Minggang Hu

Ultra-low viscosity liquid crystal materials

We report five ultra-low viscosity nematic liquid crystal mixtures with birefringence around 0.1, dielectric anisotropy in the range of 3 to 6, and clearing temperature about 80°C. A big advantage of these low viscosity mixtures is low activation energy, which significantly suppresses the rising rate of viscosity at low temperatures. Using our mixture M3 as an example, the response time of a 3-μm cell at −20°C is only 30 ms. Widespread application of these materials for display devices demanding a fast response time, especially at low temperatures, is foreseeable.

Fast-response liquid crystals for high image quality wearable displays

We demonstrate two ultra-low viscosity liquid crystal mixtures to enable field-sequential-color wearable displays for low temperature operation, while keeping a wide color gamut. Our mixtures offer ~4X faster response time than a commercial material at 20°C and ~8X faster at −20°C. Other major attractive features include: (1) submillisecond response time at room temperature and vivid color even at −20°C without a heating device, (2) high brightness and excellent ambient contrast ratio, and (3) suppressed color breakup with 360Hz frame rate.

Flexoelectric effect and human eye perception on the image flickering of a liquid crystal display

We investigated the flexoelectric effect of a fringe field switching liquid crystal (LC) cell and characterised the resultant image flicker with different LC mixtures at different frame rates. Incorporating with human eye perception of 10 observers, we found that LC mixtures with a dielectric anisotropy smaller than ~7 lead to unnoticeable image flicker at 60 frames per second. The obtained flicker sensitivity line serves as important guidelines for optimising LC materials and display devices.

High performance liquid crystals for vehicle displays

We report three liquid crystal (LC) mixtures with a wide nematic range (−40°C to ~100°C), small visco-elastic coefficient and low activation energy for vehicular displays. Physical properties at different temperatures were characterized. These LCs greatly improve the performance of different display devices in a car: 1) for head-up projection using liquid-crystal-on-silicon with an average gray-to-gray (GTG) response time less than 1 ms at an elevated temperature. 2) The average GTG response time is maintained at ~10 ms for fringing field switching LCD at T = 0°C and also ~10 ms for twisted nematic LCD at T = −20°C.

Highly fluorinated liquid crystals with wide nematic phase interval and good solubility

A series of new liquid crystal compounds with both ethylene and difluoromethyleneoxy linking groups have been synthesised and their physical properties were measured. The compounds exhibit lower melting points and broader nematic mesophase temperature range than that of corresponding four-rings compound. Their anisotropic properties are Δε of about 25 and Δn of 0.135. The investigation shows that their solubilities are much better than that of reference compound. A mixture made by equivalent mass ratio of the compounds with side chain of ethyl, propyl and pentyl is found to keep nematic phase from 12°C°C to 109°C, which is rarely observed in highly fluorinated liquid crystals.

Tolane liquid crystals bearing fluorinated terminal group and their mid-wave infrared properties

This paper describes the synthesis and characterisation of several liquid crystal (LC) compounds having a tolane core structure and a trifluoromethoxy terminal group. The mesomorphic properties, mid-wave infrared (IR) absorption and birefringence were investigated. These materials exhibit low absorption in mid-wave IR regions (MWIR) and high birefringence (Δn ~ 0.26–0.29). The impact of fluorine substitution was investigated. Compounds with monofluorine exhibit wide mesophase temperature (88.5°C), and the mesomorphic behaviour weakened with increasing fluorine atom. The results show that they are promising LC materials for applications in the MWIR.

New isothiocyanatotolane liquid crystals with terminal but-3-enyl substitute

ABSTRACT Four kinds of new but-3-enyl-based isothiocyanate liquid crystals composed of tolane core and but-3-enyl terminal group (A1–A4) were synthesised via seven step reactions based on 2-(4-bromophenethyl)-1,3-dioxolane, and four n-butyl analogues B1–B4 as comparison structures were also prepared. The mesomorphic properties and physical properties of the compounds were investigated. Single fluorinated compounds A2 and A3 exhibit monotropic nematic phase, and they have lower melting enthalpy and higher clearing points than those of the comparison compounds B2 and B3. The non-fluoro-substituted compound A1 and difluorinated compound A4 exhibit no nematic phase. Replacement of n-butyl chain by but-3-enyl as terminal group is enabled to increase birefringence (Δn ~ 0.394–0.430) and reduce rotational viscosity. These isothiocyanatotolanes with terminal but-3-enyl substitution have potential application for high birefringence mixtures. GRAPHICAL ABSTRACT

Macroscopic model for analyzing the electro-optics of uniform lying helix cholesteric liquid crystals

A macroscopic model is developed for analyzing the electro-optics of short-pitch uniform lying helix (ULH) cholesteric liquid crystals (CLCs). Both flexoelectric effect and dielectric effect make important contributions to the maximum transmittance and operation voltage of the ULH devices. Based on the proposed macroscopic approximation, we derive an analytical expression to quantitatively evaluate the relative strength of these two effects. Very good agreement between theory and experiment is achieved. We also investigate the viewing angle of ULH CLC displays and find that their viewing angle characteristics are similar to those of conventional in-plane switching liquid crystal displays.A macroscopic model is developed for analyzing the electro-optics of short-pitch uniform lying helix (ULH) cholesteric liquid crystals (CLCs). Both flexoelectric effect and dielectric effect make important contributions to the maximum transmittance and operation voltage of the ULH devices. Based on the proposed macroscopic approximation, we derive an analytical expression to quantitatively evaluate the relative strength of these two effects. Very good agreement between theory and experiment is achieved. We also investigate the viewing angle of ULH CLC displays and find that their viewing angle characteristics are similar to those of conventional in-plane switching liquid crystal displays.

Enlarging the Kerr constant of polymer-stabilised blue phases with a novel chiral monomer

ABSTRACT Polymer-stabilised blue phase liquid crystals (PS-BPLC) have attracted many attentions in the area of display and photonic applications because of the superior electro-optical properties. Before application, the problem of high driving voltage should be resolved first. In this report, a new chiral monomer (C5011) has been synthesised and its influence on PS-BPLC was investigated. By adopting this chiral monomer, the Kerr constant of the PS-BPLC could be increased dramatically, which means improved driving capacity can be achieved. GRAPHICAL ABSTRACT

The effect of locations of triple bond at terphenyl skeleton on the properties of isothiocyanate liquid crystals

ABSTRACT Three series of new tolanyl benzene isothiocyanate liquid crystals A, B and C were synthesised with lateral fluorine substituent at different positions and 3,5-difluoro terminal groups. Series D and compound E4 with carbon–carbon triple bond connected with the isothiocyanated benzene were also prepared as reference. Their structures were confirmed using infrared spectrometry, nuclear magnetic resonance and mass spectrometry. The mesomorphic properties, birefringence, dielectric anisotropy and miscibility of these compounds were investigated. Series A exhibits higher clearing points than that of the corresponding compounds D. Series B displays the lowest melting points, the broadest nematic phase temperature range and no smectic phase with increase of the carbon number of alkyl chain. Lateral fluorine in the position of Y (series C) results in an increase of smectic phase. The birefringence (~0.454–0.490) of series A is almost the same as that of the corresponding reference compounds D, while series B shows a decrease of Δn about 0.05 compared with compounds D. For comparison, mixtures formulated by A and B exhibit higher clearing points and better low temperature stability than those of the mixtures based compounds D in the same fraction. Graphical Abstract