Max Frenzel

Record of paleofluid circulation in faults revealed by hematite (U-TH)/He and apatite fission-track dating: an example from Gower Peninsula Fault Fissures, Wales

Fault rock low-temperature thermochronometry can inform the timing, temperature, and significance of hydrothermal fluid circulation in fault systems. We demonstrate this with combined hematite (U-Th)/He (He) dating, and sandstone apatite fission-track (AFT) and apatite and zircon (U-Th)/He (He) thermochronometry from fault-related fissures on the Gower Peninsula, Wales. Hematite He dates from 141 ± 5.1 Ma to 120 ± 5.0 Ma overlap with a 131 ± 20 Ma sandstone infill AFT date. Individual zircon He dates are 402–260 Ma, reflecting source material erosion, and imply a maximum Late Permian infill depositional age. Burial history reconstruction reveals modern exposures were not buried sufficiently in the Triassic–Early Cretaceous to have caused reheating to temperatures necessary to reset the AFT or hematite He systems, and thus these dates cannot reflect cooling due to erosion alone. Hot fluids circulating through fissures in the Early Cretaceous reset the AFT system. Hematite was either also reset by fluids or precipitated from these fluids. Similar hematite He dates from fault-related mineralization in south Glamorgan (Wales) and Cumbria (England) imply concomitant regional hot groundwater flow along faults. In this example, hydrothermal fluid circulation, coeval with North Atlantic rifting, occurred in higher-permeability fissures and fault veins long after they initially formed, directly influencing local and regional geothermal gradients.

Advanced Identification and Quantification of In-Bearing Minerals by Scanning Electron Microscope-Based Image Analysis

The identification and accurate characterization of discrete grains of rare minerals in sulfide base-metal ores is usually a cumbersome procedure due to the small grain sizes (typically <10 μm) and complex mineral assemblages in the material. In this article, a new strategy for finding and identifying indium minerals, and quantifying their composition and abundance is presented, making use of mineral liberation analysis (MLA) and electron probe microanalysis (EPMA). The method was successfully applied to polymetallic massive sulfide ores from the Neves-Corvo deposit in Portugal. The presence of roquesite and sakuraiite could be systematically detected, their concentration quantified by MLA measurements, and their identity later confirmed by EPMA analyses. Based on these results, an almost complete indium deportment could be obtained for the studied samples. This validates the approach taken, combining automated mineralogy data with electron microprobe analysis. A similar approach could be used to find minerals of other common minor and trace elements in complex base-metal sulfide ores, for example Se, Ge, Sb, or Ag, thus permitting the targeted development of resource technologies suitable for by-product recovery.

Erratum to: On the geological availability of germanium

The original version of this article inadvertently contained a mistake. All numbers referring to the recoverable amounts of germanium hosted by zinc ores, as stated in tables 6 and 9 as well as the main text and abstract of this publication, should be corrected upward by division through 0.67. This correction reflects the fact that reserve/resource data given by the USGS refer to contained zincmetal, while germanium concentrations in the literature refer to sphalerite (zinc sulphide, ZnS) which contains only up to 67 wt.% zinc.