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Michael Buehl

Ohio State University

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Featured researches published by Michael Buehl.

Journal of the American Chemical Society | 2014

Geometrically enforced donor-facilitated dehydrocoupling leading to an isolable arsanylidine-phosphorane

Brian A. Chalmers; Michael Buehl; Kasun S. Athukorala Arachchige; Alexandra M. Z. Slawin; Petr Kilian

A proximate Lewis basic group facilitates the mild dehydrogenative P-As intramolecular coupling in the phosphine-arsine peri-substituted acenaphthene 3, affording thermally and hydrolytically stable arsanylidine-phosphorane 4 with a sterically accessible two-coordinate arsenic atom. The formation of 4 is thermoneutral due to the dehydrogenation being concerted with the donor coordination. Reaction of 4 with a limited amount of oxygen reveals arsinidene-like reactivity via formation of cyclooligoarsines, supporting the formulation of the bonding in 4 as base-stabilized arsinidene R3P→AsR.

Journal of the American Chemical Society | 1992

Application and evaluation of ab initio chemical shift calculations for boranes and carboranes. How reliable are "accurate" experimental structures?

Michael Buehl; Paul von Ragué Schleyer

Journal of the American Chemical Society | 1990

Structure of Lithium Isodicyclopentadienide and Lithium Cyclopentadienide in Tetrahydrofuran Solution. A Combined NMR, IGLO, and MNDO Study

Leo A. Paquette; Walter Bauer; Mark R. Sivik; Michael Buehl; Martin. Feigel; Paul van Rague Schleyer

Inorganic Chemistry | 1991

On the origin of the antipodal effect in closo-heteroboranes

Michael Buehl; Paul von Ragué Schleyer; Z. Havlas; Drahomír Hnyk; S. Hermanek

Journal of the American Chemical Society | 1993

SN2 reaction at neutral nitrogen: transition state geometries and intrinsic barriers.

Michael Buehl; Henry F. Schaefer

Inorganic Chemistry | 1990

Theoretical refinement of the pentaborane (B5H11) structure. Application of IGLO chemical shift calculations

Paul von Ragué Schleyer; Michael Buehl; Ulrich Fleischer; Wolfram Koch

Journal of the American Chemical Society | 1991

Applications and evaluations of IGLO (individual gauge for localized orbitals) chemical shift calculations for organolithium compounds

Michael Buehl; Nicolaas J. R. van Eikema Hommes; Paul von Ragué Schleyer; Ulrich Fleischer; Werner Kutzelnigg

Inorganic Chemistry | 1993

Molecular structure of 1-aza-closo-dodecaborane(12). Experimental and theoretical refinement

Drahomír Hnyk; Michael Buehl; Paul von Ragué Schleyer; Hans V. Volden; Snefrid Gundersen; Jens Mueller; Peter Paetzold

Inorganic Chemistry | 1993

Theoretical investigation of four-center two-electron bonding involving boron derivatives

Michael L. McKee; Michael Buehl; O. P. Charkin; Paul von Ragué Schleyer

Journal of the American Chemical Society | 1991

Allylborane and its isomers. An ab initio study of the C3BH7 potential energy surface, the barrier to 1,3-shifts in allylboranes, and nonclassical boracyclobutane, cyclopropylborane, and vinylborane structures

Michael Buehl; Paul von Ragué Schleyer; Mustafa A. Ibrahim; Timothy Clark

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Paul von Ragué Schleyer

University of Erlangen-Nuremberg

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P. Von Rague Schleyer

University of Georgia

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Drahomír Hnyk

Academy of Sciences of the Czech Republic

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Alexandra M. Z. Slawin

University of St Andrews

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O. P. Charkin

Russian Academy of Sciences

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David W. H. Rankin

University of Edinburgh

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Heather E. Robertson

University of Edinburgh

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Kasun S. Athukorala Arachchige

University of St Andrews

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Alexander M. Mebel

Florida International University

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Brian A. Chalmers

University of St Andrews

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