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Michael P. Pompeo

University of South Carolina

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Featured researches published by Michael P. Pompeo.

Polyhedron | 1990

Cluster synthesis—XXVII. New sulphido osmium carbonyl cluster complexes from the pyrolysis of Os6(CO)16(μ4-S)(μ3-S)

Richard D. Adams; Gong Chen; Michael P. Pompeo; Sixiu Sun

Abstract When Os6(CO)16(μ4-S)(μ3-S) (1) was heated to 125°C for 5 h in octane solvent, two new compounds Os6(CO)16(μ-S)2

Journal of Cluster Science | 1992

Reversible formation of an intramolecular agostic CH interaction in a dimanganese complex

Richard D. Adams; Gong Chen; Linfeng Chen; Michael P. Pompeo; Wengan Wu

Agostic interactions of CH bonds with metal atoms are currently of great interest. UV irradiation of Mn2(CO)8 (PMe2Ph)2 in the presence of the HC≡COEt yielded the new compound Mn2(CO)6(PMe2Ph)2 [μ-C(OEt)=C(H)C=C(H)C=O(OEt)],1 that contains a strong agostic interaction of an olefinic CH bond to one of the managanese atoms, Mn...C=2.349(5), Mn...H=2.01(4). This interaction can be removed (reversibly) by CO addition (25°C/1000 psi) to1 to yield the new complex Mn2(CO)7(PMe2Ph)2[μ-C(OEt)=C(H)C=C(H)C=O(OEt)],2.

Journal of the American Chemical Society | 1993

Formation of butenethiolate by the ring opening of tetrahydrothiophene by a triosmium cluster complex

Richard D. Adams; Michael P. Pompeo; Wengan Wu; John H. Yamamoto

Inorganic Chemistry | 1991

Unusual coordination properties of trialkoxysilyl groups in metal cluster complexes. Synthesis, structure, and reactivity of the osmium carbonyl hydrido cluster Os3(CO)9[.mu.3-.eta.3-Si(OEt)3](.mu.-H)

Richard D. Adams; Jeffrey E. Cortopassi; Michael P. Pompeo

Organometallics | 1992

Thermal and photoassisted ring opening of thietane in a triosmium cluster complex

Richard D. Adams; Michael P. Pompeo

Journal of the American Chemical Society | 1991

Ring-opening oligomerization of 3,3-dimethylthietane by a triosmium cluster complex

Richard D. Adams; Michael P. Pompeo

Inorganic Chemistry | 1991

Cluster synthesis. 33. New platinum-osmium carbonyl cluster complexes from Pt sub 2 Os sub 5 (CO) sub 17 (. mu. -H) sub 6 : Synthesis and characterization of PtOs sub 5 (CO) sub 15 (. mu. sub 3 -S)(. mu. -H) sub 6 , PtOs sub 5 (CO) sub 18 (. mu. -H) sub 4 , and PtOs sub 4 (CO) sub 15 (. mu. -H) sub 2

Richard D. Adams; Michael P. Pompeo; Wengan Wu

Inorganic Chemistry | 1991

Cluster synthesis. 32. Hydrogen-rich metal cluster complexes from the reaction of octadecacarbonyltetraosmiumdiplatinum with hydrogen. Synthesis and molecular structures of PtOs5(CO)16(.mu.-H)6, Pt2Os5(CO)17(.mu.-H)6, PtOs6(CO)18(.mu.-H)8, and Pt2Os7(CO)23(.mu.-H)8

Richard D. Adams; Michael P. Pompeo; Wengan Wu

Organometallics | 1992

Carbon-sulfur bond cleavage with a loss of stereochemistry in the ring opening of trans-2,4-diphenylthietane by Os{sub 3}(CO){sub 10}(NCMe){sub 2}

Richard D. Adams; Michael P. Pompeo

Organometallics | 1990

Ring-opening reactions of strained-ring thioethers in metal cluster complexes. Photoinduced transformation of thietane to 2-propenethiolate in a triosmium cluster complex

Richard D. Adams; Michael P. Pompeo

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Richard D. Adams

University of South Carolina

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Wengan Wu

University of South Carolina

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Gong Chen

University of South Carolina

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Jeffrey E. Cortopassi

University of South Carolina

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Judy A. Belinski

University of South Carolina

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James T. Tanner

University of South Carolina

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John H. Yamamoto

University of South Carolina

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Linfeng Chen

University of South Carolina

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Jianguo Yin

University of South Carolina

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Sixiu Sun

University of South Carolina

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