Mauricio Ibanez-Mejia

What happens when n= 1000? Creating large-n geochronological datasets with LA-ICP-MS for geologic investigations

The direct age dating of individual mineral components in sedimentary rocks through the analysis of radiogenic parent and daughter isotopes has been routinely applied to better understand sediment provenance and dispersal patterns for several decades. Time, labor, and financial cost—sadly, not scientific inquiry—are typically the determining factors in the number of analyses run for a sedimentary rock sample during provenance investigations. The number of observations reported for detrital zircon provenance investigations using secondary ion mass spectrometers SIMS and laser-ablation inductively-coupled-plasma mass-spectrometers LA-ICP-MS typically range from n = 60–120. In this range, minor, but commonly geological relevant, age components are commonly not identified from the sample aliquot. In addition, the relative proportions of zircon ages from within an age component are typically unreliable for intersample comparisons because the relative proportions of ages from aliquots of n = 60–120 may poorly reflect the ‘true’ proportions of ages from a sample. This study investigates the practicality and usefulness of generating large-n (n = 300–1000) datasets. A LA-MC-ICP-MS and LA-SC-ICP-MS were used to generate four n ≈ 1000 datasets. We show that precision large-n U–Pb detrital zircon datasets can be created using LA-ICP-MS with total sample-run analysis times that are on par with more traditional studies. At best, most provenance investigations based on n = 60–100 have been statistically limited to identifying principle age components. The statistical robustness on n = 1000 datasets not only significantly increase the probability that exotic or low abundance age components (i.e., f < 0.05) are identified in detrital samples, but it allows for the quantitative comparisons between relatively high abundance age components in samples. This potentially transformative outcome of large-n has the potential to stimulate new avenues of research in sedimentology and tectonics.

New age constraints for the Salamanca Formation and lower Río Chico Group in the western San Jorge Basin, Patagonia, Argentina: Implications for cretaceous-paleogene extinction recovery and land mammal age correlations

The Salamanca Formation of the San Jorge Basin (Patagonia, Argentina) preserves critical records of Southern Hemisphere Paleocene biotas, but its age remains poorly resolved, with estimates ranging from Late Cretaceous to middle Paleocene. We report a multi-disciplinary geochronologic study of the Salamanca Formation and overlying Rio Chico Group in the western part of the basin. New constraints include (1) an 40Ar/39Ar age determination of 67.31 ± 0.55 Ma from a basalt flow underlying the Salamanca Formation, (2) micropaleontological results indicating an early Danian age for the base of the Salamanca Formation, (3) laser ablation HR-MC-ICP-MS (high resolution-multi collector-inductively coupled plasma-mass spectrometry) U-Pb ages and a high-resolution TIMS (thermal ionization mass spectrometry) age of 61.984 ± 0.041(0.074)[0.100] Ma for zircons from volcanic ash beds in the Penas Coloradas Formation (Rio Chico Group), and (4) paleomagnetic results indicating that the Salamanca Formation in this area is entirely of normal polarity, with reversals occurring in the Rio Chico Group. Placing these new age constraints in the context of a sequence stratigraphic model for the basin, we correlate the Salamanca Formation in the study area to Chrons C29n and C28n, with the Banco Negro Inferior (BNI), a mature widespread fossiliferous paleosol unit at the top of the Salamanca Formation, corresponding to the top of Chron C28n. The diverse paleobotanical assemblages from this area are here assigned to C28n (64.67–63.49 Ma), ∼2–3 million years older than previously thought, adding to growing evidence for rapid Southern Hemisphere floral recovery after the Cretaceous-Paleogene extinction. Important Peligran and “Carodnia” zone vertebrate fossil assemblages from coastal BNI and Penas Coloradas exposures are likely older than previously thought and correlate to the early Torrejonian and early Tiffanian North American Land Mammal Ages, respectively.

Magmatic history and crustal genesis of western South America: Constraints from U-Pb ages and Hf isotopes of detrital zircons in modern rivers

Western South America provides an outstanding laboratory for studies of magmatism and crustal evolution because it contains Archean–Paleoproterozoic cratons that amalgamated during Neoproterozoic supercontinent assembly, as well as a long history of Andean magmatism that records crustal growth and reworking in an accretionary orogen. We have attempted to reconstruct the growth and evolution of western South America through U-Pb geochronologic and Hf isotopic analyses of detrital zircons from 59 samples of sand mainly from modern rivers. Results from 5524 new U-Pb ages and 1199 new Hf isotope determinations are reported. Our data are integrated with previously published geochronologic and Hf isotopic information, yielding a combined record that includes >42,000 ages and >1900 Hf isotope analyses. These large data sets yield five main conclusions: (1) South America has an age distribution that is similar to most other continents, presumably reflecting processes of crustal generation and/or preservation related to the supercontinent cycle, with age maxima at 2.2–1.8 Ga, 1.6–0.9 Ga, 700–400 Ma, and 360–200 Ma; (2) <200 Ma magmatism in western South America has age maxima at ca. 183, 166, 149, 125, 110, 88, 65, 35, 21, and 4 Ma (with significant north-south and east-west variations), yielding an average cyclicity of ∼33 m.y.; (3) for the past 200 m.y., no correlation exists between magmatism and the velocity of convergence between central South America and Pacific oceanic plates, the age of the downgoing plate, or the absolute motion of South America; (4) Hf isotopes record reworking of older crustal materials during most time periods, with incorporation of juvenile crust at ca. 1.6–1.0 Ga, 500–300 Ma, and ca. 175–35 Ma; and (5) the Hf isotopic signature of <200 Ma magmatism is apparently controlled by the generation of evolved crust during crustal thickening and eastward arc migration, versus juvenile magmas during extensional tectonism and westward and/or outboard migration of arc magmatism.

Relationship of Mesozoic graben development, stress, shortening magnitude, and structural style in the Eastern Cordillera of the Colombian Andes

Abstract We use the Eastern Cordillera of Colombia as an example in early stages of inversion orogen showing still modest values of shortening. The style of deformation recorded in this orogenic chain seems to be strongly influenced by two main factors. The first is the pre-compression geometry of the rift basin, conditioning the strong heterogeneity imparted by a trough filled with Jurassic to Neocomian sediments limited by Precambrian and Palaeozoic high-angle walls. The second factor is the orientation of the stress regime with respect to the main normal faults during the inversion. If the stress field is of pure compression, the normal faults are not extensively inverted and the deformation is accommodated mainly in terms of footwall shortcuts. On the other hand, in transpressive regimes the inversion of the former normal faults is more common and the footwall shortcuts are not dominant structures. No significant lateral variations in tectonic shortening are found in the Eastern Cordillera. Finally we emphasize the role of buckle folds in the internal parts of the inversion orogens and give a cautionary note when interpreting these structures in terms of fault-related folding using the well-documented example of the Soapaga fault area.

Timing of initial seafloor spreading in the Newfoundland-Iberia rift

Broad areas of subcontinental lithospheric mantle are commonly exposed along ocean-continent transition zones in magma-poor rifts and are thought to be exhumed along lithospheric-scale detachment faults during the final stages of rifting. However, the nature of the transition from final rifting to seafloor spreading is controversial. We present the first high-precision U-Pb zircon geochronologic and Hf isotopic data from gabbros that intrude exhumed mantle at Ocean Drilling Program (ODP) Sites 1070 and 1277 in the Newfoundland-Iberia rift (North Atlantic). The sites are conjugate to one another within crust that is commonly considered to have been emplaced during early seafloor spreading. Magnetic data suggest that crustal accretion occurred at both sites during magnetic polarity chrons M3–M0 (130–126 Ma). However, our data indicate that asthenospheric melts were emplaced over brief intervals (≤1 m.y.) prior to or coeval with mantle exhumation at 124 Ma at ODP Site 1070 and 115 Ma at ODP Site 1277. We suggest that this discrepancy is the result of continued mantle exhumation along large, west-dipping detachment faults until lithospheric breakup. The breakup location is likely coincident with the large-amplitude magnetic J anomaly, and our 115 Ma date for magmatism within this anomaly provides the best available age constraint for breakup along the studied transect.

New age constraints for early Paleogene strata of central Patagonia, Argentina: Implications for the timing of South American Land Mammal Ages

The Rio Chico Group in the San Jorge Basin of central Patagonia (Argentina) preserves some of South America’s most significant Paleogene records of biotic and climatic change. Three of its constituent formations, the Penas Coloradas, Las Flores, and Koluel-Kaike, host vertebrate faunas referred to the “ Carodnia faunal zone,” the Itaboraian South American Land Mammal Age (SALMA), and the Riochican SALMA. However, the precise absolute ages of these units, and thus their associated faunas and paleoclimate records, are poorly resolved. Herein, we report new paleomagnetic and geochronologic results from these formations in south-central Chubut Province, Argentina. U-Pb dating of four volcanic ashes, using both laser ablation−multicollector−inductively coupled plasma−mass spectrometry and high-resolution chemical abrasion−isotope dilution−thermal ionization mass spectrometry, indicates ages of igneous crystallization of 51.403 ± 0.037 (0.045) [0.071] Ma for a level within the middle Las Flores Formation and 46.714 ± 0.012 (0.026) [0.057] Ma, 44.579 ± 0.013 (0.026) [0.054] Ma, and 42.856 ± 0.017 (0.027) [0.054] Ma for levels in the lower, middle, and upper Koluel-Kaike Formation, respectively. Combining these with previous isotopic ages in our new magnetostratigraphic framework, we correlate the Penas Coloradas Formation to chrons C27n-26r (ca. 62.5 to ca. 61.6 Ma; late Danian) and the section from the middle Las Flores to the uppermost Koluel-Kaike to chrons C23n to C19r (ca. 51.4−42.2 Ma; mid Ypresian−late Lutetian). We combine these data with other recently published chronostratigraphic results from Paleogene units in Patagonia to better constrain the ages of noteworthy Paleogene plant and mammal fossil sites in Patagonia and to develop a revised temporal calibration of the Las Flores, Vacan, and “Sapoan” faunas.

Linking Late Cretaceous to Eocene Tectonostratigraphy of the San Jacinto Fold Belt of NW Colombia With Caribbean Plateau Collision and Flat Subduction

Collision with and subduction of an oceanic plateau is a rare and transient process that usually leaves an indirect imprint only. Through a tectono-stratigraphic analysis of pre-Oligocene sequences in the San Jacinto fold belt of Northern Colombia, we show the Late Cretaceous to Eocene tectonic evolution of northwestern South America upon collision and ongoing subduction with the Caribbean plate. We linked the deposition of four forearc basin sequences to specific collision/subduction stages and related their bounding unconformities to major tectonic episodes. The Upper Cretaceous Cansona sequence was deposited in a marine forearc setting in which the Caribbean plate was being subducted beneath northwestern South America, producing contemporaneous magmatism in the present-day Lower Magdalena Valley basin. Coeval strike slip faulting by the Romeral wrench fault system accommodated right-lateral displacement due to oblique convergence. In Latest Cretaceous times, the Caribbean plateau collided with South America marking a change to more terrestrially-influenced marine environments characteristic of the upper Paleocene to lower Eocene San Cayetano sequence, also deposited in a forearc setting with an active volcanic arc. A lower to middle Eocene angular unconformity at the top of the San Cayetano sequence, the termination of the activity of the Romeral Fault system and the cessation of arc magmatism are interpreted to indicate the onset of low-angle subduction of the thick and buoyant Caribbean plateau beneath South America, which occurred between 56 and 43 Ma. Flat subduction of the plateau has continued to the present and would be the main cause of amagmatic post-Eocene deposition.