Minxiang Zeng

A review of nanomaterials for nanofluid enhanced oil recovery

Applying nanomaterials in nanoflooding is an emerging research topic in nanomaterials and petroleum engineering research. In this review, we analyzed the functions of nanomaterials during nanofluid flooding operations. We summarized different nanomaterials that have been reported to be used for nanofluid flooding in the lab. We concluded different factors that can control nanofluid flooding qualities. Lastly, we discussed the challenges and opportunities present in nanofluid flooding research.

The Synthesis of Amphiphilic Luminescent Graphene Quantum Dot and Its Application in Miniemulsion Polymerization

Although emulsion applications of microscale graphene sheets have attracted much attention recently, nanoscale graphene platelets, namely, graphene quantum dots (GQDs), have been rarely explored in interface science. In this work, we study the interfacial behaviors and emulsion phase diagrams of hydrophobic-functionalized graphene quantum dots (C18-GQDs). Distinctive from pristine graphene quantum dots (p-GQDs), C18-GQDs show several interesting surface-active properties including high emulsification efficiency in stabilizing dodecane-in-water emulsions. We then utilize the C18-GQDs as surfactants in miniemulsion polymerization of styrene, achieving uniform and relatively small polystyrene nanospheres. The high emulsification efficiency, low production cost, uniform morphology, intriguing photoluminescence, and extraordinary stability render C18-GQDs an attractive alternative in surfactant applications.

High-flux underwater superoleophobic hybrid membranes for effective oil–water separation from oil-contaminated water

Recent oil spills and the rapid expansion of petrochemical industries have highlighted the challenge of effective oil–water separation. Developing a filtration platform based on new surface modification strategies that exhibits good oil–water separation, particularly in a complex environment, is highly desirable for purposes of environmental clean-up. Herein, we present a polymer-modified filter paper (PMFP) with an underwater superoleophobic surface fabricated via a facile dip-coating process. The as-prepared polymer-modified filter paper not only separates the oil–water mixture in gentle environment, but performs effectively in harsh environments, including high salt concentrations, extreme pH, and oil-in-water emulsions with surfactants, suggesting its great potential for large-scale industrial applications.

Thermosensitive ZrP-PNIPAM Pickering Emulsifier and the Controlled-Release Behavior

Asymmetric Janus and Gemini ZrP-PNIPAM monolayer nanoplates were obtained by exfoliation of two-dimensional layered ZrP disks whose surface was covalently modified with thermosensitive polymer PNIPAM. The nanoplates largely reduced interfacial tension (IFT) of the oil/water interface so that they were able to produce stable oil/water emulsions, and the PNIPAM grafting either on the surface or the edge endowed the nanoplates rapid temperature responsivity. The ZrP-PNIPAM nanoplates proved to be thermosensitive Pickering emulsifiers for controlled-release applications.

Aqueous Exfoliation of Graphite into Graphene Assisted by Sulfonyl Graphene Quantum Dots for Photonic Crystal Applications

We investigate the π-π stacking of polyaromatic hydrocarbons (PAHs) with graphene surfaces, showing that such interactions are general across a wide range of PAH sizes and species, including graphene quantum dots. We synthesized a series of graphene quantum dots with sulfonyl, amino, and carboxylic functional groups and employed them to exfoliate and disperse pristine graphene in water. We observed that sulfonyl-functionalized graphene quantum dots were able to stabilize the highest concentration of graphene in comparison to other functional groups; this is consistent with prior findings by pyrene. The graphene nanosheets prepared showed excellent colloidal stability, indicating great potential for applications in electronics, solar cells, and photonic displays which was demonstrated in this work.

Biomimetic colloidal photonic crystals by coassembly of polystyrene nanoparticles and graphene quantum dots

Biomimetic nanostructured materials with iridescent structural colors have attracted great attention due to their potential in photonic devices, materials science, and biomedical engineering. The technological applications of artificial photonic crystals (PCs), however, are often hindered by their low color visibility. Herein, we report colloidal PCs with enhanced color visibility through the coassembly of thioglycerol-modified graphene quantum dots (GQDs) into the close-packed array of polystyrene (PS) nanospheres. The enhanced polystyrene PCs were fabricated by both centrifugal sedimentation and drop-casting methods. The color visibility of the resulting PCs was found to be strongly dependent on the hydrothermal time (i.e., carbonization) and the doping concentrations of GQDs. The PCs with brilliant reflection colors with red, green and blue (RGB) regions have been achieved by controlling the size of the constituent PS nanoparticles. As a proof of concept for photonic ink applications, we demonstrated a number of photonic images with RGB colors on multiple substrates including paper, silicon wafer and glass. This work is expected to provide new insight into the development of emerging advanced photonic crystals with high color visibility for applications such as colloidal paints, textile fabrics, and wearable displays.

Electrostatic‐Driven Dynamic Jamming of 2D Nanoparticles at Interfaces for Controlled Molecular Diffusion

Dynamically engineering the interfacial interaction of nanoparticles has emerged as a new approach for bottom-up fabrication of smart systems to tailor molecular diffusion and controlled release. Janus zwitterionic nanoplates are reported that can be switched between a locked and unlocked state at interfaces upon changing surface charge, allowing manipulation of interfacial properties in a fast, flexible, and switchable manner. Combining experimental and modeling studies, an unambiguous correlation is established among the electrostatic energy, the interface geometry, and the interfacial jamming states. As a proof-of-concept, the well-controlled interfacial jamming of nanoplates enabled the switchable molecular diffusion through liquid-liquid interfaces, confirming the feasibility of using nanoparticle-based surfactants for advanced controlled release.

Hierarchical, Self-Healing and Superhydrophobic Zirconium Phosphate Hybrid Membrane Based on the Interfacial Crystal Growth of Lyotropic Two-Dimensional Nanoplatelets

We demonstrate a facile route to in situ growth of lyotropic zirconium phosphate (ZrP) nanoplates on textiles via an interfacial crystal growing process. The as-prepared hybrid membrane shows a hierarchical architecture of textile fibers (porous platform for fluid transport), ZrP nanoplatelets (layered scaffolds for chemical barriers), and octadecylamine (organic species for superhydrophobic functionalization). Interestingly, such a hybrid membrane is able to separate the oily wastewater with a high separation efficiency of 99.9%, even at in harsh environments. After being chemically etched, the hybrid membrane is able to restore its hydrophobicity autonomously and repeatedly, owing to the hierarchical structure that enables facile loading of healing agent. We anticipate that the concept of implanting superhydrophobic self-healing features in anisotropic structure of lyotropic nanoparticles will open up new opportunities for developing advanced multifunctional materials for wastewater treatment, fuel purification, and oil spill mitigation.