Michael J. Donn

The origin and function of dissolved organic matter in agro‐urban coastal streams

[1] Streams draining urban and agriculture catchments are often a source of inorganic nutrients to downstream aquatic ecosystems, but little is known about how changes in land use influence the quality and biodegradability of dissolved organic matter (DOM). We used parallel factor analysis of excitation‐emission fluorescence spectroscopy and biodegradation incubations to examine how DOM composition influences bioavailable dissolved organic carbon (DOC) in surface waters of urban and agricultural catchments during summer (low flow), winter (high flow) and spring (flow recession). Percent bioavailable DOC was variable for all catchments (2–57%) and negatively related to percent humic‐like fluorescence, but positively related to percent protein‐like fluorescence and simple fluorescence metrics of DOM precursor material (fluorescence index and b:a values). Conversely, highly variable DOC concentrations (2–140 mg L −1 ) were negatively related to protein‐like fluorescence and positively related to humic‐like fluorescence. Elevated concentrations of DOC (>30 mg L −1 ) in agro‐urban streams revealed fluorescence indices (<1.3) typical of wetland and forest‐dominated ecosystems, suggesting that enriched stream DOM is either derived from the destabilization of legacy soil carbon or currently produced from remnant wetlands and patches of native vegetation. Overall, we demonstrate that fluorescence characteristics can be used to predict bioavailable DOC in human‐dominated catchments to better understand the flow of carbon and nutrients in aquatic food webs for improved monitoring and management of coastal ecosystems.

Identification of phosphorus export from low-runoff yielding areas using combined application of high frequency water quality data and MODHMS modelling

In basins combining flat-sandy valleys and hilly-bedrock sub-catchments, the assessment of nutrient (phosphorus) exports from low-runoff yielding environments is difficult. To overcome this issue hydrological modelling and high frequency phosphorus measurements were simultaneously employed. A coupled surface water-groundwater interaction model (MODHMS) was used to determine runoff from the low-runoff yielding part of the catchment. The modelling results indicated that the lower catchment contributed less than 10% of annual catchment discharge over a number of weeks during mid-winter. High frequency phosphorus (P) measurements showed a threefold increase in P concentration during this period in 2008, which lasted for 3 weeks. Concentration-discharge analysis suggested that the increase in P concentration was associated with runoff generation processes in the low-runoff yielding sub-catchment. It was estimated that this area contributed 32% of the annual P load though only 2% of total annual discharge in 2008. Both runoff and P contributions occurred during the period when the water table rose to the surface causing inundation. It was shown that the P concentrations in discharge from the low-runoff yielding sub-catchment were similar to those observed in the shallow groundwater layers.

Fate of benzotriazole and 5-methylbenzotriazole in recycled water recharged into an anaerobic aquifer: Column studies

The fate of benzotriazole (BTri) and 5-methylbenzotriazole (5-MeBT) was investigated under anaerobic conditions at nano gram per litre concentrations in large-scale laboratory columns to mimic a managed aquifer recharge replenishment strategy in Western Australia. Investigations of BTri and 5-MeBT sorption behaviour demonstrated mobility of the compounds with retardation coefficients of 2.0 and 2.2, respectively. Degradation processes over a period of 220 days indicated first order biodegradation of the BTri and 5-MeBT under anaerobic aquifer conditions after a biological lag-time of approximately 30-60 days. Biodegradation half-lives of 29 ± 2 and 26 ± 1 days for BTri and 5-MeBT were respectively observed, with no threshold effect to biodegradation observed at the 200 ng L(-1). The detection of degradation products provided further evidence of BTri and 5-MeBT biodegradation. These results suggested that if BTri and 5-MeBT were present in recycled water recharged to the Leederville aquifer, biodegradation during aquifer passage is likely given sufficient aquifer residence times or travel distances between recycled water injection and groundwater extraction.

Concentration effects on biotic and abiotic processes in the removal of 1,1,2-trichloroethane and vinyl chloride using carbon-amended ZVI

A permeable reactive barrier, consisting of both zero valent iron (ZVI) and a biodegradable organic carbon, was evaluated for the remediation of 1,1,2-trichloroethane (1,1,2-TCA) contaminated groundwater. During an 888 day laboratory column study, degradation rates initially stabilized with a degradation half-life of 4.4±0.4 days. Based on the accumulation of vinyl chloride (VC) and limited production of 1,1-dichloroethene (1,1-DCE) and 1,2-dichloroethane (1,2-DCA), the dominant degradation pathway was likely abiotic dichloroelimination to form VC. Degradation of VC was not observed based on the accumulation of VC and limited ethene production. After a step reduction in the influent concentration of 1,1,2-TCA from 170±20 mg L(-1) to 39±11 mg L(-1), the degradation half-life decreased 5-fold to 0.83±0.17 days. The isotopic enrichment factor of 1,1,2-TCA also changed after the step reduction from -14.6±0.7‰ to -0.72±0.12‰, suggesting a possible change in the degradation mechanism from abiotic reductive degradation to biodegradation. Microbiological data suggested a co-culture of Desulfitobacterium and Dehalococcoides was responsible for the biodegradation of 1,1,2-TCA to ethene.

3D exploratory analysis of descriptive lithology records using regular expressions

This paper presents an interactive approach for analyzing a database of descriptive lithology records to locate a specific lithology feature in three-dimensional space. The method uses a regular expression to search individual lithology records, assigning a match score to indicate the relative strength of a search result. Spatial analysis of the resulting match scores generates a three-dimensional representation of the search results, which indicates the likely locations of the lithology feature. The method enables direct analysis of lithology descriptions, which are often characterized by inconsistencies in terminology, accuracy, level of detail, and spatial distribution. Using regular expressions, the approach circumvents the need for manual interpretation and classification of lithology records. The method was applied to a case study area in Western Australia to delineate the extent of three lithology features (clay, calcareous sediments, and iron-rich sediments). The approach is generally applicable for layered lithology features that are regularly documented in a lithology database.