Mirjana Vojinović Miloradov

GIS and the Analytic Hierarchy Process for Regional Landfill Site Selection in Transitional Countries: A Case Study From Serbia

The Serbian National Waste Management Strategy for the Period 2010–2019, harmonized with the European Union Directives, mandates new and very strict requirements for landfill sites. To enable analysis of a number of required qualitative and quantitative factors for landfill site selection, the traditional method of site selection must be replaced with a new approach. The combination of GIS and the Analytic Hierarchy Process (AHP) was selected to solve this complex problem. The Srem region in northern Serbia, being one of the most environmentally sensitive areas, was chosen as a case study. Seventeen factors selected as criteria/sub-criteria were recognized as most important, divided into geo-natural, environmental, social and techno-economic factors, and were evaluated by experts from different fields using an AHP extension in Arc GIS. Weighted spatial layers were combined into a landfill suitability map which was then overlapped with four restriction maps, resulting in a final suitability map. According to the results, 82.65% of the territory of Srem is unsuitable for regional landfill siting. The most suitable areas cover 9.14%, suitable areas 5.24%, while areas with low and very low suitability cover 2.21 and 0.76% of the territory, respectively. Based on these findings, five sites close to two large urban agglomerations were suggested as possible locations for a regional landfill site in Srem. However, the final decision will require further field investigation, a public acceptance survey, and consideration of ownership status and price of the land.

Application of Twisselmann Extraction, SPME, and GC-MS To Assess Input Sources for Organophosphate Esters into Soil

Although the ubiquitous distribution of organophosphate esters (OPEs) in the environment has been documented very thoroughly, data on their occurrence in soil is so far sparse. In this study, an analytical method was developed to determine six OPEs in soil. The method consists of a combination of Twisselmann extraction and solid-phase microextraction (SPME), followed by gas chromatography-mass spectrometry (GC-MS). To develop the method, spiked soil was extracted using a Twisselmann extractor after freeze-drying. The extract was evaporated to dryness, redissolved, and filtered. A volume of 7 mL was then analyzed by SPME, followed by GC-MS. The effects of different parameters on analyte recoveries during sample preparation, e.g., solvent for Twisselmann extraction, solvent for redissolving the extract, addition of copper, and filtration of the extract, were systematically investigated. Under optimum conditions, 10 g soil samples were extracted using toluene, and the extract was redissolved in methanol/water (1:14) and filtered. It was not necessary to add copper. For TnBP, TBEP, TCPP, and TCEP, recoveries ranged from 77.0% to 89.6%. Those for TPP and TDCP were much lower, at 31.5% and 42.0%, respectively (addition level 22.9-45.8 ng g(-1)). The variability of recoveries under these conditions was between 0.3 and 16.2% (n = 3). Limits of detection (LOD) were 0.002-3 ng g(-1). When ultrasonication was used in place of Twisselmann extraction in the developed method, recoveries were three to four times lower (27.4% to 30.6%), but the variability of recoveries was below 3% (n = 3). The method was applied to quantify OPEs in soil collected from the university campus in Osnabrueck (Germany). Average concentrations (n = 6) in soil samples ranged from 1.23 ng g(-1) to 4.96 ng g(-1) (dry weight) for TCPP, TPP, and TCEP. The results demonstrate for the first time that atmospheric deposition leads to soil contamination by OPEs.

Occurrence of antibiotics as emerging contaminant substances in aquatic environment

The occurrence of pharmaceutical residues in the environment has become a subject of growing concern. Due to the constant input of the emerging contaminants in the surface water via wastewater which leads to the long-term adverse effects on the aquatic and terrestrial organisms, special attention is being paid to their presence in the aquatic environment. Most of the emerging substances, especially pharmaceuticals, could not be completely removed using the wastewater treatment. Pharmaceuticals are usually water soluble and poorly degradable. They can pass through all natural filtrations and then reach the groundwater and, finally, the drinking water. The trace levels of antibiotics could have a negative impact on the environment and public health because of their inherent bioactivity. This article is an overview of the presence of the antibiotic residual concentrations, methods and levels of detection and possible risks to both health and environment.

Gas-particle partitioning of persistent organic pollutants in the Western Balkan countries affected by war conflicts.

Background, aim, and scopeBombing and destruction of the industrial and military targets accompanied by complete or incomplete combustion during the war conflict and NATO operation in former Yugoslavia caused the emission of persistent organic pollutants into the atmosphere, water, and soil. A total of 129 ambient air samples from 24 background, urban, and industrial sites, including hot spots, were collected to assess a gas–particle partitioning behavior of various persistent organic pollutants.Materials and methodsHigh volume sampling technique was applied with quartz filters that collect the atmospheric particles and polyurethane foam filters (PUF) that retain the gaseous compounds. Three to ten samples were taken at each site. GFs and PUFs were analyzed separately for their content of polychlorinated biphenyls, organochlorine pesticides, and polyaromatic hydrocarbons.ResultsGas phase and particle phase concentrations of selected persistent organic pollutants (POPs) in all samples were converted into the particle-bound fractions ϕ. These fractions were found to be highly variable, but generally highest in Bosnia and Herzegovina due to the elevated levels of total suspended material in ambient air.DiscussionExperimental values of particle-associated fraction were compared to the Junge–Pankow model. Interestingly, a model for urban/industrial environments provided a better prediction of partitioning behavior than a model for background and rural background sites. That is probably because the total amount of atmospheric particles is higher in the Balkan region than found in the previously published studies.ConclusionsEven though it has been stated in previous studies that less than 5% of polychlorinated biphenyls (PCBs) are bound to the particles, up to 67% of PCBs were particle associated at several sampling sites in this study. PCB-contaminated soils are probably still one of the strong sources of particles to the atmosphere.Recommendations and perspectivesInformation on the particle-bound fractions of POPs is important not only for prediction of their fate but also for an estimation of risks they can pose to the environment as well as to humans. When assessing such hazards, it has to be considered that modeled values of the particle-bound fractions can be seriously underestimated at sites with elevated levels of suspended atmospheric matter or at sites with heavily contaminated soils.

PCB pollution of early milk in the Province of Vojvodina

Seven EPA PCB congeners (28, 52, 101, 118, 138, 153, and 180) were determined in samples of early human milk collected from 18 mothers in Novi Sad, using GC-ECD (HP 5890) supplied with a Quadra fused silica column 5% Ph for PCBs. The sum of seven PCB congeners was 3.26±3.90 (X¯±S.D.), median 1.25, range 0.4-14.31 and the range of individual congeners was for: 28: 0.04-0.37; 52: 0.04-0.44, 101: 0.04-1.21; 118: 0.05-0.62; 138: 0.13-4.61; 153: 0.13-4.81; 180: 0.10-3.07, ng/g wet. No correlation was found between maternal age and seven PCB congeners. In two primiparous mothers below 30 years, the sum of seven PCB congeners was three to fourfold, and in one multiparous twofold higher than the average for the group. Unchanged level of assumed total PCBs in early human milk in 2003, compared with measured total PCBs in 1993, suggest the continuous inlet of these chemicals into the environment.

Meat industry wastewater: microbiological quality and antimicrobial susceptibility of E. coli and Salmonella sp. isolates, case study in Vojvodina, Serbia

Wastewater from meat processing industries is a fusion of compounds with a high load of organic matter, and pathogen microorganisms like Escherichia coli, and Salmonella sp. The aim of this research was to determine microbiological characteristics of the wastewater discharged from the meat processing industry in order to get a more detailed insight into meat industry wastewater pollution, and to evaluate the resistance of bacterial strains E. coli and Salmonella sp. to antibiotics. The evaluation of the antimicrobial susceptibility was performed on 37 strains of E. coli and eight strains of Salmonella sp. to nine different antibiotics. The number of faecal pollution indicators was very high in all samples. From a total of 37 strains of E. coli, a moderate degree of resistance was shown to tetracycline (37.83%); a low degree of resistance to ampicillin (21.62%), streptomycin (24.32%), trimethoprim-sulfamethoxazol (18.92%) and nalidixic acid (16.22%); and very low to: chloramphenicol (13.51%), ciprofloxacin (2.7%), gentamicin and cefotaxime (0.0%). The results for eight strains of Salmonella sp. show that all eight isolates had some degree of susceptibility to nine tested antimicrobial agents and six strains were fully susceptible to all tested antibiotics.

Heavy Metals in the Danube River in Yugoslavia

An evaluation of the potential ecological impact of heavy metals which are not essential for biological communities, such as lead, cadmium, and mercury, clearly illustrates the transpositional problems associated with the by-products of modern society. While some environmental contamination results from the natural leaching of geological formations, the most significant redistribution of toxic trace metals, with the exception of mercury, occurs as a result of societal activities such as mining and fossil fuel combustion. Mercury is continuously evaporating from the Earth’s surfaces and then being washed back to the surfaces through rain and snow; this naturally occurring redistribution of mercury is greater than the redistribution due to societal activities. These materials cannot be easily removed once they are released into the environment. However, they are reactive under certain conditions, and various physical and biological processes (bioaccumulation, biomagnification, etc.) may act to alter their form and distribution.

The emission of BTEX compounds during movement of passenger car in accordance with the NEDC

The results of the research in the field of benzene, toluene, ethylbenzene and xylene isomers (BTEX) concentrations in exhaust gases of spark ignition engines under different operating conditions are presented in this paper. The aim of this paper is to gain a clearer insight into the impact of different engine working parameters on the concentrations of BTEX. The experimental investigation has been performed on the SCHENCK 230 W test stand with the controlled IC engine. The engine operating points have been chosen based on the results of a simulation and they are considered as the typical driving conditions according to the New European Driving Cycle. Concentration levels of BTEX compounds in exhaust gas mixtures have been determined by gas chromatography technique by using the combination of Supelcowax 10-Polyethylene glycol column and the PID detector. Based on the experimental research results, the emission model of BTEX compounds has been defined by the simulation of movement of a Fiat Punto Classic passenger car in accordance with the NEDC cycle. Using the results obtained within the simulation, the official statistics on the number of gasoline-powered cars on the territory of the Republic of Serbia and the European Commission data on the annual distance traveled by car, the amounts of BTEX compounds emitted annually per car have been estimated, as well as the emissions of the entire Serbian car fleet.

Health risk assessment of PAHs, PCBs and OCPs in atmospheric air of municipal solid waste landfill in Novi Sad, Serbia

The municipal solid waste landfill in Novi Sad, Serbia is in its operative status from early 1980s and represents potential significant source of environmental compartments pollution and the threat to human health as a result of undeveloped waste management practice. Residues of Polycyclic Aromatic Hydrocarbons (PAHs) and Persistent Organic Pollutants (POPs) as toxic, mutagenic, teratogenic and carcinogenic chemicals were investigated in ambient air of landfill site in Novi Sad. Passive air sampling technique was used for the purpose of ambient air sampling. Total risk to the human health is calculated as a sum of individual risks for each group of substances according to the recommended United States Environmental Protection Agency (US EPA) methodology. The overall results indicate that the landfill site in Novi Sad does not pose a relevant treat to human by inhalation of PAHs and POPs. The effect of low concentrations, non-monotonic dose response, synergistic and amplifying effects of chemical complexes must be highly respected while performing future health risk assessment.

Emission sources and health risk assessment of polycyclic aromatic hydrocarbons in ambient air during heating and non-heating periods in the city of Novi Sad, Serbia

Abstract The paper presents the assessment of emission sources and health risk of 16 PAHs in the city of Novi Sad, Serbia, with developed oil, food, chemical and cement industry. Although the observed region has been previously studied with regard to the occurrence of PAHs in ambient air, the sources of emission and health risk using multivariate statistical methods have never been studied before. The research was conducted during the heating and non-heating periods at three sampling sites located in industrial, residential and high-traffic area. The samples were collected by high-volume air sampler and analysed using the GC/MS system. The data were processed using the positive matrix factorization (PMF) and cluster analysis. To assess the cancer-risk of PAHs, potency equivalency factor approach was used. The results of PMF analysis have indicated that significant sources of PAH emissions are industrial processes and diesel combustion during the non-heating, and coal combustion, heating plants and diesel combustion during the heating season. Cluster analysis of experimental data has confirmed the results obtained using the PMF method. Estimated values of lifetime lung cancer risk were higher than those set by the World Health Organization and US Environmental Protection Agency which indicates that cancer risk due to exposure to PAHs in ambient air exists in both time periods on the territory of Novi Sad.