Michel Franceschi

Changes in induced polarization associated with the sorption of sodium, lead, and zinc on silica sands

Low-frequency dielectric spectroscopy can be measured in terms of a conductance and a phase lag between the electrical current and the electrical field. This conductance and phase lag can be written as into a complex conductivity with both an in-phase and quadrature components that are frequency dependent. In sands, the low-frequency (10 mHz-40 kHz) spectra of the complex conductivity are dominated by the polarization of the electrical double layer (especially the internal part of the electrical double layer called the Stern layer) and the Maxwell-Wagner polarization (typically above 100 Hz). We present a polarization that is able to explain the complex conductivity spectra including the grain size distribution, the porosity, and the complexation of the mineral surface with the ions of the pore water. To test this model, we investigate the sorption of various cations (Na, Pb, Zn) characterized by different affinities with the surface of silica. Sand column experiments were carried out to see the change in the complex conductivity during the advective/dispersive transport of a lead nitrate solution and a zinc sulfate solution, replacing a sodium chloride solution in the pore space of the sand. The complex conductivity model is able to explain the change of the phase over time.

Vertical heterogeneities of hydraulic aquitard parameters: preliminary results from laboratory and in situ monitoring

Abstract A borehole is developed in a shallow multi-layered aquifer and used to derive the porosity, specific storage and hydraulic conductivity of the aquitard. Local values of hydrodynamical parameters are estimated from petrophysical analysis of core samples, and the empirical relationship between porosity and permeability. Vertical diffusivity is determined from the response of the aquitard to a loading cyclic signal using pressure records at different depths. Hydraulic conductivities deduced from the petrophysical analysis ranged from 10−8 to 10−10 m s−1 and are comparable with those of facies of marine/lacustrine clay observed in samples. The permeability values calculated based on diffusivity are within the range 10−9 to 10−11 m s−1 with a quasi-systematic bias of one order of magnitude. These values are average for a larger part of the aquitard and correspond to an integrated value. The methodology retained for the aquitard characterization is discussed with emphasis on the implications for the management of a complex aquifer system. Citation Larroque, F., Cabaret, O., Atteia, O., Dupuy, A., and Franceschi, M., 2013. Vertical heterogeneities of hydraulic aquitard parameters: preliminary results from laboratory and in situ monitoring. Hydrological Sciences Journal, 58 (4), 912–929.

Origine et évolution du soufre au sein de l'aquifère des Sables infra-molassiques du Bassin aquitain

Abstract New data on isotopic composition of sulphur and oxygen in dissolved sulphates are used to determine the origin of sulphate ions (SO 4 2− ) in the water of the Infra-Molassic Sands Eocene aquifer. Two very distinct origins appear: one is the gypsum dissolution, from the molasse, and the second is the pyrite oxidation, present at the bottom of and within the aquifer. These isotopic analyses helped, in agreement with hydrogeology, to identify geochemical basins whose properties modify the chemical water composition. They also highlight the existence of bioreduction areas. To cite this article: L. Andre et al., C. R. Geoscience 334 (2002) 749–756.

On the role of low-permeability beds in the acquisition of F and SO4 concentrations in a multi-layer aquifer, South-West France.

Fluoride (F(-)) commonly threatens groundwater quality. This is the case around the city of Bordeaux (France), where numerous wells tapping the thick and complex Eocene aquifer are contaminated by fluoride, which presents an issue for drinking water supply. The joint analysis of the spatial distribution of fluoride with other species like sulfate suggests that concentrations are mainly related to the occurrence of low-permeability layers containing evaporites or fluorite deposits. In order to identify the origin of the observed concentrations, a radial flow and transport model is implemented at the borehole scale. The hydraulic conductivity of the low-permeability layers and the vertical dispersivity of the aquifer were optimized to match the observed values of sulfate and fluoride concentrations. Interestingly, each of these parameters influences differently the simulated concentrations. This model has been successfully implemented to a neighboring well with the same parameter values, which tests the approach. The major conclusions drawn are: (i) the contamination in fluoride originates from the low-permeability layers, (ii) every low-permeability layer intercepted by the well releases fluoride (iii) Contamination not only originates from pore water of low-permeability layers, but may persist with long-term pumping due to mineral dissolution. As a consequence, fluoride contamination is likely to persist for a long time and the only solution to reduce fluoride concentration in abstracted water is to seal well screens facing low-permeability layers.

The Relative Importance of Saturated Silica Sand Interfacial and Pore Fluid Geochemistry on the Spectral Induced Polarization Response

Author(s): Peruzzo, L; Schmutz, M; Franceschi, M; Wu, Y; Hubbard, SS | Abstract: ©2018. American Geophysical Union. All Rights Reserved. Adsorption at the solid-pore fluid interface is a key mechanism controlling the mobility of nutrients and contaminants in subsurface soils and sediments. The spectral induced polarization (SIP) method has been shown to be sensitive to the quantity and type of adsorbed ions. Extending previous results, we investigated the relevance of pH, solution conductivity, and ion type on the SIP response of saturated silica sand. We also performed adsorption experiments to evaluate whether adsorption plays a relevant role on the effect of saturating solution conductivity and pH. Given their environmental relevance and different electrochemical characteristics, we focused on exploring the influence of Cu2+ and Na+ adsorption on the SIP signature. The adsorption results confirm the expected and modeled pH influence on the adsorption of both Cu2+ and Na+. The measured quadrature conductivity spectra indicate that pH and solution conductivity control the electrical double layer electrochemical state and its capacitive behavior. On the contrary, no appreciable SIP signal changes are associated with ion substitution. The adsorption experiments highlight low values of site occupancy for Na and Cu, which suggests that the effects of pH and fluid conductivity are unrelated to their control on the ion adsorption. We interpret the solution conductivity as a proxy for ionic strength. The relative importance of pH and solution conductivity over ion type helps to further constrain the interpretation of SIP results in field geochemical and biogeochemical characterization and monitoring.