Publication


Featured researches published by Mikhail S. Alnajjar.


Journal of the American Chemical Society | 1989

Absolute rate expressions for the abstraction of hydrogen by primary, secondary, and tertiary alkyl radicals from thiophenol

James A. Franz; Bruce A. Bushaw; Mikhail S. Alnajjar


Journal of the American Chemical Society | 1992

Effects of adjacent acceptors and donors on the stabilities of carbon-centered radicals

F. G. Bordwell; Xian-Man Zhang; Mikhail S. Alnajjar


Journal of Organic Chemistry | 1986

Absolute rate constants for hydrogen atom abstraction by benzyl radical from thiophenol, tributylstannane, tributylstannane-d, and dicyclohexylphosphine and for the cyclization of the 2-allylbenzyl radical

James A. Franz; Naushadali K. Suleman; Mikhail S. Alnajjar


Journal of Organic Chemistry | 1986

Products and mechanism of the oxidation of 9-methylanthracene by peroxydisulfate. Proton loss and nucleophile addition reactions of the 9-methylanthracene radical cation

Larrie A. Deardurff; Mikhail S. Alnajjar; Donald M. Camaioni


Journal of Organic Chemistry | 1986

Reactions of the 2-allylbenzyl radical: relative and absolute rate constants for abstraction of hydrogen atom from thiophenol, dicyclohexylphosphine, phenols, and arylalkyl donors

James A. Franz; Mikhail S. Alnajjar; Russell D. Barrows; David L. Kaisaki; Donald M. Camaioni; Naushadali K. Suleman


Journal of the American Chemical Society | 1985

Solvent and counterion effects on the stereochemistry and the competition between electron-transfer and SN2 mechanisms in the reactions of (trimethylstannyl)alkalis with bromides

Mikhail S. Alnajjar; Henry G. Kuivila


Journal of Organic Chemistry | 1984

Reactions of cyclopropylcarbinyl halides with (trimethylstannyl)alkalis. Evidence that kinetically free intermediates need not be involved in cyclopropylcarbinyl to 3-butenyl rearrangements

Mikhail S. Alnajjar; Gary F. Smith; Henry G. Kuivila


Journal of the American Chemical Society | 1982

Inversion of configuration in a free-radical process. Mechanisms of the reactions of trimethylstannyl alkalis with (+)-2-bromooctane

Henry G. Kuivila; Mikhail S. Alnajjar


Journal of the American Chemical Society | 1992

A kinetic study of the migration of a phenyl group from sulfur to a carbon radical center: rearrangement of the .alpha.-(phenylthio)benzyl radical

Mikhail S. Alnajjar; James A. Franz


Journal of Organic Chemistry | 2004

Absolute Rate Constants for Reactions of Tributylstannyl Radicals with Bromoalkanes, Episulfides, and α-Halomethyl-Episulfides, -Cyclopropanes, and -Oxiranes: New Rate Expressions for Sulfur and Bromine Atom Abstraction

James A. Franz; Wendy J. Shaw; Claude N. Lamb; Thomas Autrey; Douglas S. Kolwaite; Donald M. Camaioni; Mikhail S. Alnajjar

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