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Volume 6: Materials Technology; Polar and Arctic Sciences and Technology; Petroleum Technology Symposium | 2012

Development of Corrosion Resistant Steel for Bottom Plates of Crude Oil Tankers and Onboard Evaluation Results

Minoru Ito; Michio Kaneko; Seiji Nishimura; Hidehiko Sato

Pitting corrosion on the bottom plates of cargo oil tanks (COT) in very large crude carriers (VLCC) is very serious problem. Each tank may suffer up to 1,000 pits, with some reaching a depth of as much as 10 mm. As a result, the workload of repairing such pitting corrosions in periodical dock inspection is extremely heavy. Many studies have already been conducted to clarify the mechanism of pitting corrosion, but it has yet to be fully understood.We have clarified the pitting corrosion mechanism through onboard research on some VLCCs and various corrosion tests, in addition to the findings obtained by previous studies. Based on our understanding of the mechanism, we developed a corrosion test method to simulate the corrosive environment within the pits. Furthermore, we developed a new corrosion resistant steel (CRS) with trace amounts of alloying elements. The corrosion rate for CRS is less than one-fifth of conventional steels. Due to its very low alloy content, the weldability and mechanical properties of CRS remain similar to conventional steels. This CRS has already been applied to several VLCCs and we have examined its corrosion resistance through onboard investigations of the two VLCCs. One was for all its uncoated COT bottom plates, which were built of CRS, at the first docking (after 2.5 years). No pits deeper than 4 mm were found in the bottom plates of any COTs. Also, only about twenty pits of 2∼4-mm depth were found. The other was for the bottom plates of six unpainted COTs built of CRS at her first and second dockings (after 2.3 and 5 years). At five years, tens of pits deeper than 4 mm were found in all, but the pit count was much lower than that of VLCCs constructed of conventional steel. Thus, the good corrosion resistance of CRS was confirmed. In addition, it was also revealed through onboard research during a dock inspection that pit growth halted on VLCCs with more than five years service.SOLAS II-1 Cargo Oil Tank Corrosion Protection, which adopts the test method developed by us as the qualification test for bottom plates, comes into effect in 2013. In addition, CRS has already been certified by Class NK as corrosion resistant steel for COT bottom plates.CRS is set to play its part in the safe navigation of oil tankers. Furthermore, CRS does not require a protective coating of paint, which also benefits the global environment by reducing the use of volatile organic compounds.Copyright


Archive | 2009

Titanium material having low contact resistance for use in separator for solid polymer-type fuel cell and process for producing the titanium material

Kazuhiro Takahashi; Kiyonori Tokuno; Hiroshi Kihira; Koki Tanaka; Michio Kaneko


Archive | 2010

Stainless steel, titanium, or titanium alloy solid polymer fuel cell separator and its method of production and method of evaluation of warp and twist of separator

Hiroshi Kihira; Michio Kaneko; Mitsuharu Yamagata; Koki Tanaka; Yoichi Ikematsu; Yoichi Matsuzaki; Kazuoto Kawakami; Wataru Hisada; Suguru Suzuki


Archive | 2006

Various Scale Analyses to Create Functioning Corrosion Products

Masao Kimura; Tadashi Mizoguchi; Hiroshi Kihira; Michio Kaneko


Archive | 2007

Pure titanium or titanium alloy separator for solid polymer fuel cell and method for producing the same

Michio Kaneko; Kazuhiro Takahashi; Kiyonori Tokuno; Hiroshi Kihira; Wataru Hisada


Archive | 2006

Separator for solid polymer electrolyte fuel cell of stainless steel, titanium or titanium alloy, process for producing the same, and method for evaluating warping and twisting of separator

Hiroshi Kihira; Michio Kaneko; Mitsuharu Yamagata; Koki Tanaka; Yoichi Ikematsu; Yoichi Matsuzaki; Kazuto Kawakami; Wataru Hisada; Suguru Suzuki


Archive | 2003

Low-contact-resistance interface structure between separator and carbon material for fuel cell, separator and carbon material used therein, and production method for stainless steel separator for fuel cell

Hiroshi Kihira; Michio Kaneko; Satoshi Akamatsu; Hotaka Homma; Takehide Senuma


Archive | 2007

Solid Polymer Type Fuel Cell Separator and Method of Production of Same

Koki Tanaka; Youichi Ikematsu; Hiroshi Kihira; Michio Kaneko; Wataru Hisada; Tamotsu Itoh


Archive | 2007

Highly corrosion-resistant, rust-prevention coating material, highly corrosion-resistant steel, and steel structure

Makoto Nagasawa; Minoru Ito; Michio Kaneko; Kenji Katoh; Shiro Imai; Masatoshi Kominami; Toshiro Terakawa; Takashi Kumai


Archive | 2003

Cleaning agent and cleaning method for ridding titanium and titanium alloy building materials of discoloration

Michio Kaneko; Kiyonori Tokuno; Hiroshi Shimizu; Takateru Dekura

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Hiroshi Kihira

Nagoya Institute of Technology

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