Michael S. Lodge

Dark-field transmission electron microscopy and the Debye-Waller factor of graphene.

Graphenes structure bears on both the materials electronic properties and fundamental questions about long range order in two-dimensional crystals. We present an analytic calculation of selected area electron diffraction from multi-layer graphene and compare it with data from samples prepared by chemical vapor deposition and mechanical exfoliation. A single layer scatters only 0.5% of the incident electrons, so this kinematical calculation can be considered reliable for five or fewer layers. Dark-field transmission electron micrographs of multi-layer graphene illustrate how knowledge of the diffraction peak intensities can be applied for rapid mapping of thickness, stacking, and grain boundaries. The diffraction peak intensities also depend on the mean-square displacement of atoms from their ideal lattice locations, which is parameterized by a Debye-Waller factor. We measure the Debye-Waller factor of a suspended monolayer of exfoliated graphene and find a result consistent with an estimate based on the Debye model. For laboratory-scale graphene samples, finite size effects are sufficient to stabilize the graphene lattice against melting, indicating that ripples in the third dimension are not necessary.

Superb resolution and contrast of transmission electron microscopy images of unstained biological samples on graphene-coated grids

BACKGROUND In standard transmission electron microscopy (TEM), biological samples are supported on carbon films of nanometer thickness. Due to the similar electron scattering of protein samples and graphite supports, high quality images with structural details are obtained primarily by staining with heavy metals. METHODS Single-layered graphene is used to support the protein self-assemblies of different molecular weights for qualitative and quantitative characterizations. RESULTS We show unprecedented high resolution and contrast images of unstained samples on graphene on a low-end TEM. We show for the first time that the resolution and contrast of TEM images of unstained biological samples with high packing density in their native states supported on graphene can be comparable or superior to uranyl acetate-stained TEM images. CONCLUSION Our results demonstrate a novel technique for TEM structural characterization to circumvent the potential artifacts caused by staining agents without sacrificing image resolution or contrast, and eliminate the need for toxic metals. Moreover, this technique better preserves sample integrity for quantitative characterization by dark-field imaging with reduced beam damage. GENERAL SIGNIFICANCE This technique can be an effective alternative for bright-field qualitative characterization of biological samples with high packing density and those not amenable to the standard negative staining technique, in addition to providing high quality dark-field unstained images at reduced radiation damage to determine quantitative structural information of biological samples.

Lubricity of gold nanocrystals on graphene measured using quartz crystal microbalance

In order to test recently predicted ballistic nanofriction (ultra-low drag and enhanced lubricity) of gold nanocrystals on graphite at high surface speeds, we use the quartz microbalance technique to measure the impact of deposition of gold nanocrystals on graphene. We analyze our measurements of changes in frequency and dissipation induced by nanocrystals using a framework developed for friction of adatoms on various surfaces. We find the lubricity of gold nanocrystals on graphene to be even higher than that predicted for the ballistic nanofriction, confirming the enhanced lubricity predicted at high surface speeds. Our complementary molecular dynamics simulations indicate that such high lubricity is due to the interaction strength between gold nanocrystals and graphene being lower than previously assumed for gold nanocrystals and graphite.

InP- and graphene-based grating-gated transistors for tunable THz and mm-wave detection

Plasmon excitation in the two dimensional electron gas (2DEG) of grating-gated high electron mobility transistors (HEMTs) gives rise to terahertz absorption lines, which may be observed via transmission spectroscopy. Such absorption resonances may alter the channel conductance, giving a means for tunable terahertz detection. The transmission spectrum may be calculated analytically by making simplifying assumptions regarding the electron distribution. Such assumptions can limit the usefulness of such analytical theories for device optimization. Indeed, significant differences between experimentally observed resonances and theory have been noted and explained qualitatively as due to additional, unanticipated, sheets of charge in the device. Here, we explore finite element method (FEM) simulations, used to obtain realistic carrier profiles. Simulated plasmon spectra do not support previous explanations of red-shifting due to interactions with additional neighboring charge distributions. Simulations do show unexpected plasmon resonances associated with the unanticipated sheet charge, named virtual-gate, as well as the expected resonances associated with the 2DEG. Plasmonic modes determined from these investigations are able to account for the measured absorption lines which were previously thought to be red-shifted 2DEG plasmons. Additionally, the same simulation approach was applied to proposed graphene-based devices to investigate their plasmon resonance spectra.

Metal-oxide-semiconductor photocapacitor for sensing surface plasmon polaritons

An electronic detector of surface plasmon polaritons (SPP) is reported. SPPs optically excited on a metal surface using a prism coupler are detected by using a close-coupled metal-oxide-semiconductor capacitor. Semitransparent metal and graphene gates function similarly. We report the dependence of the photoresponse on substrate carrier type, carrier concentration, and back-contact biasing.