Mikhail Yu. Tretyakov

Speed dependence of collisional relaxation in ground vibrational state of OCS: Rotational behaviour

Accurate experimental data on pressure broadened profiles of (16)O(12)C(32)S pure rotational lines in a broad range of quantum number J have been analyzed taking into account the speed dependence of collisional relaxation. Refined values of collisional self-broadening coefficients are determined and compared to previously known data. New quantitative information on departures of observed line shapes from the traditional Voigt profile is obtained. It is shown that these departures result mainly from the speed dependence of collisional relaxation. Theoretical calculations of self-broadening parameters are performed in the framework of the semiclassical impact Robert-Bonamy formalism where the mean relative molecular speed as well as the Maxwell-Boltzmann distribution of relative speeds is considered. The necessity of allowance for the speed dependence in line shape models is confirmed and satisfactory results have been obtained by arbitrarily limiting the integration of the differential cross section to a finite value of the impact parameter. It is shown for the first time for the whole rotational spectrum that speed dependent models not only improve accuracy of modeling the observed line profiles but also give physically grounded values of collisional relaxation parameters.

Modern Resonator Spectroscopy at Submillimeter Wavelengths

Classical resonator spectroscopy methods have been realized for the first time in the submillimeter wave range. A resonator spectrometer was developed earlier at the IAP RAS on the basis of an open Fabry-Perot resonator excited by the radiation of a backward wave oscillator whose frequency is stabilized by the phase lock loop system. This spectrometer is successfully used for high-precision measurements of the dielectric properties of solid, liquid, and gaseous dielectrics as well as for the metal and coating reflection measurements in the 36-370 GHz range. In this paper, we report an extension of the upper limit of the spectrometer operation frequency to 520 GHz. Features of operation of the main spectrometer systems in the extended frequency range are analyzed. The broadband measurements of absorption in modern MPCVD diamonds are presented. A continuous record of the absorption spectrum of the laboratory atmosphere in the 350-500 GHz range obtained for the first time by the high-sensitivity microwave method is demonstrated. Further prospects for extension of the spectrometer range to terahertz frequencies are discussed.

Subterahertz primary radiation source with ultra narrow spectrum: New application of femtosecond laser comb

The frequency of a primary subterahertz oscillator has been stabilized by phase lock with one of the component of the terahertz frequency comb produced by femtosecond laser pulses. Stabilization allows to reach radiation spectrum with very low phase noise and less than 10 Hz bandwidth.