Miklas Scholz

Carbon Storage and Fluxes within Freshwater Wetlands: a Critical Review

We critically review recent literature on carbon storage and fluxes within natural and constructed freshwater wetlands, and specifically address concerns of readers working in applied science and engineering. Our purpose is to review and assess the distribution and conversion of carbon in the water environment, particularly within wetland systems. A key aim is to assess if wetlands are carbon sinks or sources. Carbon sequestration and fluxes in natural and constructed wetlands located around the world has been assessed. All facets of carbon (solid and gaseous forms) have been covered. We draw conclusions based on these studies. Findings indicate that wetlands can be both sources and sinks of carbon, depending on their age, operation, and the environmental boundary conditions such as location and climate. Suggestions for further research needs in the area of carbon storage in wetland sediments are outlined to facilitate the understanding of the processes of carbon storage and removal and also the factors that influence them.

Constructed wetlands: a review

The first aim of this invited literature review is critically to review and evaluate hydrological, physical and biochemical processes within natural and constructed wetlands. The second aim is to contribute the thoughts of the authors to the discussion with the help of a case study focusing on gully pot liquor treatment. The performances of constructed treatment wetlands with and without macrophytes, and aggregates of different adsorption capacities will be assessed, principle findings highlighted and conclusions, also relevant to the literature review, will be drawn. The relationships between aggregates, microbial and plant communities as well as the reduction of predominantly biochemical oxygen demand, suspended solids and heavy metals are investigated. After maturation of the biomass, which dominates the litter zone, organic and inorganic contaminants are usually reduced similarly for all wetland types. There appears to be no additional benefit in using macrophytes and expensive adsorption media in constructed wetlands.

The Integrated Constructed Wetlands (ICW) concept

The free surface flow Integrated Constructed Wetlands (ICW) concept explicitly combines the objectives of cleansing and managing water flow from farmyards with that of integrating the wetland infrastructure into the landscape and enhancing its biological diversity. This leads to system robustness and sustainability. Hydraulic dissipation, vegetation interception, and evapotranspiration create an additional freeboard at the outlet of each wetland segment and at the point of discharge, thus enhancing hydraulic residence time and cleansing capacity during hydraulic fluxes. The principal design criteria leading to adequate effluent water quality (i.e., molybdate reactive phosphorus less than 1 mg/1) from ICW are that the wetland area needs to be sized by a factor of at least 1.3 times the farmyard area and the aspect ratio for the individual wetland segments (i.e., approximately four cells) needs to be less than 1:2.2 (width to length). Within a year of ICW commissioning, approximately 75% of farmyard runoff was intercepted, leading to improvements in the receiving surface waters of the catchment. Most of the recorded phosphate concentrations after ICW treatment agreed with the Irish Urban Wastewater Treatment Regulation 2001, which can be used as a benchmark to assess ICW treatment performance and which is usually applied unofficially to ICW even if it may appear to be too stringent. A case study of 13 ICW systems suggested that phosphorus exported from an ICW system was similar to the typical background concentrations of phosphorus export rates from land to water.

Performance comparison of experimental constructed wetlands with different filter media and macrophytes treating industrial wastewater contaminated with lead and copper

The aim of this study was to investigate the treatment efficiency of passive vertical-flow wetland filters containing different macrophytes (Phragmites and/or Typha) and granular media with different adsorption capacities. Gravel, sand, granular activated carbon, charcoal and Filtralite (light expanded clay) were used as filter media. Different concentrations of lead and copper sulfate were added to polluted urban stream inflow water to simulate pretreated mine wastewater. The relationships between growth media, microbial and plant communities as well as the reduction of predominantly lead, copper and five-day biochemical oxygen demand (BOD5) were investigated. An analysis of variance showed that concentration reductions (mg l(-1)) of lead, copper and BOD5 were significantly similar for the six experimental wetlands. Microbial diversity was low due to metal pollution and similar for all filters. There appears to be no additional benefit in using adsorption media and macrophytes to enhance biomass performance during the first 10 months of operation.

Ecological equilibrium on biological activated carbon

This paper examines the potential of a biological activity control system (BACS) for biological activated carbon (BAC) in comparison to granular activated carbon (GAC) for the treatment of potable water. The overall objective of the project is to produce drinking water of a higher quality more economically by developing a BACS for exhausted GAC that can be transformed to BAC by the development of a natural biofilm during the bio-regeneration mode. The research therefore may be interesting for water companies and the activated carbon industry. Findings show that the lifetime of a GAC filter can be significantly extended by maintaining an active biofilm that has to be controlled in order to avoid filter clogging. The most important parameters are dissolved oxygen (DO), pH and a correct balance of nutrients, which enables a natural control of the biomass. pH control was required to maintain an optimal bacteria-protozoa level. Excessive growth of filamentous bacteria can be prevented by a decrease in DO, increase in pH and the reduction of one essential nutrient, e.g. total phosphorus (P). Total organic carbon (TOC) and chemical oxygen demand (COD) values were reduced by bioactivity. DO, turbidity and suspended solids (SS) values were kept in acceptable ranges with respect to drinking water objectives. Plants without a significant population of protozoa deliver turbid low quality effluent high on SS and biochemical oxygen demand (BOD). It was possible to control the biofilm on GAC containing a natural biofilm and BAC during the bio-regeneration mode. Natural and artificial bio-regeneration lead to similar performance characteristics.

The universal design, operation and maintenance guidelines for farm constructed wetlands (FCW) in temperate climates

This paper comprises the scientific justification for the Farm Constructed Wetland (FCW) Design Manual for Northern Ireland and Scotland. Moreover, this document addresses an international audience interested in applying wetland systems in the wider agricultural context. Farm constructed wetlands combine farm wastewater (predominantly farmyard runoff) treatment with landscape and biodiversity enhancements, and are a specific application and class of integrated constructed wetlands (ICW), which have wider applications in the treatment of other wastewater types such as domestic sewage. The aim of this review paper is to propose guidelines highlighting the rationale for FCW, including key water quality management and regulatory issues, important physical and biochemical wetland treatment processes, assessment techniques for characterizing potential FCW sites and discharge options to water bodies. The paper discusses universal design, construction, planting, maintenance and operation issues relevant specifically for FCW in a temperate climate, but highlights also catchment-specific requirements to protect the environment.

Review of environmental effects and treatment of runoff from storage and handling of wood

This review paper summarises the environmental effects of runoff from wood handling sites including log yards. The characteristics of site runoff and the corresponding effects on the receiving watercourses are presented for worldwide case studies, highlighting the urgent need to address the water pollution problem associated with the wood industry. The methods used to reduce the negative environmental impact of the runoff, such as constructed wetlands, soil infiltration and chemical oxidation, are evaluated. The principal environmental problem of runoff is usually the high concentration of organic substances originating from the wood and bark, some of which are toxic to aquatic life. Phosphorus is also a problem according to some studies. The toxicity of the runoff varies greatly, and depends on the species of tree stored, the amount of water the wood has been in contact with and the degree of runoff treatment.

Assessment of pre-digested piggery wastewater treatment operations with surface flow integrated constructed wetland systems

Non-point source pollution such as land-spreading of nitrogen-rich piggery wastewater poses a significant threat to surface waters. The aim was to examine the treatment of anaerobically digested piggery wastewater using four different meso-scale integrated constructed wetland (ICW) systems planted with Glyceria maxima. Four replicates were used for each system to assess differences due to nutrient loading, hydraulic loading and effluent recycling. All systems were effective in removing total organic nitrogen, ammonia-nitrogen, nitrate-nitrogen and molybdate reactive phosphorus. However, ammonia-nitrogen removal was the greatest challenge for high flow rates (>100 m(3)/ha/d). Nitrification was higher in summer than winter. Findings show for the first time that effluent recycling within ICW was beneficial to lower ammonia-nitrogen but was associated with higher operational costs. The cost-benefit ratio based on ammonia-nitrogen removal for standard, recycling, high nutrients and high flow rate treatments was 1.08:1.04:1.06:1.00. It follows that a high flow rate was only marginally more cost-effective.

Processes impacting on benzene removal in vertical-flow constructed wetlands.

The overall aim of this research project was to reduce low molecular weight hydrocarbons such as benzene in produced wastewaters. Over 30 months of research was conducted to test the treatment performance in terms of benzene removal in vertical-flow constructed wetlands. Based on an influent concentration of 1 g L(-1) benzene, the results show mean benzene removal efficiencies between 88.71% and 89.77%, and 72.66% and 80.46% for indoor and outdoor constructed wetlands, respectively. A statistical analysis indicated that the five days at 20 degrees C N-allylthiourea biochemical oxygen demand (BOD(5)), chemical oxygen demand (COD), nitrate-nitrogen (NO(3)-N), dissolved oxygen (DO) and electric conductivity (EC) values of the effluent were positively correlated with the effluent benzene concentrations following the order COD>DO>EC>NO(3)-N>BOD(5), and negatively correlated according to the order pH>redox potential (redox)>temperature (T)>turbidity. No strong relationships between benzene and the variables ortho-phosphate-phosphorus (PO(4)(3-)) and ammonia-nitrogen (NH(4)-N) were recorded.

Assessment of the nutrient removal performance in integrated constructed wetlands with the self-organizing map

The self-organizing map (SOM) model was applied to predict outflow nutrient concentrations for integrated constructed wetlands (ICWs) treating farmyard runoff. The SOM showed that the outflow ammonia-nitrogen concentrations were strongly correlated with water temperature and salt concentrations, indicating that ammonia-nitrogen removal is effective at low salt concentrations and comparatively high temperatures in ICWs. Soluble reactive phosphorus removal was predominantly affected by salt and dissolved oxygen concentrations. In addition, pH and temperature were weakly correlated with soluble reactive phosphorus removal, suggesting that soluble reactive phosphorus was easily removed within ICWs, if salt concentrations were low, and dissolved oxygen, temperature and pH values were high. The SOM model performed very well in predicting the nutrient concentrations with water quality variables such as temperature, conductivity and dissolved oxygen, which can be measured cost-effectively. The results indicate that the SOM model was an appropriate approach to monitor wastewater treatment processes in ICWs.