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Dive into the research topics where Maurice R. Smith is active.

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Featured researches published by Maurice R. Smith.


Tetrahedron Letters | 1979

Conformational analysis of tertiary cycloalkyl (C6,C7,C8) carbocations using molecular mechanics. Comparison with stable ion experimental data

J. Milton Harris; Steven G. Shafer; Maurice R. Smith; Samuel P. McManus

Abstract Conformational calculations of the 1-methylcyclohexyl, 1-methylcycloheptyl, and 1-methylcyclooctyl cations agree with reported experimental observations.


Tetrahedron Letters | 1983

On the intermediacy of trimethylenechloronium ions

Samuel P. McManus; Maurice R. Smith; M.B. Smith; S.D. Worley

Abstract Semiempirical SCF MO calculations are presented which predict that α, α, α′, α′-tetraalkylethylenechloronium and trimethylenechloronium ions are more stable than some experimentally observed ions with larger ring sizes.


Journal of Organic Chemistry | 1978

Application of molecular mechanics to predict solvolysis rates of polycyclic secondary derivatives

Maurice R. Smith; J. Milton Harris


Journal of Organic Chemistry | 1984

Solution and flash vacuum pyrolyses of 3-arylpropanesulfonyl and 2-(aryloxy)ethanesulfonyl azides. Synthesis of 7- and 8-membered sultams

R. A. Abramovitch; Albert O. Kress; Samuel P. McManus; Maurice R. Smith


Journal of Organic Chemistry | 1978

Neighboring group participation in the conversion of .beta.-substituted ethanesulfonate salts to .beta.-substituted ethanesulfonyl chlorides

Samuel P. McManus; Maurice R. Smith; Frederick T. Herrmann; R. A. Abramovitch


Journal of the American Chemical Society | 1977

Solvolysis of secondary substrates by a limiting mechanism. The cyclooctyl system

J. Milton Harris; Dwight L. Mount; Maurice R. Smith; Samuel P. McManus


Journal of Organic Chemistry | 1984

Thermolysis of sulfonyl azides bearing nucleophilic neighboring groups. A search for anchimeric assistance

Samuel P. McManus; Maurice R. Smith; R. A. Abramovitch; Mercy N. Offor


Journal of Organic Chemistry | 1988

Application of mechanistic and transition-state indicators to endo- and exo-2-norbornyl arenesulfonates. Definition of a new mechanistic indicator

Samuel P. McManus; Maurice R. Smith; Jean M. Shankweiler; Robert V. Hoffman


Journal of Computational Chemistry | 1982

Evaluation of MINDO/3 calculated structures. III. Saturated acyclic compounds with chlorine, nitrogen, oxygen, or sulfur

Samuel P. McManus; Maurice R. Smith; Steven G. Shafer


Tetrahedron Letters | 1978

Some systematic errors in mindo/3 calculations

Samuel P. McManus; Maurice R. Smith

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Samuel P. McManus

University of Alabama in Huntsville

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J. Milton Harris

University of Alabama in Huntsville

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Steven G. Shafer

University of Alabama in Huntsville

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Douglas J. Raber

University of South Florida

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Frederic C. Haupt

University of Alabama in Huntsville

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M.B. Smith

University of Alabama in Huntsville

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Michael D. Dukes

University of South Florida

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Robert V. Hoffman

New Mexico State University

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