Mervyn Roy

Magnetic field induced confinement–deconfinement transition in graphene quantum dots

Massless Dirac particles cannot be confined by an electrostatic potential. This is a problem for making graphene quantum dots but confinement can be achieved with a magnetic field and here general conditions for confined and deconfined states are derived. There is a class of potentials for which the character of the state can be controlled at will. Then a confinement-deconfinement transition occurs which allows the Klein paradox to be probed experimentally in graphene dots. A dot design suitable for this experiment is presented.

Unraveling Quantum Hall Breakdown in Bilayer Graphene with Scanning Gate Microscopy

Investigating the structure of quantized plateaus in the Hall conductance of graphene is a powerful way of probing its crystalline and electronic structure and will also help to establish whether graphene can be used as a robust standard of resistance for quantum metrology. We use low-temperature scanning gate microscopy to image the interplateau breakdown of the quantum Hall effect in an exfoliated bilayer graphene flake. Scanning gate images captured during breakdown exhibit intricate patterns where the conductance is strongly affected by the presence of the scanning probe tip. The maximum density and intensity of the tip-induced conductance perturbations occur at half-integer filling factors, midway between consecutive quantum Hall plateau, while the intensity of individual sites shows a strong dependence on tip-voltage. Our results are well-described by a model based on quantum percolation which relates the points of high responsivity to tip-induced scattering in a network of saddle points separating localized states.

Interface exchange coupling in Co nanoparticles dispersed in a Mn matrix

The structural and magnetic properties of 1.8 nm Co particles dispersed in a Mn matrix by co-depositing pre-formed mass-selected Co clusters with an atomic vapour of Mn onto a common substrate have been studied by using EXAFS (extended x-ray absorption fine structure), XMCD (x-ray magnetic circular dichroism), magnetometry, and theoretical modelling. At low Co volume fraction (5%) Co@Mn shows a significant degree of alloying and the well-defined particles originally deposited become centres of high Co concentration CoMn alloy that evolves from pure Co at the nanoparticle centre to the pure Mn matrix within a few nm. Each inhomogeneity is a core-shell particle with a Co-rich ferromagnetic core in contact with a Co-depleted antiferromagnetic shell. The XMCD reveals that the Co moment localized on the Co atoms within the Co-rich cores is much smaller than the ferromagnetic moment of the Co nanoparticles deposited at the same volume fraction in Ag. Electronic structure calculations indicate that the small magnitude of the core Co moment can be understood only if significant alloying occurs. Monte Carlo modelling replicates the exchange bias (EB) behaviour observed at low temperature from magnetometry measurements. We ascribe EB to the interaction between the ferromagnetic Co-rich cores and the antiferromagnetic Mn-rich shells.

Methane band and Spitzer mid-IR imaging of L and T dwarf candidates in the Pleiades

We present Spitzer observations at [3.6] and [4.5] μm together with the methane short (1.58 μm) − methane long (1.69 μm) colour for three cool dwarfs in the Pleiades, PLZJ23, PLZJ93 and PLZJ100. We determine the effective temperatures of PLZJ23 and PLZJ93 to be ≈1200 and ≈1100 K. From the broad-band photometry we place an upper limit of 1100 K on the effective temperature of PLZJ100 but lack the data required to determine the value more precisely. These temperatures are in the T dwarf regime, yet the methane colours indicate no methane is present. We attribute this to youth/low gravity in line with theoretical expectations. However, we find even less methane is present than predicted by the models. PLZJ23 and PLZJ93 are also very bright in the [3.6] μm waveband (PLZJ100 is not measured) compared to field brown dwarfs which can also be explained by this lack of methane. The definition of the T spectral class is the appearance of methane absorption, so strictly, via this definition, PLZJ93 and PLZJ100 cannot be described as T dwarfs. The colours of these two objects are, however, not compatible with those of L dwarfs. Thus we have a classification problem and cannot assign these objects a (photometric) spectral type.

Probing the intermixing in In(Ga)As∕GaAs self-assembled quantum dots by Raman scattering

We show that Raman scattering is a sensitive technique for probing the degree of Ga intermixing in In(Ga)As∕GaAs self-assembled quantum dots (QDs). The shifts of the QD phonon frequency that we observe are explained by the modification of the strain due to Ga incorporation into the QDs from the GaAs matrix during growth. Using an elastic continuum model, we estimate the average In content of the dots from the QD phonon frequency. The varying amount of intermixing in QDs grown with different In compositions, QD layer thicknesses, growth temperatures, and stacking spacer layer thicknesses are investigated. The Raman data indicate that Ga intermixing is larger for QD samples with low In(Ga)As coverage thickness and∕or high growth temperature and, in multilayered systems, for samples with small GaAs spacer layers.

Amplitude reduction in EXAFS

In real systems, inelastic processes remove photoelectrons from the elastic scattering channel. This reduces the amplitude of the EXAFS causing disagreement between the experimental and theoretically predicted amplitudes. Traditionally these discrepancies were treated by including two semi empirical reduction factors in the data analysis: a mean tree path term, which models the so called extrinsic loss processes, and a constant amplitude reduction factor which accounts for many electron excitations at the absorbing atom. The extrinsic inelastic effects may, however, be modelled more rigorously using a complex exchange and correlation potential. For example the Hedin-Lundqvist (H-L) potential used in most EXAFS data analysis programs. We present a method by which the losses caused by such a potential may be evaluated quickly and easily in the first Born approximation. The losses produced by the H-L potential significantly overestimate those produced by the mean free path alone. Instead the losses appear to agree well with the total reduction given by the semi-empirical reduction factors. These losses do not exhibit the correct low or high energy behaviour but do show excellent agreement with experiment over the range of a typical EXAFS spectrum. We therefore conclude, that the semi-empirical reduction parameters should not be included when data fitting using the H-L potential.

Realizing high magnetic moments in fcc Fe nanoparticles through atomic structure stretch.

We describe the realization of a high moment state in fcc Fe nanoparticles through a controlled change in their atomic structure. Embedding Fe nanoparticles in a Cu(1-x)Au(x) matrix causes their atomic structure to switch from bcc to fcc. Extended x-ray absorption fine structure (EXAFS) measurements show that the structure in both the matrix and the Fe nanoparticles expands as the amount of Au in the matrix is increased, with the data indicating a tetragonal stretch in the Fe nanoparticles. The samples were prepared directly from the gas phase by co-deposition, using a gas aggregation source and MBE-type sources respectively for the nanoparticle and matrix materials. The structure change in the Fe nanoparticles is accompanied by a sharp increase in atomic magnetic moment, ultimately to values of ~2.5 ± 0.3 μ(B)/atom .

Probing atomic structure in magnetic core/shell nanoparticles using synchrotron radiation

Core/shell Fe/Cu and Fe/Au nanoparticles were prepared directly by deposition from the gas phase. A detailed study of the atomic structure in both the cores and shells of the nanoparticles was undertaken by means of extended absorption fine structure (EXAFS) measurements. For Fe/Cu nanoparticles, a Cu shell ∼ 20 monolayers thick appears similar in structure to bulk Cu and is sufficient to cause the structure in the Fe core to switch from body centred cubic (bcc; as in bulk Fe) to face centred cubic. This is not the case for thinner Cu shells, 1-2 monolayers in thickness, in which there is a considerable contraction in nearest-neighbour interatomic distance as the shell structure changes to bcc. In Fe/Au nanoparticles, the crystal structure in the Fe core remains bcc for all Au thicknesses although there is some stretching of the lattice. In thin Au shells ∼ 2 monolayers thick, there is strong contraction in interatomic distances. There does not appear to be significant alloying at the Fe/Au interface.

Atomic structure of embedded Fe nanoclusters as a function of host matrix material: a synchrotron radiation study

The atomic structure of Fe nanoclusters embedded in a range of matrix materials has been studied using synchrotron radiation. In particular, the effect of embedding the clusters in Ag, amorphous carbon (a-C) and a porous C60 matrix is investigated. The embedded cluster samples were prepared by co-deposition using a gas aggregation cluster source. Samples with both dilute and high-volume-filling fraction of clusters, at 4 and 40% respectively, were prepared. Fe K edge EXAFS measurements were used to probe the structure within the clusters. In a Ag matrix, the Fe clusters retain the b.c.c. structure of bulk Fe while in a-C there is evidence for both b.c.c. and f.c.c. structures in the clusters. These results are independent of cluster volume-filling fraction over the range investigated. When embedded in a porous C60 matrix, the Fe clusters oxidize to Fe2O3.

Loss of long-range magnetic order in a nanoparticle assembly due to random anisotropy

We have used soft x-ray photoemission electron microscopy (XPEEM) combined with x-ray magnetic circular dichroism (XMCD) and DC SQUID (superconducting quantum interference device) magnetometry to probe the magnetic ground state in Fe thin films produced by depositing size-selected gas-phase Fe nanoparticles with a diameter of 1.7 nm (~200 atoms) onto Si substrates. The depositions were carried out in ultrahigh vacuum conditions and thicknesses of the deposited film in the range 5–50 nm were studied. The magnetometry data are consistent with the film forming a correlated super-spin glass with a magnetic correlation length ~5 nm. The XPEEM magnetic maps from the cluster-assembled films were compared to those for a conventional thin Fe film with a thickness of 20 nm produced by a molecular beam epitaxy (MBE) source. Whereas a normal magnetic domain structure is observed in the conventional MBE thin film, no domain structure could be observed in any of the nanoparticle films down to the resolution limit of the XMCD based XPEEM (100 nm) confirming the ground state indicated by the magnetometry measurements. This observation is consistent with the theoretical prediction that an arbitrarily weak random anisotropy field will destroy long-range magnetic order.