Merritt N. Deeter

Satellite-observed pollution from Southern Hemisphere biomass burning.

Biomass burning is a major source of pollution in the tropical Southern Hemisphere, and fine mode carbonaceous particles are produced by the same combustion processes that emit carbon monoxide (CO). In this paper we examine these emissions with data from the Terra satellite, CO profiles from the Measurement of Pollution in the Troposphere (MOPITT) instrument, and fine-mode aerosol optical depth (AOD) from the Moderate-Resolution Imaging Spectroradiometer (MODIS). The satellite measurements are used in conjunction with calculations from the MOZART chemical transport model to examine the 2003 Southern Hemisphere burning season with particular emphasis on the months of peak fire activity in September and October. Pollutant emissions follow the occurrence of dry season fires, and the temporal variation and spatial distributions of MOPITT CO and MODIS AOD are similar. We examine the outflow from Africa and South America with emphasis on the impact of these emissions on clean remote regions. We present comparisons of MOPITT observations and ground-based interferometer data from Lauder, New Zealand, which indicate that intercontinental transport of biomass burning pollution from Africa often determines the local air quality. The correlation between enhancements of AOD and CO column for distinct biomass burning plumes is very good with correlation coefficients greater than 0.8. We present a method using MOPITT and MODIS data for estimating the emission ratio of aerosol number density to CO concentration which could prove useful as input to modeling studies. We also investigate decay of plumes from African fires following export into the Indian Ocean and compare the MOPITT and MODIS measurements as a way of estimating the regional aerosol lifetime. Vertical transport of biomass burning emissions is also examined using CO profile information. Low-altitude concentrations are very high close to source regions, but further downwind of the continents, vertical mixing takes place and results in more even CO vertical distributions. In regions of significant convection, particularly in the equatorial Indian Ocean, the CO mixing ratio is greater at higher altitudes, indicating vertical transport of biomass burning emissions to the upper troposphere.

Modeling of Submillimeter Passive Remote Sensing of Cirrus Clouds

The scattering properties of cirrus clouds at submillimeter-wave frequencies are analyzed and characterized in this paper. This study lays a theoretical foundation for using radiometric measurements to investigate and monitor cirrus properties from high-flying aircraft or satellite. The significance of this capability is that it would provide data on the global distribution of cloud ice mass that is currently required to validate climate models. At present, these needs remain unmet by existing and planned observational systems. In this study the brightness temperature depression (DTb) of upwelling radiation due to cirrus clouds is simulated at 150, 220, 340, 500, 630, and 880 GHz. The effects of a range of size distributions, eight ice particle shapes, and different atmospheric profiles are modeled. The atmospheric transmission is high enough in the submillimeter windows to allow upper-tropospheric sensing from space, but absorption by water vapor reduces the sensitivity to lower cirrus clouds in a simply predictable manner. It is shown that frequencies above 500 GHz have adequate sensitivity to measure cirrus cloud properties. For these higher frequencies, the DTb is closely proportional to ice water path (IWP) for median mass equivalent sphere diameters (Dme) above 125 mm. The differing sensitivity with frequency allows two channels to determine particle size. A two-channel Bayesian algorithm is developed to assess retrieval accuracy with a Monte Carlo error analysis procedure. Particle shape, size distribution width, and receiver noise are considered as error sources. The rms errors for a nadir view with 630/880 GHz are less than 40% for IWP . 5gm 22 and Dme . 100 mm, while using an oblique viewing angle of 738 results in the same accuracy down to an IWP o f1gm 22 (visible optical depth less than 0.1). The two-channel algorithm and error analysis methods are used to show how submillimeter radiometer and millimeter radar measurements may be combined.

Measurement of low‐altitude CO over the Indian subcontinent by MOPITT

We show that the dayside MOPITT retrievals in the lower troposphere can provide useful information on surface sources of atmospheric CO over the Indian subcontinent. We find that MOPITT retrievals at 850 hPa show localized enhancements over the Indian subcontinent, which correlate with similar enhancements seen in the tropospheric NO2 columns from the SCIAMACHY instrument. In particular, high concentrations of CO over the Indo-Gangetic basin and some prominent cities are captured in the lower-tropospheric retrievals in spring. MOPITT averaging kernels (normalized to take into account the absorber amounts in the layers) indicate that the retrievals are sensitive to CO in the lower troposphere. In winter, MOPITT retrievals at 850 hPa can detect the strongest source areas over the eastern states of Bihar and West Bengal, thus confirming the so-called “Bihar pollution pool,” which was detected earlier in the aerosol measurements by the multiangle imaging spectroradiometer (MISR) aboard Terra. The pollution features are consistent with the spatial distribution of CO emissions in India, as reflected in the GEOS-Chem simulation of CO. Furthermore, these lower-tropospheric features in the simulation are still present after smoothing the modeled fields using the MOPITT averaging kernels and a priori profile, demonstrating that the retrievals do have sensitivity in the lower troposphere. This work indicates that although MOPITT retrievals are often most sensitive to CO in the middle and upper troposphere, they do provide information on lower-tropospheric CO in selected continental regions with strong thermal contrast and could be useful for pollution studies.

21st Century drought-related fires counteract the decline of Amazon deforestation carbon emissions

Tropical carbon emissions are largely derived from direct forest clearing processes. Yet, emissions from drought-induced forest fires are, usually, not included in national-level carbon emission inventories. Here we examine Brazilian Amazon drought impacts on fire incidence and associated forest fire carbon emissions over the period 2003–2015. We show that despite a 76% decline in deforestation rates over the past 13 years, fire incidence increased by 36% during the 2015 drought compared to the preceding 12 years. The 2015 drought had the largest ever ratio of active fire counts to deforestation, with active fires occurring over an area of 799,293 km2. Gross emissions from forest fires (989 ± 504 Tg CO2 year−1) alone are more than half as great as those from old-growth forest deforestation during drought years. We conclude that carbon emission inventories intended for accounting and developing policies need to take account of substantial forest fire emissions not associated to the deforestation process.Deforestation carbon emissions from the Brazilian Amazon have declined steeply, but how much drought-induced forest fire emissions add to this process is still unclear. Here the authors show that gross emissions from forest fires are more than half as great as those from deforestation during drought years.

Comparing optimized CO emission estimates using MOPITT or NOAA surface network observations

This paper compares two global inversions to estimate carbon monoxide (CO) emissions for 2004. Either surface flask observations from the National Oceanic and Atmospheric Administration Earth System Research Laboratory (NOAA/ESRL) Global Monitoring Division (GMD) or CO total columns from the Measurement of Pollution in the Troposphere (MOPITT) instrument are assimilated in a 4D-Var framework. Inferred emission estimates from the two inversions are consistent over the Northern Hemisphere (NH). For example, both inversions increase anthropogenic CO emissions over Europe (from 46 to 94 Tg CO/yr) and Asia (from 222 to 420 Tg CO/yr). In the Southern Hemisphere (SH), three important findings are reported. First, due to their different vertical sensitivity, the stations-only inversion increases SH biomass burning emissions by 108 Tg CO/yr more than the MOPITT-only inversion. Conversely, the MOPITT-only inversion results in SH natural emissions (mainly CO from oxidation of NMVOCs) that are 185 Tg CO/yr higher compared to the stations-only inversion. Second, MOPITT-only derived biomass burning emissions are reduced with respect to the prior which is in contrast to previous (inverse) modeling studies. Finally, MOPITT derived total emissions are significantly higher for South America and Africa compared to the stations-only inversion. This is likely due to a positive bias in the MOPITT V4 product. This bias is also apparent from validation with surface stations and ground-truth FTIR columns. Our results show that a combined inversion is promising in the NH. However, implementation of a satellite bias correction scheme is essential to combine both observational data sets in the SH.

A Novel Ice-Cloud Retrieval Algorithm Based on the Millimeter-Wave Imaging Radiometer (MIR) 150- and 220-GHz Channels

Abstract A novel microwave technique for simultaneously retrieving cirrus ice water path (IWP) and characteristic ice particle size is described. The retrieval algorithm exploits radiance measurements made at 150 and 220 GHz by the airborne Millimeter-Wave Imaging Radiometer (MIR). Other MIR channels additionally are used to test for the presence of liquid clouds and precipitation, which otherwise would have a contaminating effect on the retrievals. Forward radiative transfer modeling was used to generate a two-dimensional retrieval table in which brightness-temperature depressions (relative to clear-sky values) for both microwave channels were recorded as functions of IWP and characteristic particle size for gamma distributions of ice particles. Retrieval errors due to particle shape, size distribution, clear-sky water vapor variability, cirrus-cloud altitude variability, and instrument noise were estimated using Monte Carlo analysis. Particle shape uncertainty is believed to be the dominant source of re...

AMSU-B Observations of Mixed-Phase Clouds over Land

Abstract Measurements from passive microwave satellite instruments such as the Advanced Microwave Sounding Unit B (AMSU-B) are sensitive to both liquid and ice cloud particles. Radiative transfer modeling is exploited to simulate the response of the AMSU-B instrument to mixed-phase clouds over land. The plane-parallel radiative transfer model employed for the study accounts for scattering and absorption from cloud ice as well as absorption and emission from trace gases and cloud liquid. The radiative effects of mixed-phase clouds on AMSU-B window channels (i.e., 89 and 150 GHz) and water vapor line channels (i.e., 183 ± 1, 3, and 7 GHz) are studied. Sensitivities to noncloud parameters, including surface temperature, surface emissivity, and atmospheric temperature and water vapor profiles, are also quantified. Modeling results indicate that both cloud phases generally have significant radiative effects and that the 150- and 183 ± 7-GHz channels are typically the most sensitive channels to integrated cloud...

Operational validation of the MOPITT instrument optical filters

Abstract Optical bandpass filters in the Measurements of Pollution in the Troposphere (MOPITT) satellite remote sensing instrument selectivity limit the throughput radiance to absorptive spectral bands associated with the satellite-observed trace gases CO and CH4. Precise specification of the spectral characteristics of these filters is required to optimize retrieval accuracy. The effects and potential causes of spectral shifts in the optical bandpass filter profiles are described. Specifically, a shift in the assumed bandpass profile produces a relative bias between the calibrated satellite radiances and the corresponding values calculated by an instrument-specific forward radiative transfer model. Conversely, it is shown that the observed bias (as identified and quantified using operational MOPITT satellite radiance data) can be used to determine the relative spectral shift between the nominal (prelaunch) filter profiles and the true operational (in orbit) profiles. Revising both the radiance calibratio...

Effects of a Spectral Surface Reflectance on Measurements of Backscattered Solar Radiation: Application to the MOPITT Methane Retrieval

Abstract The amount of solar radiation emerging from the top of the atmosphere is strongly influenced by the reflectance of the underlying surface. For this reason, some information about the magnitude and the spectral variability of the surface reflectance typically has to be included in the retrieval of atmospheric parameters from reflected solar radiation measurements. Sufficient information about the surface reflectance properties is rarely available, and the integration of this effect in the retrieval might turn out to be a challenge, especially for broadband instruments. In this paper the focus is on the Measurements of Pollution in the Troposphere (MOPITT) remote sensing instrument. Theoretical studies are performed to investigate how a spectrally varying surface reflectance might impact the retrieval of the total column amount of methane from MOPITT radiance measurements, and the current findings are compared to observed biases. However, the findings present herein might be valuable and applicable...

Assessing the impacts of assimilating IASI and MOPITT CO retrievals using CESM-CAM-chem and DART

We show the results and evaluation with independent measurements from assimilating both MOPITT (Measurements Of Pollution In The Troposphere) and IASI (Infrared Atmospheric Sounding Interferometer) retrieved profiles into the Community Earth System Model (CESM). We used the Data Assimilation Research Testbed ensemble Kalman filter technique, with the full atmospheric chemistry CESM component Community Atmospheric Model with Chemistry. We first discuss the methodology and evaluation of the current data assimilation system with coupled meteorology and chemistry data assimilation. The different capabilities of MOPITT and IASI retrievals are highlighted, with particular attention to instrument vertical sensitivity and coverage and how these impact the analyses. MOPITT and IASI CO retrievals mostly constrain the CO fields close to the main anthropogenic, biogenic, and biomass burning CO sources. In the case of IASI CO assimilation, we also observe constraints on CO far from the sources. During the simulation time period (June and July 2008), CO assimilation of both instruments strongly improves the atmospheric CO state as compared to independent observations, with the higher spatial coverage of IASI providing better results on the global scale. However, the enhanced sensitivity of multispectral MOPITT observations to near surface CO over the main source regions provides synergistic effects at regional scales.