Michel Michaelovitch de Mahiques

Historical record of polycyclic aromatic hydrocarbons (PAHs) and spheroidal carbonaceous particles (SCPs) in marine sediment cores from Admiralty Bay, King George Island, Antarctica

This paper describes the first results of polycyclic aromatic hydrocarbons (PAHs) and spheroidal carbonaceous particles (SCPs) in sediment cores of Admiralty Bay, Antarctica. These markers were used to assess the local input of anthropogenic materials (particulate and organic compounds) as a result of the influence of human occupation in a sub-Antarctic region and a possible long-range atmospheric transport of combustion products from sources in South America. The highest SCPs and PAHs concentrations were observed during the last 30 years, when three research stations were built in the area and industrial activities in South America increased. The concentrations of SCPs and PAHs were much lower than those of other regions in the northern hemisphere and other reported data for the southern hemisphere. The PAH isomer ratios showed that the major sources of PAHs are fossil fuels/petroleum, biomass combustion and sewage contribution generally close to the Brazilian scientific station.

Polycyclic aromatic hydrocarbons (PAHs) in a large South American industrial coastal area (Santos Estuary, Southeastern Brazil): sources and depositional history.

Located in southeastern Brazil, the Santos Estuary has the most important industrial and urban population area of South America. Since the 1950s, increased urbanization and industrialization near the estuary margins has caused the degradation of mangroves and has increased the discharge of sewage and industrial effluents. The main objectives of this work were to determine the concentrations and sources of polycyclic aromatic hydrocarbons (PAHs) in sediment cores in order to investigate the input of these substances in the last 50 years. The PAHs analyses indicated multiple sources of these compounds (oil and pyrolitic origin), basically anthropogenic contributions from biomass, coal and fossil fuels combustion. The distribution of PAHs in the cores was associated with the formation and development of Cubatão industrial complex and the Santos harbour, waste disposal, world oil crisis and the pollution control program, which results in the decrease of organic pollutants input in this area.

Three-dimensional distribution of plastic pellets in sandy beaches: shifting paradigms

Plastic pellets are worldwide contaminants that accumulate in the ocean, especially in sandy beaches, where their historic standing-stock quantification relies on surface sediment samples. We demonstrated these particles present a three-dimensional instead of a simple along-across shore distribution, being found as deep as 2.0 m, with surface layers accounting for <10% of the total abundance in the sediment column. This gradient seemed to be more related to oceanographic rather than anthropic processes, suggesting a general pattern whose applicability to microplastics and sedimentary environments as a whole should be investigated. This poses criticism in the exactness of standing-stock records and demands urgent discussion of sampling protocols.

Anthropogenic influences in a lagoonal environment: a multiproxy approach at the Valo Grande mouth, Cananéia-Iguape system (SE Brazil)

The Cananeia-Iguape system, SE Brazil, consists of a complex of lagoonal channels, located in a United Nations Educational, Scientific and Cultural Organization (UNESCO) Biosphere Reserve. Nevertheless, important environmental changes have occurred in approximately the last 150 yrs due to the opening of an artificial channel, the Valo Grande, connecting the Ribeira de Iguape River to the lagoonal system. Our objective is to assess the historical record of the uppermost layers of the sedimentary column of the lagoonal system in order to determine the history of environmental changes caused by the opening of the artificial channel. In this sense, an integrated geochemical-faunal approach is used. The environmental changes led significant modifications in salinity, in changes of the depositional patterns of sediments and foraminiferal assemblages (including periods of defaunation), and, more drastically, in the input of heavy metals to the coastal environment. The concentrations Pb in the core analyzed here were up to two times higher than the values measured in contaminated sediments from the Santos estuary, the most industrialized coastal zone in Brazil.

Modern sedimentation in the Cabo Frio upwelling system, Southeastern Brazilian shelf

The analyses of U k � 37 paleotemperatures and sedimentological parameters in box cores from the Cabo Frio upwelling zone, southeastern Brazil, were used to understand the modern sedimentation as well as to evaluate the role played by the upwelling process in the sedimentary patterns. Three box-cores located closer to the upwelling area show a general trend of cooling waters taking place in the last 700 years. Since the present upwelling is dependent on local and remote wind regime, a phase of dominating NE winds favors a more effective upward transport of the cold thermocline level South Atlantic Central Water towards the coast. The intensification in the upwelling regime for the last ca. 700 years can be associated with the strengthening of the NE winds off the area and a possible increase of the Brazil Current mesoscale activity. Nevertheless, the lack of significant correlation of the paleotemperatures and most of sedimentological parameters indicate that upwelling is not the only sedimentation mechanism in the area. Also, the comparison of sedimentological parameters reveals that eventual temporal changes are superimposed by the geographical variability. Sedimentation rates vary from 0.26 mm.yr –1 to 0.66 mm.yr –1 .

Characteristics of the sedimentary organic matter on the inner and middle continental shelf between Guanabara Bay and São Francisco do Sul, southeastern Brazilian margin

Abstract A total of 111 Petersen grab sediment samples, collected during two cruises in 1991 and 1993, on the inner and middle continental shelf between Guanabara Bay and Sao Francisco do Sul, on the southeastern Brazilian margin, were analyzed for the purpose of understanding the nature and distribution of the organic matter in the surface sediments. The analysis of the distribution of the different parameters related to the organic matter revealed the existence of an important distinction between the sediments to the south and to the north of the Sao Sebastiao Island. Six sedimentary zones characterized by different mean values of the organic matter parameters can be identified. The analysis of the δ 13 C and C/N ratios distribution suggest an increasing contribution of land derived organic matter toward the north. The distribution of the organic matter in the area can be explained qualitatively by a model of water mass dynamics, which acts over the southeastern shelf of Brazil.

Post-LGM sedimentation on the outer shelf–upper slope of the northernmost part of the São Paulo Bight, southeastern Brazil

Abstract Sedimentary and isotope data as well as 14 C AMS dating on 15 box cores were used to identify the main post-Last Glacial Maximum (LGM) processes in the outer shelf and upper slope of the northernmost part of the Sao Paulo Bight, southeastern Brazil. Results show slight but significant variations in calcium carbonate, total sulphur and nitrogen contents as well as carbon and oxygen isotope ratios. Sedimentation rates, varying from 5 to 184 mm kyr −1 are controlled by the shelf and upper slope morphology, the Brazil Current meander dynamics, and the Coastal Water offshore motion.

An extensive reef system at the Amazon River mouth

A novel Amazonian reef biome was discovered, encompassing large rhodolith and sponge beds under low light, low oxygen, and high POC. Large rivers create major gaps in reef distribution along tropical shelves. The Amazon River represents 20% of the global riverine discharge to the ocean, generating up to a 1.3 × 106–km2 plume, and extensive muddy bottoms in the equatorial margin of South America. As a result, a wide area of the tropical North Atlantic is heavily affected in terms of salinity, pH, light penetration, and sedimentation. Such unfavorable conditions were thought to imprint a major gap in Western Atlantic reefs. We present an extensive carbonate system off the Amazon mouth, underneath the river plume. Significant carbonate sedimentation occurred during lowstand sea level, and still occurs in the outer shelf, resulting in complex hard-bottom topography. A permanent near-bottom wedge of ocean water, together with the seasonal nature of the plume’s eastward retroflection, conditions the existence of this extensive (~9500 km2) hard-bottom mosaic. The Amazon reefs transition from accretive to erosional structures and encompass extensive rhodolith beds. Carbonate structures function as a connectivity corridor for wide depth–ranging reef-associated species, being heavily colonized by large sponges and other structure-forming filter feeders that dwell under low light and high levels of particulates. The oxycline between the plume and subplume is associated with chemoautotrophic and anaerobic microbial metabolisms. The system described here provides several insights about the responses of tropical reefs to suboptimal and marginal reef-building conditions, which are accelerating worldwide due to global changes.

Assessment of the health quality of Ria de Aveiro (Portugal): Heavy metals and benthic foraminifera

This work analyses the distribution of heavy metals in the sediments of Ria de Aveiro (Portugal) assessed by total digestion and sequential chemical extraction of the sediments. The influence of environmental parameters on the living benthic foraminiferal assemblages was studied. The most polluted parts in the Ria de Aveiro are areas where the residence time is high and cohesive sediments are deposited. Organic matter, which is an excellent scavenger for a number of metals, is in general more abundant in the finer deposits of this lagoon, which act as sinks of anthropogenic pollutants. This condition is observed in Aveiro canals and Murtosa channel where sediments with the highest concentrations of Zn, Pb, Cu, and Cr are found. The sediments of Murtosa channel are also enriched in As, Co and Hg. In Aveiro canals the enrichment of heavy metals is mostly related to the past industrial production at their margins (ceramic and metallurgy), whereas in Murtosa channel with effluent discharges of the Chemical Complex of Estarreja. Foraminiferal density and diversity reach higher values near the lagoon mouth under higher marine influence and decline in general under very low-oxygen conditions. Some species seems to be indifferent to the increasing of TOC (e.g. Haynesina germanica and Ammonia tepida) and some have an opportunistic behaviour in areas with very depressed levels of oxygen (e.g. A. tepida and Quinqueloculina seminulum) whereas other species can better tolerate sulphide/reducing conditions (e.g. H. germanica, Bolivina ordinaria, Buliminella elegantissima, Bulimina elongata/gibba and Nonionella stella) a widespread condition in this lagoon. Foraminiferal density and some species are negatively correlated with concentrations of heavy metals. A most sensitive group of species to higher concentrations of heavy metals is identified (such as B. ordinaria, B. pseudoplicata and B. elongata/gibba) and another one of more tolerant species (such as H. germanica A. tepida and Q. seminulum). Foraminifera are more tolerate higher available concentrations (AC) of Zn in any phase than higher AC of Cu adsorbed do clay minerals (F1) and associated with Fe and Mn oxides (F2) and of Pb in F2; the phase F2, probably the most mobile phase, and even phase F1 seems to be more toxic than the increasing of metals in organic matter (F3).

Arsenic and trace metal contents in sediment profiles from the Admiralty Bay, King George Island, Antarctica

Admiralty Bay (Antarctica) hosts three scientific stations (Ferraz, Arctowski and Macchu Picchu), which require the use of fossil fuel as an energy source. Fossil fuels are also considered the main source of pollution in the area, representing important inputs of major pollutants (organic compounds) and trace metals and metalloids of environmental interest. Accordingly, this work presents the results of As, Cd, Cr, Cu, Ni, Pb and Zn in sediment profiles from Admiralty Bay. The sediment results from Ferraz station were slightly higher than the other sampling sites. The highest contents were observed for Cu and Zn (from 44 to 89 mg kg(-1)). Otherwise, by using enrichment factors and geochronology analysis, the most relevant enrichment was observed for As in the samples collected close to the Ferraz station, indicating that increasing As content may be associated with the activities associated with this site.