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Dive into the research topics where Miroslav Krumpolc is active.

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Featured researches published by Miroslav Krumpolc.


Inorganic Chemistry | 1985

Chromium(V) oxidations of organic compounds

Miroslav Krumpolc; Jan Rocek

Oxydation de composes organiques (diacides carboxyliques, hydroxy- et cetoacides, alcools, aldehydes et divers) par le complexe bis-[ethyl-2 hydroxy-2 butanoato (2-)] oxochromate(V) de sodium


Nuclear Instruments and Methods | 1978

A new CrV doping agent for polarized targets

D. Hill; Robert Miller; Miroslav Krumpolc; Jan Rocek

Abstract Proton dynamic polarization in excess of 70% has been obtained in a first test of a new Cr V complex which can be isolated in a pure, stable form.


Nuclear Instruments and Methods | 1979

Dynamic polarization of protons and deuterons with Crv-complex in pure stable form

Shigenori Hiramatsu; Shigeru Isagawa; Shigeru Ishimoto; A. Masaike; Kimio Morimoto; Toshikazu Adachi; M. Minowa; Miroslav Krumpolc

Abstract Protons in 1,2-propanediol and deuterons in ethylene glycol whose hydrogens were replaced completely by deuterons were dynamically polarized with the Cr v -complex in pure stable form (EHBA-Cr v ) at 25 kG and 0.5 K. Polarizations of protons and deuterons were (82±4)% and (24±3)% respectively.


Journal of the American Chemical Society | 1979

Synthesis of stable chromium(V) complexes of tertiary hydroxy acids

Miroslav Krumpolc; Jan Rocek


Journal of the American Chemical Society | 1978

A stable chromium(V) compound. Synthesis, properties, and crystal structure of potassium bis(2-hydroxy-2-methylbutyrato)oxochromate(V) monohydrate

Miroslav Krumpolc; Barry G. DeBoer; Jan Rocek


Journal of the American Chemical Society | 1977

Three-electron oxidations. 12. Chromium(V) formation in the chromic acid oxidation of 2-hydroxy-2-methylbutyric acid

Miroslav Krumpolc; Jan Rocek


ChemInform | 1979

SYNTHESIS OF STABLE CHROMIUM(V) COMPLEXES OF TERTIARY HYDROXY ACIDS

Miroslav Krumpolc; Jan Rocek


ChemInform | 1978

A STABLE CHROMIUM(V) COMPOUND. SYNTHESIS, PROPERTIES, AND CRYSTAL STRUCTURE OF POTASSIUM BIS(2-HYDROXY-2-METHYLBUTYRATO)OXOCHROMATE(V) MONOHYDRATE

Miroslav Krumpolc; Barry G. DeBoer; Jan Rocek


Journal of the American Chemical Society | 1980

Three-electron oxidations. 17. The chromium(VI) and chromium(V) steps in the chromic acid cooxidation of 2-hydroxy-2-methylbutyric acid and 2-propanol

Surendra N. Mahapatro; Miroslav Krumpolc; Jan Rocek


ChemInform | 1985

CHROMIUM(V) OXIDATIONS OF ORGANIC COMPOUNDS

Miroslav Krumpolc; Jan Rocek

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Jan Rocek

The Catholic University of America

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D. Hill

Argonne National Laboratory

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Robert Miller

Argonne National Laboratory

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