glacial, melting icebergs blocked the eastward advection of warm surface water toward Great Britain, thus accelerating buildup of the great European ice sheets; in the early deglacial, meltwater probably induced a southward flow of cold water along Norway, which led to the Oldest Dryas cold spell. An electronic supplement of this material may be obtained on a diskette or Anonymous FTP from KOSMOS.AGU.ORG. (LOGIN to AGUs FTP account using ANONYMOUS as the username and GUEST as the password. Go to the right directory by typing CD APEND. Type LS to see what files are available. Type GET and the name of the file to get it. Finally, type EXIT to leave the system.) (Paper 95PA01453, Variations in Atlantic surface ocean paleoceanography, 50°-80°N: A time-slice record of the last 30,000 years, M. Sarnthein et al.) Diskette may be ordered from American Geophysical Union, 2000 Florida Avenue, N.W., Washington, DC 20009;

Radiocarbon Reservoir Ages In The Mediterranean Sea And Black Sea

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Changes in sea surface hydrology associated with Heinrich event 4 in the North Atlantic Ocean between 40° and 60°N

We measured apparent marine radiocarbon ages for the Mediterranean Sea, Black Sea, and Red Sea by accel- erator mass spectrometry radiocarbon analyses of 26 modern, pre-bomb mollusk shells collected living between AD 1837 and 1950. The marine reservoir (R(t)) ages were estimated at some 390 ± 85 yr BP, 415 ± 90 yr BP and 440 ± 40 yr BP, respec- tively. R(t) ages in the Mediterranean Sea and Black Sea are comparable to those for the North Atlantic Ocean (<65° N), in accordance with the modern oceanic circulation pattern. The DR values of about 35 ± 70 yr and 75 ± 60 yr in the Mediterra- nean area show that the global box-diffusion carbon model, used to calculate R(t) ages, reproduces the measured marine 14 C R(t) ages in these oceanic areas. Nevertheless, high values of standard deviations, larger than measurement uncertainties are obtained and express decadal R(t) changes. Such large standard deviations are indeed related to a decrease of the apparent marine ages of some 220 yr from 1900 AD to 1930 AD in both the Mediterranean Sea and the western North Atlantic Ocean.

Hydrographic changes of the Southern Ocean (southeast Indian Sector) Over the last 230 kyr

Abstract The changes in distribution of sea surface temperature and salinity in the North Atlantic between 40 and 60°N were reconstructed for the time interval between 40 and 30 kyr BP, which includes the large iceberg discharge event associated with the deposition of Heinrich layer 4. We found that the meltwater input during deposition of Heinrich layer 4 resulted in a 1–2 kyr temperature decrease of about 2°C and a salinity decrease in the range of 1.5‰–3.5‰ between 40 and 50°N. Sites above 50°N did not experience significant salinity variations. A much larger area was affected by the reduction in sea surface temperature. The amplitude of the sea surface temperature shift was, however, much smaller than the atmospheric temperature changes over Greenland at GISP and GRIP sites.

New age data for Mid‐Atlantic Ridge hydrothermal sites: TAG and Snakepit chronology revisited

Hydrographical changes of the southern Indian Ocean over the last 230 kyr, is reconstructed using a 17-m-long sediment core (MD 88 770; 46°01′S 96°28′E, 3290m). The oxygen and carbon isotopic composition of planktonic (N. pachyderma sinistra and G. bulloides) and benthic (Cibicidoides wuellerstorfi, Epistominella exigua, and Melonis barleeanum) foraminifera have been analysed. Changes in sea surface temperatures (SST) are calculated using diatom and foraminiferal transfer functions. A new core top calibration for the Southern Ocean allows an extension of the method developed in the North Atlantic to estimate paleosalinities (Duplessy et al., 1991). The age scale is built using accelerator mass spectrometry (AMS) 14C dating of N. pachyderma s. for the last 35 kyr, and an astronomical age scale beyond. Changes in surface temperature and salinity clearly lead (by 3 to 7 kyr) deep water variations. Thus changes in deep water circulation are not the cause of the early response of the surface Southern Ocean to climatic changes. We suggest that the early warming and cooling of the Southern Ocean result from at least two processes acting in different orbital bands and latitudes: (1) seasonality modulated by obliquity affects the high-latitude ocean surface albedo (sea ice coverage) and heat transfer to and from the atmosphere; (2) low-latitude insolation modulated by precession influences directly the atmosphere dynamic and related precipitation/ evaporation changes, which may significantly change heat transfer to the high southern latitudes, through their control on latitudinal distribution of the major frontal zones and on the conditions of intermediate and deep water formation.

Geomagnetic field control of 14C production over the last 80 Ky: Implications for the radiocarbon time‐scale

The chronologies of TAG and Snakepit hydrothermal fields have been established using 210Pb/Pb, 230Th/234U and 14C dating. At the TAG field, a Mn-oxide record, indicative of low temperature events, began at least 125,000 years and possibly 140,000 years ago with maximum intensities at 15,000, 7000 and 4000 years before present. High temperature events, giving rise to sulfide deposits, began about 100,000 years ago and have been intermittent to the present day. A presently active site has experienced intermittent pulses of activity every 4000 to 6000 years over the past 20,000 years. Decrease in activity is often marked by low temperature aragonite precipitation in chimney conduits at 4000, 7000 and 9000 years ago. After a period of quiescence lasting about 4000 years this site was reactivated about 50 years ago. The Snakepit field is much younger and no sulfides older than 4000 years have been recovered. Relict sulfide deposits are dated between 2000 and 4000 years old indicating this site was active during a quiescent period at TAG. Reactivation of Snakepit. took place about 80 years ago, and is presently concurrent with that of TAG. Comparison with hydrothermal sites on the East Pacific Rise suggests that on slow spreading ridges the major fracture systems focussing the hydrothermal discharge can be reactivated at intervals and new deposits precipitated on top of older ones, while on faster spreading ridges each pulse of activity is separated in space and time resulting in discrete deposits.