Mohamed Jaziri

Untreated and alkali treated fibers from Alfa stem: effect of alkali treatment on structural, morphological and thermal features

AbstractAlfa stems are rich in cellulose and they are an inexpensive, easily renewable source of natural fibers with the potential for polymer reinforcement. However, large amounts of non-cellulosic materials, surface impurities and low degradnation temperature make natural fibers less attractive for reinforcement of polymeric materials, unless they can be modified in a proper way. In this paper, Alfa stems were treated with NaOH solution with two different concentrations (1 and 5 wt%). Raw and treated stems were crushed to obtain fibers. Stems and fibers were characterized by scanning electron microscopy (SEM) and optical microscopy, respectively. Their crystallinity index was determined by X-ray diffraction, thermal stability by thermogravimetry and structural change by FT-IR and 13C NMR spectroscopy. Comparison and analysis of results confirmed some thermal, structural and morphological changes of the fibers after treatment due to removal of some non-crystalline constituents from the plant. SEM showed rougher surfaces after alkalization. FT-IR and 13C NMR showed a gradual improvement in cellulose level by alkali treatment with increasing NaOH concentration. The crystallinity index and thermal stability of treated Alfa fibers were also found to be improved.

Rheological, Morphological and Mechanical Studies of Sustainably Sourced Polymer Blends Based on Poly(Lactic Acid) and Polyamide 11

The objective of this study was to gain a deep understanding of composition and compatibilization effects on the properties of entirely sustainably sourced polymer blends based on polylactide (PLA) and polyamide 11 (PA11). Generally, PLA cannot challenge regular commodity polymers due to its weak thermo-mechanical properties and its poor elongation properties. With this work, however, we present a promising route to overcome these drawbacks in order to enhance the processability of PLA: blending the polymer with various compositions of other ductile biopolymers such as PA11, as well as mixing PLA/PA11 blends with various amounts of a chain extender, Joncryl ADR®-4368, containing reactive epoxy functions, in a laboratory-scale twin-screw extruder. The effects on the rheological, morphological and mechanical properties were investigated. Results showed that a “self compatibilization” between PLA and PA11 chains can occur but it was found to be insufficient, contrary to recent work reported in the literature. The role of Joncryl as a compatibilizer for the PLA/PA11 system has been demonstrated by the significant decrease of particle size and interfacial tension as well as the improvement of ductile properties. Moreover, a new relaxation peak appeared in the relaxation spectrum, indicating the generation of a copolymer at the polymer-polymer interface.

The effect of extrusion reprocessing cycles on the structure and properties of nano-silica reinforced polypropylene/ethylene-propylene-rubber composites

In this study, the effect of repeated extrusion processing cycles on the structure and properties of polypropylene/ethylene-propylene-rubber/nano-silica composites was investigated. The recycling process was simulated by performing three extrusion runs, using a high shear twin screw extruder by varying the speed screw rotation (300, 800, and 1200u2009r/min), in order to get better understanding of the multi recycling effects. For comparative purposes, neat polypropylene/ethylene-propylene-rubber was also reprocessed under the same conditions as a reference material. From the morphological analyses performed by scanning electron microscopy, multiple extrusions were found to be not only helpful for decreasing the ethylene-propylene-rubber phase size, but also useful for ensuring a more homogenous dispersion of silica nanoparticles within the matrix. The physico-chemical properties analyses illustrate that the repeated cycles of extrusion processing provoke a decrease of the molar masses and an increase in the melt flow index. It was marked that, when going from the 1st to the 2nd extrusion cycle, and by increasing the rotation speed from 300 to 800u2009r/min at the same cycle, the mechanical properties were greatly enhanced. A substantial improvement of these properties was achieved after incorporating the silica nanoparticles and the maleic anhydride grafted polyethylene copolymer.